Mappable criteria for Li-mineralized pegmatites in the Appalachian orogen (utilizing the mineral systems approach)

Li-mineralized pegmatites are found throughout the Appalachian orogenic belt. Available evidence layers (e.g. tectonic setting, structures, geochemistry, geochronology) are used to develop mappable criteria for mineral resource assessments of Li-mineralized pegmatites in the northern and southern U.S. Appalachians. These evidence layers are placed into a mineral systems anatomy and classification of tectonic settings approach. We find that triggers of Li-mineralized pegmatite petrogenesis are closely associated with terrane accretion, continental collision, and orogenic collapse, spanning the Acadian to Alleghanian orogenies. These include overthickened crust in the northern Appalachians (Acadian altiplano) and terrane accretion in the southern Appalachians. The energy drivers of the system are anatexis broadly plutonism and/or deformation-related melting processes. Metal sources are associated with magmatic fluids of highly differentiated granitoids (e.g. peraluminous, S-type) and Silurian- Devonian sedimentary rocks. In many instances permeability and pathways of these systems are structurally controlled along major fault systems and within highly deformed metasedimentary rocks in the north. Notably, there are Li-mineralized pegmatite gaps along the Appalachian orogen that include: 1) regions of exposure of unfavorable metamorphic grade rocks, 2) favorable areas deeply buried by sedimentary rocks, and 3) gaps of unknown causes. Exhumation and preservation of midcrustal rocks are favourable as hosts to lithiummineralized pegmatites.