Applying geological unit distribution and chemical weathering indices to evaluate potential lithological sources of Al, As and Pb to the San Juan River, Four Corners region, USA

In arid to semi-arid landscapes, sporadic monsoonal events, varying widely in scale and distribution, can generate overland flow resulting in streamflow in ephemeral channels. These channels may contain metal-laden sediments that are a by-product of the weathering and erosion of local geological units. To evaluate the potential for local geology to contribute aluminium (Al), arsenic (As) and lead (Pb) to the San Juan River, northwestern New Mexico, USA, the distributions of geological units were delineated for 12 hydrological basins within the greater San Juan River watershed. Concentrations of Al, As and Pb in the predominant geological units were compiled from data in the National Geochemical Database. Chemical indices of weathering (CIW) were calculated for geological units with greater than 5% coverage in the entire San Juan River watershed. Based on CIWs of the major geological units, the Mesaverde Group (CIW = 95.2), Chinle and Dolores Formations (combined) (CIW = 93.3), and Mancos Shale (combined) (CIW = 82.6) are the most likely units to weather, erode and contribute sediments with elevated concentrations of Al, As and Pb to the San Juan River. The results of this study show the importance of understanding geological sources of sediments because they could be substantial contributors of constituents of concern to water, especially in arid environments where surface water may be the only source of water in the region.