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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

Occurrence and accumulation of pesticides and organic contaminants in river sediment, water and clam tissues from the San Joaquin River and tributaries, California Occurrence and accumulation of pesticides and organic contaminants in river sediment, water and clam tissues from the San Joaquin River and tributaries, California

A study was conducted in 1992 to assess the effects of anthropogenic activities and land use on the water quality of the San Joaquin River and its major tributaries. This study focused on pesticides and organic contaminants, looking at distributions of contaminants in water, bed and suspended sediment, and the bivalve Corbicula fluminea. Results indicated that this river system is...
Authors
W. E. Pereira, Joseph L. Domagalski, F. D. Hostettler, L. R. Brown, J. B. Rapp

Variability in surface energy flux partitioning during Washita '92: Resulting effects on Penman-Monteith and Priestley-Taylor parameters Variability in surface energy flux partitioning during Washita '92: Resulting effects on Penman-Monteith and Priestley-Taylor parameters

During the Washita '92 field experiment, the local surface energy balance was evaluated at four locations in the USDA-ARS Little Washita River Watershed near Chickasha, OK, using the Bowen ratio-energy balance (BREB) approach. For any given day, differences in the partitioning of the available energy appeared to be mostly a function of the type of vegetation at the site, while the actual...
Authors
William P. Kustas, D.I. Stannard, K.J. Allwine

Experimental investigation and modeling of uranium (VI) transport under variable chemical conditions Experimental investigation and modeling of uranium (VI) transport under variable chemical conditions

The transport of adsorbing and complexing metal ions in porous media was investigated with a series of batch and column experiments and with reactive solute transport modeling. Pulses of solutions containing U(VI) were pumped through columns filled with quartz grains, and the breakthrough of U(VI) was studied as a function of variable solution composition (pH, total U(VI) concentration...
Authors
M. Kohler, G.P. Curtis, D.B. Kent, J.A. Davis

Copper speciation and binding by organic matter in copper-contaminated streamwater Copper speciation and binding by organic matter in copper-contaminated streamwater

Fulvic acid binding sites (1.3−70 μM) and EDTA (0.0017−0.18 μM) accounted for organically bound Cu in seven stream samples measured by potentiometric titration. Cu was 84−99% organically bound in filtrates with 200 nM total Cu. Binding of Cu by EDTA was limited by competition from other trace metals. Water hardness was inversely related to properties of dissolved organic carbon (DOC)...
Authors
R.F. Breault, J.A. Colman, G. R. Aiken, D. McKnight

Reactive solute transport in streams: 1. Development of an equilibrium- based model Reactive solute transport in streams: 1. Development of an equilibrium- based model

An equilibrium-based solute transport model is developed for the simulation of trace metal fate and transport in streams. The model is formed by coupling a solute transport model with a chemical equilibrium submodel based on MINTEQ. The solute transport model considers the physical processes of advection, dispersion, lateral inflow, and transient storage, while the equilibrium submodel...
Authors
Robert L. Runkel, Kenneth E. Bencala, Robert E. Broshears, Steven C. Chapra

Use of 13C NMR and ftir for elucidation of degradation pathways during natural litter decomposition and composting I. early stage leaf degradation Use of 13C NMR and ftir for elucidation of degradation pathways during natural litter decomposition and composting I. early stage leaf degradation

Oxidative degradation of plant tissue leads to the formation of natural dissolved organic carbon (DOC) and humus. Infrared (IR) and 13C nuclear magnetic resonance (NMR) spectrometry have been used to elucidate the chemical reactions of the early stages of degradation that give rise to DOC derived from litter and compost. The results of this study indicate that oxidation of the lignin...
Authors
R.L. Wershaw, J.A. Leenheer, K. R. Kennedy, T.I. Noyes

Hydrologic evaluation methodology for estimating water movement through the unsaturated zone at commercial low-level radioactive waste disposal site Hydrologic evaluation methodology for estimating water movement through the unsaturated zone at commercial low-level radioactive waste disposal site

This report identifies key technical issues related to hydrologic assessment of water flow in the unsaturated zone at low-level radioactive waste (LLW) disposal facilities. In addition, a methodology for incorporating these issues in the performance assessment of proposed LLW disposal facilities is identified and evaluated. The issues discussed fall into four areas:Estimating the water...
Authors
P.D. Meyer, M.L. Rockhold, W.E. Nichols, G.W. Gee

Hydrogeology and simulation of ground-water flow, Picatinny Arsenal and vicinity, Morris County, New Jersey Hydrogeology and simulation of ground-water flow, Picatinny Arsenal and vicinity, Morris County, New Jersey

Ground-water flow in glacial sediments and bedrock at Picatinny Arsenal, N.J., was simulated by use of a three-dimensional finite-difference ground- water-flow model. The modeled area includes a 4.3-square-mile area that extends from Picatinny Lake to the Rockaway River. Most of the study area is bounded by the natural hydrologic boundaries of the ground-water system. eophysical logs...
Authors
L. M. Voronin, D.E. Rice

Effects of sampling strategies on estimates of annual mean herbicide concentrations in midwestern rivers Effects of sampling strategies on estimates of annual mean herbicide concentrations in midwestern rivers

The effects of 10 sampling strategies on estimates of annual mean concentrations of the herbicides atrazine, alachlor, and cyanazine in selected midwestern rivers were tested. The accuracy of the strategies was computed by comparing time-weighted annual mean herbicide concentrations calculated from water samples collected from 17 locations on midwestern rivers, with simulated annual mean
Authors
W.A. Battaglin, L.E. Hay

The deethylatrazine/atrazine ratio as an indicator of the onset of the spring flush of herbicides into surface water of the Midwestern United States The deethylatrazine/atrazine ratio as an indicator of the onset of the spring flush of herbicides into surface water of the Midwestern United States

The ratio of deethylatrazine to atrazine (DAR) may be used to record the first major runoff of herbicides from non-point-source corn fields to surface water in the Midwestern United States. The DAR dramatically decreases from ∼0.5 to 0.1 upon application of herbicide and the first major runoff event of a basin. The DAR then gradually increases to values of approximately 0.4–0.6 during...
Authors
E.M. Thurman, J. D. Fallon
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