Standardization of Petrographic Thermal Indices
Advent of the shale revolution since about 2005 caused increased demand for reliable petrographic measurements of thermal maturity in shale via vitrinite reflectance, which has long been considered the gold standard approach. The first standardized methodology for vitrinite reflectance measurement in shale became available in 2011. Subsequent interlaboratory studies demonstrated that significant work remains to be done to improve measurement precision and further advances in the standardization and reliability of petrographic measurements of thermal maturity. Standardization efforts of this research task were recognized by bestowment of the 2019 Organic Petrology Award from the International Committee for Coal and Organic Petrology (ICCP).
Objective:
The overall objective of this research is to improve the standardization and reliability of petrographic measurements of thermal maturity, including reflectance and fluorescence of sedimentary organic matter.
Methodology:
One research goal is to develop a standard test method for quantitative spectroscopic measurement of fluorescence in sedimentary organic matter (SOM). This thermal maturity parameter is used on sedimentary organic matter (SOM) in the early- to mid-oil window. Absence of a standardized approach has resulted in poor interlaboratory agreement. Development of a standard test method will improve reporting and understanding of spectral fluorescence in SOM as well as improve the accuracy of the placement of continuous undiscovered oil and gas resource assessment boundaries, which may, in some cases, use the beginning of the oil window for spatial delineation.
Another research goal is to improve understanding of the effects of broad ion beam (BIB) milling on SOM. BIB milling is a common approach for sample preparation in scanning electron microscopy petrography. Poor understanding of BIB milling effects on SOM has prevented its adoption as a standardized preparation technique.
The third research goal is to develop improved classification schemes for environmental applications of organic petrology. The absence of uniform terminology and nomenclature in environmental applications results in multiple identifying terms for the same material, which interferes with scientific communication.
Listed below are other science projects or tasks associated with this project.
Petrographic Thermal Indices Research
Vitrinite Reflectance Service
Thermal Indices Innovation
Hydrous Pyrolysis and Kerogen Conversion
Listed below are data products associated with this project.
Reflectance and confocal laser scanning fluorescence spectroscopy of bituminite in Kimmeridge Clay
Investigating the effects of broad ion beam milling to sedimentary organic matter
Listed below are publications associated with this project.
Finalization of the Confocal Laser Scanning Microscopy (CLSM) working group
Identification of thermal maturity-relevant organic matter in Shale Working Group Report 2021
Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy
The Confocal Laser Scanning Microscopy Working Group of the ICCP: Final report 2021
A review of spatially resolved techniques and applications of organic petrography in shale petroleum systems
Investigating the effects of broad ion beam milling to sedimentary organic matter: Surface flattening or heat-induced aromatization and condensation?
Sample mounting for organic petrology: No thermal effects from transient exposure to elevated temperatures
Testing reproducibility of vitrinite and solid bitumen reflectance measurements in North American unconventional source-rock reservoir petroleum systems
Reflectance increase from broad beam ion milling of coals and organic-rich shales due to increased surface flatness
Listed below are online interactive applications associated with this project.
Photomicrograph Atlas
A database of images related to the characterization of fossil fuel resources in the United States and the world.
Advent of the shale revolution since about 2005 caused increased demand for reliable petrographic measurements of thermal maturity in shale via vitrinite reflectance, which has long been considered the gold standard approach. The first standardized methodology for vitrinite reflectance measurement in shale became available in 2011. Subsequent interlaboratory studies demonstrated that significant work remains to be done to improve measurement precision and further advances in the standardization and reliability of petrographic measurements of thermal maturity. Standardization efforts of this research task were recognized by bestowment of the 2019 Organic Petrology Award from the International Committee for Coal and Organic Petrology (ICCP).
Objective:
The overall objective of this research is to improve the standardization and reliability of petrographic measurements of thermal maturity, including reflectance and fluorescence of sedimentary organic matter.
Methodology:
One research goal is to develop a standard test method for quantitative spectroscopic measurement of fluorescence in sedimentary organic matter (SOM). This thermal maturity parameter is used on sedimentary organic matter (SOM) in the early- to mid-oil window. Absence of a standardized approach has resulted in poor interlaboratory agreement. Development of a standard test method will improve reporting and understanding of spectral fluorescence in SOM as well as improve the accuracy of the placement of continuous undiscovered oil and gas resource assessment boundaries, which may, in some cases, use the beginning of the oil window for spatial delineation.
Another research goal is to improve understanding of the effects of broad ion beam (BIB) milling on SOM. BIB milling is a common approach for sample preparation in scanning electron microscopy petrography. Poor understanding of BIB milling effects on SOM has prevented its adoption as a standardized preparation technique.
The third research goal is to develop improved classification schemes for environmental applications of organic petrology. The absence of uniform terminology and nomenclature in environmental applications results in multiple identifying terms for the same material, which interferes with scientific communication.
Listed below are other science projects or tasks associated with this project.
Petrographic Thermal Indices Research
Vitrinite Reflectance Service
Thermal Indices Innovation
Hydrous Pyrolysis and Kerogen Conversion
Listed below are data products associated with this project.
Reflectance and confocal laser scanning fluorescence spectroscopy of bituminite in Kimmeridge Clay
Investigating the effects of broad ion beam milling to sedimentary organic matter
Listed below are publications associated with this project.
Finalization of the Confocal Laser Scanning Microscopy (CLSM) working group
Identification of thermal maturity-relevant organic matter in Shale Working Group Report 2021
Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy
The Confocal Laser Scanning Microscopy Working Group of the ICCP: Final report 2021
A review of spatially resolved techniques and applications of organic petrography in shale petroleum systems
Investigating the effects of broad ion beam milling to sedimentary organic matter: Surface flattening or heat-induced aromatization and condensation?
Sample mounting for organic petrology: No thermal effects from transient exposure to elevated temperatures
Testing reproducibility of vitrinite and solid bitumen reflectance measurements in North American unconventional source-rock reservoir petroleum systems
Reflectance increase from broad beam ion milling of coals and organic-rich shales due to increased surface flatness
Listed below are online interactive applications associated with this project.
Photomicrograph Atlas
A database of images related to the characterization of fossil fuel resources in the United States and the world.