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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

Terbuthylazine and deethylterbuthylazine in rain and surface water: Determination by enzyme immunoassay and gas chromatography/mass spectrometry Terbuthylazine and deethylterbuthylazine in rain and surface water: Determination by enzyme immunoassay and gas chromatography/mass spectrometry

Rain and surface water samples from Southern Germany were investigated from 1991 to 1995 for terbuthylazine and one of its major metabolites, deethylterbuthylazine. The concentrations observed were compared to the concentrations found for atrazine and deethylatrazine in the same water samples. Concentrations ranged from 0.02 μg/L to 0.7 μg/L for terbuthylazine and from 0.02 μg/L to 0.6...
Authors
A. Dankwardt, E.M. Thurman, B. Hock

Identification of ionic chloroacetanilide-herbicide metabolites in surface water and groundwater by HPLC/MS using negative ion spray Identification of ionic chloroacetanilide-herbicide metabolites in surface water and groundwater by HPLC/MS using negative ion spray

Solid-phase extraction (SPE) was combined with high-performance liquid chromatography/high-flow pneumatically assisted electrospray mass spectrometry (HPLC/ESP/MS) for the trace analysis of oxanilic and sulfonic acids of acetochlor, alachlor, and metolachlor. The isolation procedure separated the chloroacetanilide metabolites from the parent herbicides during the elution from C18...
Authors
Imma Ferrer, E.M. Thurman, Damia Barcelo

Modeling structural influences on soil water retention Modeling structural influences on soil water retention

A new model quantities the effect of soil structure, considered as the arrangement of particles in the soil, on soil water retention. The model partitions the pore space into texture-related and structure-related components, the textural component being what can be deduced to exist if the arrangement of the particles were random, and the structural component being the remainder. An...
Authors
J. R. Nimmo

Bacterial oxidation of methyl bromide in fumigated agricultural soils Bacterial oxidation of methyl bromide in fumigated agricultural soils

The oxidation of [14C]methyl bromide ([14C]MeBr) to 14CO2 was measured in field experiments with soils collected from two strawberry plots fumigated with mixtures of MeBr and chloropicrin (CCl3NO2). Although these fumigants are considered potent biocides, we found that the highest rates of MeBr oxidation occurred 1 to 2 days after injection when the fields were tarped, rather than before...
Authors
L.G. Miller, T.L. Connell, J.R. Guidetti, R.S. Oremland

Borehole sampling of fracture populations - compensating for borehole sampling bias in crystalline bedrock aquifers, Mirror Lake, Grafton County, New Hampshire Borehole sampling of fracture populations - compensating for borehole sampling bias in crystalline bedrock aquifers, Mirror Lake, Grafton County, New Hampshire

The clustering of orientations of hydraulically conductive fractures in bedrock at the Mirror Lake, New Hampshire fractured rock study site was investigated by comparing the orientations of fracture populations in two subvertical borehole arrays with those mapped on four adjacent subvertical roadcuts. In the boreholes and the roadcuts, the orientation of fracture populations appears very...
Authors
G.D. McDonald, Frederick L. Paillet, C.C. Barton, C. D. Johnson

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (δ18O), 2H/1H (δD), 13C/12C (δ13C), tritium (3H), and strontium‐87/strontium‐86 (87Sr/86Sr)] along with geochemical mass‐balance modeling were used to identify the...
Authors
B. G. Katz, T.B. Coplen, T.D. Bullen, J. Hal Davis

Transport and recovery of bacteriophage PRD1 in a sand and gravel aquifer: Effect of sewage-derived organic matter Transport and recovery of bacteriophage PRD1 in a sand and gravel aquifer: Effect of sewage-derived organic matter

To test the effects of sewage-derived organic matter on virus attachment, 32P-labeled bacteriophage PRD1, linear alkylbenzene sulfonates (LAS), and tracers were injected into sewage-contaminated (suboxic, elevated organic matter) and uncontaminated (oxic, low organic matter) zones of an iron oxide-coated quartz sand and gravel aquifer on Cape Cod, MA. In the uncontaminated zone, 83% of...
Authors
A.P. Pieper, J. N. Ryan, Ronald W. Harvey, G.L. Amy, T.H. Illangasekare, D.W. Metge

Logistic model of nitrate in streams of the upper-midwestern United States Logistic model of nitrate in streams of the upper-midwestern United States

Nitrate in surface water can have adverse effects on aquatic life and, in drinking-water supplies, can be a risk to human health. As part of a regional study, nitrates as N (NO3-N) was analyzed in water samples collected from streams throughout 10 Midwestern states during synoptic surveys in 1989, 1990, and 1994. Data from the period immediately following crop planting at 124 sites were...
Authors
D. K. Mueller, B. C. Ruddy, W.A. Battaglin
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