Aaron M. Jubb, Ph.D.
Dr. Aaron Jubb is a Research Chemist with the USGS Geology, Energy & Minerals (GEM) Science Center in Reston, Virginia.
Following his graduate studies, Dr. Jubb completed post-doctoral work at the National Oceanic and Atmospheric Administration’s (NOAA) Chemical Science Division in Boulder, Colorado focusing on the atmospheric chemistry of CFC replacements and at Oak Ridge National Laboratory in Oak Ridge, Tennessee with an emphasis on the development and application of surface enhanced Raman scattering sensors. Dr. Jubb joined the USGS in 2017 where his principle areas of study involve:
- Composition of oil and gas-associated wastewaters
- Molecular characterization of sedimentary organic matter
- In situ characterization of rock wettability
Professional Experience
2017 – Present: Research Chemist, U.S. Geological Survey, Reston, VA
2015 – 2016: Post-doctoral Research Associate, Oak Ridge National Laboratory, Oak Ridge, Tennessee
2012 – 2015: Research Scientist 1, National Oceanic and Atmospheric Administration, Boulder, Colorado
Education and Certifications
Ph.D. Chemistry, The Ohio State University, 2012
B.A. Chemistry, Lawrence University, 2006
Affiliations and Memberships*
American Chemical Society
American Geophysical Union
Geochemical Society
The Society for Organic Petrology
Science and Products
Advancements in Geochemistry and Geomicrobiology of Energy Resources (AGGER)
The AGGER project’s purpose is to advance the understanding of geologic energy sources, generation, composition, movement, and production potential, including resource recovery from energy wastes.
Molecular Fingerprinting of Energy Materials
The chemical composition of complex solid organic matter (OM) from sedimentary reservoirs is a key parameter in the generation of hydrocarbon fuels. Vibrational spectroscopies such as Fourier transform infrared (FTIR) and Raman have been widely applied to understand the molecular make-up of these hydrocarbon precursors, as well as provide links to their thermal histories via correlation to proven...
Filter Total Items: 27
Produced water major ion geochemistry, water isotopes, radium content, and field parameters and gas compositions from Niobrara Formation petroleum wells in the Denver-Julesburg Basin
This data release includes field parameters (pH and specific conductance), major ion geochemistry (B, Ba, Br, Cl, Ca, Fe, K, Li, Mg, Mn, Na, Si, SO4, Sr), total dissolved solids, specific gravity, water isotopes (delta-2H and delta-18O), and radium isotopes (226Ra and 228Ra) from produced water samples taken from petroleum wells producing from the Niobrara Formation in the Denver-Julesburg Basin,
Lithium observations, machine-learning predictions, and mass estimates from the Smackover Formation brines in southern Arkansas
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. The goal of this work was to calculate the total lithium mass in brines of the Reynolds oolite unit of the Smackover Formation in southern Arkansas using predicted lithium concentrations f
Coal mine drainage effluents and associated solids major, trace, rare earth element and radium concentrations collected from Pennsylvania, USA
Discharges from abandoned coal mines and associated mine wastes represent historic and persistent sources of pollution in the Appalachian Basin, United States. In this study, we conducted the first-ever survey of radium (Ra) in coal mine drainage (CMD) water and solid samples in the United States. Samples were collected from 4 untreated coal mine discharges and 9 treated coal mine discharges (i.e.
Geochemistry and microbiology data collected to study the effects of oil and gas wastewater dumping on arid lands in New Mexico
The Permian Basin, straddling New Mexico and Texas, is one of the most productive oil and gas (OG) provinces in the United States. OG production yields large volumes of wastewater that contain elevated concentrations of major ions including salts (also referred to as brines), and trace organic and inorganic constituents. These OG wastewaters pose unknown environmental health risks, particularly in
By
Water Resources Mission Area, Energy Resources Program, Environmental Health Program, Columbia Environmental Research Center, Geology, Energy & Minerals Science Center, Eastern Energy and Environmental Laboratory (EEEL), Reston Biogeochemical Processes in Groundwater Laboratory, Reston Microbiology Laboratory
SEM-CL investigation of sedimentary organic matter samples
High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter (SOM) is widely utilized in the geosciences for evaluation of microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM approaches, the inability of SEM to d
Total neutron scattering of methane in Niobrara Formation samples at the wet-gas maturity level
Petroleum within unconventional source-rock reservoirs is hosted in organic matter and mineral pore space as well as in voids and microfractures. Recent work has shown that for source-rock reservoirs in the dry gas window, significant portions of methane (CH4), the main component of petroleum at elevated maturities, can be stored within fine organic matter porosity. However, within reservoirs at l
Portable Raman spectroscopic analysis of bulk crushed rock
This study presents a simplified method and empirical relationships for determining organic matter thermal maturity using a portable Raman system equipped with a 785 nm laser, for analysis of crushed, whole-rock samples. Several sets of rocks comprised of shale and coal samples with various mineralogical composition, thermal maturity, total organic carbon (TOC), and age were used to test the metho
Evidence for strain induced graphitization across a ductile fault zone
A suite of slate samples collected along a 2 km transect crossing the Lishan Fault in central Taiwan were evaluated to assess the role of ductile strain energy in natural graphitization at greenschist facies metamorphic conditions. Scanning electron microscope (SEM) imaging documents phyllosilicate and quartz replacement textures consistent cleavage development via dissolution-precipitation proces
Thermal evolution of graptolite and solid bitumen properties at high maturity under natural and artificial conditions
To refine the use of graptolite and solid bitumen properties as thermal proxies at overmature conditions, we evaluated their evolution via Raman and infrared spectroscopies, reflectance, and geochemical screening in high-temperature hydrous and anhydrous experiments in comparison to naturally matured samples. Naturally matured samples included four overmature Wufeng-Longmaxi marine shales from the
Strain induced molecular heterogeneity in ancient sedimentary organic matter mapped at nanoscales using optical photothermal infrared spectroscopy
Here we report ultra-high resolution infrared mapping of organic matter functional group distribution in Tasmanites (algal microfossils) from the Upper Devonian Ohio Shale using optical photothermal infrared spectroscopy (O-PTIR). O-PTIR is capable of rapidly measuring the vibrational response of samples in situ with ~500-nm spatial resolution, well below the infrared diffraction limit. Our result
Textural occurrence and organic porosity of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) to assess solid bitumen composition and porosity development as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1-103 days, 300-370°C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt. %] New
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize produced water
Filter Total Items: 37
Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse
Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concern
Authors
Aaron M. Jubb, Jenna L. Shelton, Bonnie McDevitt, Kaela K. Amundson, Amanda Sha Herzberg, Jessica Chenault, Andrew Laurence Masterson, Matthew S. Varonka, Glenn D. Jolly, Christina A. DeVera, Elliott Barnhart, Michael J. Wilkins, Madalyn S. Blondes
Evaluation of the lithium resource in the Smackover Formation brines of southern Arkansas using machine learning
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithiu
Authors
Katherine J. Knierim, Madalyn S. Blondes, Andrew Laurence Masterson, Philip A. Freeman, Bonnie McDevitt, Amanda Sha Herzberg, Peng Li, Ciara Mills, Colin A. Doolan, Aaron M. Jubb, Scott Ausbrooks, Jessica Chenault
Evaluation of coal mine drainage and associated precipitates for radium and rare earth element concentrations
Coal mine drainage (CMD) and associated metal-rich precipitates have recently been proposed as unconventional sources of rare earth elements (REEs). However, the potential occurrence of radium (Ra), a known carcinogen, with the REE-bearing phases has not been investigated. We hypothesized that Ra may occur in solids that are precipitated from CMD as a “radiobarite” solid solution ((Ba,Sr,Ra)SO4) a
Authors
Bonnie McDevitt, Charles A. III Cravotta, Ryan J. McAleer, John C Jackson, Aaron M. Jubb, Glenn D. Jolly, Benjamin C. Hedin, Nathaniel R. Warner
Ion exchange processes for CO2 mineralization using industrial waste streams: Pilot plant demonstration and life cycle assessment
An attractive technique for removing CO2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO2 (pH<4.5) and Ca2+ ions. In this study, a pH-swing process using ion exchange was demonstrated to process
Authors
Steven Bustillos, Mario Christofides, Bonnie McDevitt, Madalyn S. Blondes, Ryan J. McAleer, Aaron M. Jubb, Bu Wang, Gaurav Sant, Dante Simonetti
Cathodoluminescence differentiates sedimentary organic matter types
High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter is widely utilized in the geosciences for evaluating microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM methods, the inability of SEM to differentiate
Authors
Paul C. Hackley, Ryan J. McAleer, Aaron M. Jubb, Brett J. Valentine, Justin E. Birdwell
Deformation-induced graphitization and muscovite recrystallization in a ductile fault zone
A suite of slate samples collected along a 2 km transect crossing the Lishan fault in central Taiwan were evaluated to assess the role of ductile deformation in natural graphitization at lower greenschist facies metamorphic conditions. The process of natural aromatization, or graphitization, of an organic precursor is well established as a thermally driven process; however, experimental studies ha
Authors
Martha (Rebecca) Stokes, Aaron M. Jubb, Ryan J. McAleer, David Bish, Robert Wintsch
Insights into glendonite formation from the upper Oligocene Sagavanirktok Formation, North Slope, Alaska
The type locality for the upper Oligocene Nuwok Member of the Sagavanirktok Formation (Carter Creek, North Slope, Alaska, USA) contains abundant occurrence of glendonite, a pseudomorph after the calcium carbonate mineral ikaite, which typically forms in the shallow subsurface of cold marine sediments. The region during the time of Nuwok Member deposition was located at a high latitude, similar to
Authors
John W. Counts, Madeleine Vickers, Martha (Rebecca) Stokes, Whittney Spivey, Kristina Frank Gardner, Jean Self-Trail, Jared T. Gooley, Ryan J. McAleer, Aaron M. Jubb, David W. Houseknecht, Richard O. Lease, Neil Patrick Griffis, Martin S. Vickers, Kasia Śliwińska, Hannah Gail Dooley Tompkins, Adam M. Hudson
Evaluation of portable Raman spectroscopic analysis for source-rock thermal maturity assessments on bulk crushed rock
This study presents a simplified method and empirical relationships for determining organic matter thermal maturity using a portable Raman system equipped with a 785 nm laser, for analysis of crushed, whole-rock samples. Suites of rocks represented by shale and coal samples with various mineralogical composition, thermal maturity, and total organic carbon (TOC) were used to test the method and bui
Authors
Martha (Rebecca) Stokes, Aaron M. Jubb, Paul C. Hackley, Justin E. Birdwell, Elliott Barnhart, Clint Scott, Jenna L. Shelton, Margaret M. Sanders, Javin J. Hatcherian
Methane pore accessibility, densification, and accommodation by organic matter in the Niobrara Formation at wet-gas thermal maturity conditions
Petroleum within unconventional source-rock reservoirs is hosted in organic matter and mineral pore space as well as in voids and microfractures. Recent work has shown that for source-rock reservoirs in the dry gas window, significant portions of methane (CH4), the main component of petroleum at elevated maturities, can be stored within fine (<5 nm) organic matter porosity. However, within reservo
Authors
Aaron M. Jubb, Leslie F. Ruppert, Tristan G. A. Youngs, Tom Headen, Justin E. Birdwell, Michael Cheshire, Martha (Rebecca) Stokes
Thermal evolution of graptolite and solid bitumen properties at high maturity under natural and artificial conditions
To refine the use of graptolite and solid bitumen as thermal proxies at overmature conditions, we evaluated their evolution via Raman and infrared (IR) spectroscopies, reflectance, and geochemical screening using high-temperature pyrolysis experiments in comparison to naturally matured samples. Naturally matured samples included marine shales from the overmature Upper Ordovician Wufeng-Lower Silur
Authors
Jianyang Song, Paul C. Hackley, Margaret M. Sanders, Aaron M. Jubb, Qingyong Luo
Mapping ancient sedimentary organic matter molecular structure at nanoscales using optical photothermal infrared spectroscopy
Elucidating the molecular structure of sedimentary organic matter (SOM) is key to understanding petroleum generation processes, as well as ancient sedimentary environments. SOM structure is primarily controlled by biogenic source material (e.g., marine vs. terrigenous), depositional conditions, and subsurface thermal history. Additional factors, e.g., strain, may also impact the molecular structur
Authors
Aaron M. Jubb, Martha (Rebecca) Stokes, Ryan J. McAleer, Paul C. Hackley, Eoghan Dillion, Jing Qu
Relating systematic compositional variability to the textural occurrence of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) images to assess solid bitumen composition as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1–103 days, 300–370 °C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt%] New Albany Shale sample
Authors
Martha (Rebecca) Stokes, Brett J. Valentine, Aaron M. Jubb, Paul C. Hackley
Science and Products
Advancements in Geochemistry and Geomicrobiology of Energy Resources (AGGER)
The AGGER project’s purpose is to advance the understanding of geologic energy sources, generation, composition, movement, and production potential, including resource recovery from energy wastes.
Molecular Fingerprinting of Energy Materials
The chemical composition of complex solid organic matter (OM) from sedimentary reservoirs is a key parameter in the generation of hydrocarbon fuels. Vibrational spectroscopies such as Fourier transform infrared (FTIR) and Raman have been widely applied to understand the molecular make-up of these hydrocarbon precursors, as well as provide links to their thermal histories via correlation to proven...
Filter Total Items: 27
Produced water major ion geochemistry, water isotopes, radium content, and field parameters and gas compositions from Niobrara Formation petroleum wells in the Denver-Julesburg Basin
This data release includes field parameters (pH and specific conductance), major ion geochemistry (B, Ba, Br, Cl, Ca, Fe, K, Li, Mg, Mn, Na, Si, SO4, Sr), total dissolved solids, specific gravity, water isotopes (delta-2H and delta-18O), and radium isotopes (226Ra and 228Ra) from produced water samples taken from petroleum wells producing from the Niobrara Formation in the Denver-Julesburg Basin,
Lithium observations, machine-learning predictions, and mass estimates from the Smackover Formation brines in southern Arkansas
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. The goal of this work was to calculate the total lithium mass in brines of the Reynolds oolite unit of the Smackover Formation in southern Arkansas using predicted lithium concentrations f
Coal mine drainage effluents and associated solids major, trace, rare earth element and radium concentrations collected from Pennsylvania, USA
Discharges from abandoned coal mines and associated mine wastes represent historic and persistent sources of pollution in the Appalachian Basin, United States. In this study, we conducted the first-ever survey of radium (Ra) in coal mine drainage (CMD) water and solid samples in the United States. Samples were collected from 4 untreated coal mine discharges and 9 treated coal mine discharges (i.e.
Geochemistry and microbiology data collected to study the effects of oil and gas wastewater dumping on arid lands in New Mexico
The Permian Basin, straddling New Mexico and Texas, is one of the most productive oil and gas (OG) provinces in the United States. OG production yields large volumes of wastewater that contain elevated concentrations of major ions including salts (also referred to as brines), and trace organic and inorganic constituents. These OG wastewaters pose unknown environmental health risks, particularly in
By
Water Resources Mission Area, Energy Resources Program, Environmental Health Program, Columbia Environmental Research Center, Geology, Energy & Minerals Science Center, Eastern Energy and Environmental Laboratory (EEEL), Reston Biogeochemical Processes in Groundwater Laboratory, Reston Microbiology Laboratory
SEM-CL investigation of sedimentary organic matter samples
High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter (SOM) is widely utilized in the geosciences for evaluation of microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM approaches, the inability of SEM to d
Total neutron scattering of methane in Niobrara Formation samples at the wet-gas maturity level
Petroleum within unconventional source-rock reservoirs is hosted in organic matter and mineral pore space as well as in voids and microfractures. Recent work has shown that for source-rock reservoirs in the dry gas window, significant portions of methane (CH4), the main component of petroleum at elevated maturities, can be stored within fine organic matter porosity. However, within reservoirs at l
Portable Raman spectroscopic analysis of bulk crushed rock
This study presents a simplified method and empirical relationships for determining organic matter thermal maturity using a portable Raman system equipped with a 785 nm laser, for analysis of crushed, whole-rock samples. Several sets of rocks comprised of shale and coal samples with various mineralogical composition, thermal maturity, total organic carbon (TOC), and age were used to test the metho
Evidence for strain induced graphitization across a ductile fault zone
A suite of slate samples collected along a 2 km transect crossing the Lishan Fault in central Taiwan were evaluated to assess the role of ductile strain energy in natural graphitization at greenschist facies metamorphic conditions. Scanning electron microscope (SEM) imaging documents phyllosilicate and quartz replacement textures consistent cleavage development via dissolution-precipitation proces
Thermal evolution of graptolite and solid bitumen properties at high maturity under natural and artificial conditions
To refine the use of graptolite and solid bitumen properties as thermal proxies at overmature conditions, we evaluated their evolution via Raman and infrared spectroscopies, reflectance, and geochemical screening in high-temperature hydrous and anhydrous experiments in comparison to naturally matured samples. Naturally matured samples included four overmature Wufeng-Longmaxi marine shales from the
Strain induced molecular heterogeneity in ancient sedimentary organic matter mapped at nanoscales using optical photothermal infrared spectroscopy
Here we report ultra-high resolution infrared mapping of organic matter functional group distribution in Tasmanites (algal microfossils) from the Upper Devonian Ohio Shale using optical photothermal infrared spectroscopy (O-PTIR). O-PTIR is capable of rapidly measuring the vibrational response of samples in situ with ~500-nm spatial resolution, well below the infrared diffraction limit. Our result
Textural occurrence and organic porosity of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) to assess solid bitumen composition and porosity development as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1-103 days, 300-370°C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt. %] New
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize produced water
Filter Total Items: 37
Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse
Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concern
Authors
Aaron M. Jubb, Jenna L. Shelton, Bonnie McDevitt, Kaela K. Amundson, Amanda Sha Herzberg, Jessica Chenault, Andrew Laurence Masterson, Matthew S. Varonka, Glenn D. Jolly, Christina A. DeVera, Elliott Barnhart, Michael J. Wilkins, Madalyn S. Blondes
Evaluation of the lithium resource in the Smackover Formation brines of southern Arkansas using machine learning
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithiu
Authors
Katherine J. Knierim, Madalyn S. Blondes, Andrew Laurence Masterson, Philip A. Freeman, Bonnie McDevitt, Amanda Sha Herzberg, Peng Li, Ciara Mills, Colin A. Doolan, Aaron M. Jubb, Scott Ausbrooks, Jessica Chenault
Evaluation of coal mine drainage and associated precipitates for radium and rare earth element concentrations
Coal mine drainage (CMD) and associated metal-rich precipitates have recently been proposed as unconventional sources of rare earth elements (REEs). However, the potential occurrence of radium (Ra), a known carcinogen, with the REE-bearing phases has not been investigated. We hypothesized that Ra may occur in solids that are precipitated from CMD as a “radiobarite” solid solution ((Ba,Sr,Ra)SO4) a
Authors
Bonnie McDevitt, Charles A. III Cravotta, Ryan J. McAleer, John C Jackson, Aaron M. Jubb, Glenn D. Jolly, Benjamin C. Hedin, Nathaniel R. Warner
Ion exchange processes for CO2 mineralization using industrial waste streams: Pilot plant demonstration and life cycle assessment
An attractive technique for removing CO2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO2 (pH<4.5) and Ca2+ ions. In this study, a pH-swing process using ion exchange was demonstrated to process
Authors
Steven Bustillos, Mario Christofides, Bonnie McDevitt, Madalyn S. Blondes, Ryan J. McAleer, Aaron M. Jubb, Bu Wang, Gaurav Sant, Dante Simonetti
Cathodoluminescence differentiates sedimentary organic matter types
High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter is widely utilized in the geosciences for evaluating microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM methods, the inability of SEM to differentiate
Authors
Paul C. Hackley, Ryan J. McAleer, Aaron M. Jubb, Brett J. Valentine, Justin E. Birdwell
Deformation-induced graphitization and muscovite recrystallization in a ductile fault zone
A suite of slate samples collected along a 2 km transect crossing the Lishan fault in central Taiwan were evaluated to assess the role of ductile deformation in natural graphitization at lower greenschist facies metamorphic conditions. The process of natural aromatization, or graphitization, of an organic precursor is well established as a thermally driven process; however, experimental studies ha
Authors
Martha (Rebecca) Stokes, Aaron M. Jubb, Ryan J. McAleer, David Bish, Robert Wintsch
Insights into glendonite formation from the upper Oligocene Sagavanirktok Formation, North Slope, Alaska
The type locality for the upper Oligocene Nuwok Member of the Sagavanirktok Formation (Carter Creek, North Slope, Alaska, USA) contains abundant occurrence of glendonite, a pseudomorph after the calcium carbonate mineral ikaite, which typically forms in the shallow subsurface of cold marine sediments. The region during the time of Nuwok Member deposition was located at a high latitude, similar to
Authors
John W. Counts, Madeleine Vickers, Martha (Rebecca) Stokes, Whittney Spivey, Kristina Frank Gardner, Jean Self-Trail, Jared T. Gooley, Ryan J. McAleer, Aaron M. Jubb, David W. Houseknecht, Richard O. Lease, Neil Patrick Griffis, Martin S. Vickers, Kasia Śliwińska, Hannah Gail Dooley Tompkins, Adam M. Hudson
Evaluation of portable Raman spectroscopic analysis for source-rock thermal maturity assessments on bulk crushed rock
This study presents a simplified method and empirical relationships for determining organic matter thermal maturity using a portable Raman system equipped with a 785 nm laser, for analysis of crushed, whole-rock samples. Suites of rocks represented by shale and coal samples with various mineralogical composition, thermal maturity, and total organic carbon (TOC) were used to test the method and bui
Authors
Martha (Rebecca) Stokes, Aaron M. Jubb, Paul C. Hackley, Justin E. Birdwell, Elliott Barnhart, Clint Scott, Jenna L. Shelton, Margaret M. Sanders, Javin J. Hatcherian
Methane pore accessibility, densification, and accommodation by organic matter in the Niobrara Formation at wet-gas thermal maturity conditions
Petroleum within unconventional source-rock reservoirs is hosted in organic matter and mineral pore space as well as in voids and microfractures. Recent work has shown that for source-rock reservoirs in the dry gas window, significant portions of methane (CH4), the main component of petroleum at elevated maturities, can be stored within fine (<5 nm) organic matter porosity. However, within reservo
Authors
Aaron M. Jubb, Leslie F. Ruppert, Tristan G. A. Youngs, Tom Headen, Justin E. Birdwell, Michael Cheshire, Martha (Rebecca) Stokes
Thermal evolution of graptolite and solid bitumen properties at high maturity under natural and artificial conditions
To refine the use of graptolite and solid bitumen as thermal proxies at overmature conditions, we evaluated their evolution via Raman and infrared (IR) spectroscopies, reflectance, and geochemical screening using high-temperature pyrolysis experiments in comparison to naturally matured samples. Naturally matured samples included marine shales from the overmature Upper Ordovician Wufeng-Lower Silur
Authors
Jianyang Song, Paul C. Hackley, Margaret M. Sanders, Aaron M. Jubb, Qingyong Luo
Mapping ancient sedimentary organic matter molecular structure at nanoscales using optical photothermal infrared spectroscopy
Elucidating the molecular structure of sedimentary organic matter (SOM) is key to understanding petroleum generation processes, as well as ancient sedimentary environments. SOM structure is primarily controlled by biogenic source material (e.g., marine vs. terrigenous), depositional conditions, and subsurface thermal history. Additional factors, e.g., strain, may also impact the molecular structur
Authors
Aaron M. Jubb, Martha (Rebecca) Stokes, Ryan J. McAleer, Paul C. Hackley, Eoghan Dillion, Jing Qu
Relating systematic compositional variability to the textural occurrence of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) images to assess solid bitumen composition as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1–103 days, 300–370 °C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt%] New Albany Shale sample
Authors
Martha (Rebecca) Stokes, Brett J. Valentine, Aaron M. Jubb, Paul C. Hackley
*Disclaimer: Listing outside positions with professional scientific organizations on this Staff Profile are for informational purposes only and do not constitute an endorsement of those professional scientific organizations or their activities by the USGS, Department of the Interior, or U.S. Government