Geochemical and tectonic evolution of the Ordovician Bronson Hill arc and Silurian and Devonian Connecticut Valley–Gaspé trough: Eastern Vermont and western New Hampshire, USA

We present major and trace element whole-rock geochemistry of 94 samples from the Bronson Hill arc (BHA) and Connecticut Valley–Gaspé trough (CVGT). These data, when combined with recent zircon U-Pb geochronology and a reexamination of existing whole-rock geochemistry, enable a new analysis of the tectonic history of the ancient Laurentian-Ganderian margin in the northern Appalachians of New England, USA, and southeastern Canada. The whole-rock geochemical data from the Ordovician BHA in western New Hampshire indicate that metamorphosed extrusive and intrusive rocks share the same temporally variable geochemical fingerprint. Mafic and felsic rocks form a bimodal distribution and plot as island arc magmas on geochemical discrimination diagrams. Approximately 80% of mafic greenstone and amphibolite samples plot as island arc tholeiites with a subset of samples that trend toward a more within-plate basalt geochemical signature. Where ages are known, older felsic rocks (ca. 475–460 Ma) in the BHA tend to be more sodic and less potassic than their younger (ca. 460–445 Ma) counterparts, and the geochemical results trend from volcanic arc granites toward syn-collisional granites through time. Prior to recent geochronology, it was thought that an age gap existed between the island arc magmas and the syn collisional granites. This led to the separation of felsic plutons into the predominantly older trondhjemitic magmas assigned to the Ammonoosuc Volcanics and a younger suite of granites designated as the Oliverian Plutonic Suite. This age gap was thought to represent a flip in subduction polarity which would also account for observed changes in pluton chemistry. With the addition of more recent U-Pb isotopic age data, we now know there is a continuum of ages, and a polarity flip is no longer required. When the isotopic ages are combined with the new geochemical data presented here, they suggest that as the BHA approached and collided with Laurentia ca. 455 Ma, continental material was assimilated into the magma, and there was a transition from trondhjemite to granodiorite and granite magmas in felsic rocks and from island arc tholeiite toward more alkali-rich basalt with a continental signature in mafic magmas. The similarities in whole-rock and trace element geochemistry, rock type, and range of isotopic ages from the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic Suite, suggest they originated from the same magma source and were part of one evolving island arc system that persisted throughout the Ordovician, and the need to separate the Oliverian Plutonic Suite from the Ammonoosuc Volcanics is not necessary.

Most magmatism in the BHA ceased ca. 440 Ma. Following the Taconic orogeny, Silurian basin development was widespread along the length of the Laurentian-Ganderian suture. In New England and Québec, this resulted in the formation of the CVGT. The BHA and the CVGT are generally studied separately: the BHA in the context of arc-continent collision during the Taconic orogeny, and the CVGT as it relates to post-orogenic extension or the distal effects of the Salinic disturbance. When viewed collectively, the igneous geochemistry of the BHA and CVGT reveals an overlap between the waning stages of Taconic orogenesis and the onset of Silurian to Devonian basin development in the northern Appalachians. Metamorphosed bimodal volcanic and intrusive rocks are present in the CVGT (ca. 434–407 Ma) and Silurian cover sequence, which unconformably overlies the BHA. Mafic rocks in the CVGT are mostly tholeiitic basalts with a subset of alkali basalt in the Waits River Formation. Tectonic discrimination diagrams show that the mafic rocks are a mix of mid-ocean ridge basalt to within-plate basalt. The felsic rocks in the CVGT are mostly metamorphosed volcanic rocks that vary from island arc granite to within-plate granite. The geochemical signature of the CVGT is consistent with a post-collisional intra-arc basin, where slab breakoff or crustal attenuation played a key role before transitioning to a deepening foreland basin at the beginning of the Acadian orogeny.