Publications

The sulfate‐methane transition (SMT), a biogeochemical zone where sulfate and methane are metabolized, is commonly observed at shallow depths (1–30 mbsf) in methane‐bearing marine sediments. Two processes consume sulfate at and above the SMT, anaerobic oxidation of methane (AOM) and organoclastic sulfate reduction (OSR). Differentiating the relative contribution of each process is...

The BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well was an integral part of an ongoing project to determine the future energy resource potential of gas hydrates on the Alaska North Slope. As part of this effort, the Mount Elbert well included an advanced downhole geophysical logging program. Because gas hydrate is unstable at ground surface pressure and temperature...

Coastal wetlands are responsible for about half of all carbon burial in oceans, and their persistence as a valuable ecosystem depends largely on the ability to accumulate organic material at rates equivalent to relative sea level rise. Recent work suggests that 5 elevated CO2 and temperature warming will increase organic matter productivity and the ability of marshes to survive sea level...

The magnitude and feedbacks of future methane release from the Arctic region are unknown. Despite limited documentation of potential future releases associated with thawing permafrost and degassing methane hydrates, the large potential for future methane releases calls for improved understanding of the interaction of a changing climate with processes in the Arctic and chemical feedbacks...

The isotopic signature of geogenic and anthropogenic materials, in combination with concentration data for pollutants, can help trace the origin and the extent of contamination in the environment. This approach is particularly effective if naturally occurring and anthropogenically introduced metals have different isotopic ratios. Lead isotope analysis on soils from 7 profiles (1 m depth)...

Antecedent geology plays a crucial role in determining the inner-shelf, nearshore, and onshore geomorphology observed in coastal systems. However, the influence of the geologic framework on a system is difficult to extract when evaluating responses to changes due to storms and anthropogenic modifications, and few studies have quantified the potential for these influences in dune/beach...

Regional Ocean Modeling System (ROMS v 3.0), a three-dimensional numerical ocean model, was previously enhanced for shallow water applications by including wave-induced radiation stress forcing provided through coupling to wave propagation models (SWAN, REF/DIF). This enhancement made it suitable for surf zone applications as demonstrated using examples of obliquely incident waves on a...

In a previous study, the embryotoxicity of methylmercury dissolved in corn oil was compared among 26 species of birds. Corn oil is not soluble in the water‐based matrix that constitutes the albumen of an egg. To determine whether the use of corn oil limited the usefulness of this earlier study, a comparison was made of the embryotoxicity of methylmercury dissolved in corn oil versus...

Captive breeding is key to management of severely endangered species, but maximizing captive production can be challenging because of poor knowledge of species breeding biology and the complexity of evaluating different management options. In the face of uncertainty and complexity, decision-analytic approaches can be used to identify optimal management options for maximizing captive...

Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the methane generated in organic-rich sediments underlying surface water bodies, including lakes, wetlands, and the ocean. The fraction of the methane that reaches the...

Adaptive management is an approach to recurrent decision making in which uncertainty about the decision is reduced over time through comparison of outcomes predicted by competing models against observed values of those outcomes. The National Wildlife Refuge System (NWRS) of the U.S. Fish and Wildlife Service is a large land management program charged with making natural resource...

We report the results of low temperature (−10°C) experiments on the stability fields and phase transition pathways of five hydrous Mg-sulfates. A low temperature form of MgSO4·7H2O (LT-7w) was found to have a wide stability field that extends to low relative humidity (∼13% RH at −10°C). Using information on the timing of phase transitions, we extracted information on the reaction rates...