Critical Metals in Black Shales
Project objectives were to improve the understanding of critical mineral enrichment in black shales and improve accuracy of resource assessments.
Science Issue and Relevance
Black shales have been of increasing interest in recent years due to their oil and gas potential, but also because many are enriched in nonfuel "unconventional" critical elements such as cobalt, chromium, molybdenum, nickel, platinum group elements, rhenium, and vanadium. Critical metals residing in shales presented a challenge to economic recovery, and thus, development of deposits was "shelved" because metals could not be recovered by traditional methods. With recent advances in metals extraction, it may be feasible to mine these deposits.
Methodology to Address Issue
Re-assessing the potential for critical elements in shales is important and timely because of new analytical techniques and advances in extraction technology. The USGS is in a prime position to conduct a modern assessment of such deposits in the U.S. This requires compiling geologic, sedimentologic, geochemical, and isotopic data already available and collecting new data in selected areas. Project objectives were to improve the understanding of critical mineral enrichment in black shales and improve accuracy of resource assessments. The project consisted of three main tasks:
- Database development (to include age, host rock composition, tectonic/geologic setting, total organic carbon, rock evaluation, and other inorganic and organic chemical components;
- Identification of black shale-hosted critical element deposits in the U.S. (initial focus on the Heath Formation metalliferous oil shales in Montana); and
- Evaluation of processes that form metal-enriched black shale deposits.
Return to Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
Below are data or web applications associated with this project.
Global Geochemical Database for Critical Metals in Black Shales
Below are publications associated with this project.
Sulfur isotopes of host strata for Howards Pass (Yukon–Northwest Territories) Zn-Pb deposits implicate anaerobic oxidation of methane, not basin stagnation
The hyper-enrichment of V and Zn in black shales of the Late Devonian-Early Mississippian Bakken Formation (USA)
Transgressive-regressive cycles in the metalliferous, oil-shale-bearing Heath Formation (Upper Mississippian), central Montana
Geochemistry of host rocks in the Howards Pass district, Yukon-Northwest Territories, Canada: implications for sedimentary environments of Zn-Pb and phosphate mineralization
Re-Os systematics and age of pyrite associated with stratiform Zn-Pb mineralization in the Howards Pass district, Yukon and Northwest Territories, Canada
Depositional conditions for the Kuna Formation, Red Dog Zn-PB-Ag-Barite District, Alaska, inferred from isotopic and chemical proxies
Hydrothermal, biogenic, and seawater components in metalliferous black shales of the Brooks Range, Alaska: Synsedimentary metal enrichment in a carbonate ramp setting
Below are partners associated with this project.
Project objectives were to improve the understanding of critical mineral enrichment in black shales and improve accuracy of resource assessments.
Science Issue and Relevance
Black shales have been of increasing interest in recent years due to their oil and gas potential, but also because many are enriched in nonfuel "unconventional" critical elements such as cobalt, chromium, molybdenum, nickel, platinum group elements, rhenium, and vanadium. Critical metals residing in shales presented a challenge to economic recovery, and thus, development of deposits was "shelved" because metals could not be recovered by traditional methods. With recent advances in metals extraction, it may be feasible to mine these deposits.
Methodology to Address Issue
Re-assessing the potential for critical elements in shales is important and timely because of new analytical techniques and advances in extraction technology. The USGS is in a prime position to conduct a modern assessment of such deposits in the U.S. This requires compiling geologic, sedimentologic, geochemical, and isotopic data already available and collecting new data in selected areas. Project objectives were to improve the understanding of critical mineral enrichment in black shales and improve accuracy of resource assessments. The project consisted of three main tasks:
- Database development (to include age, host rock composition, tectonic/geologic setting, total organic carbon, rock evaluation, and other inorganic and organic chemical components;
- Identification of black shale-hosted critical element deposits in the U.S. (initial focus on the Heath Formation metalliferous oil shales in Montana); and
- Evaluation of processes that form metal-enriched black shale deposits.
Return to Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
Below are data or web applications associated with this project.
Global Geochemical Database for Critical Metals in Black Shales
Below are publications associated with this project.
Sulfur isotopes of host strata for Howards Pass (Yukon–Northwest Territories) Zn-Pb deposits implicate anaerobic oxidation of methane, not basin stagnation
The hyper-enrichment of V and Zn in black shales of the Late Devonian-Early Mississippian Bakken Formation (USA)
Transgressive-regressive cycles in the metalliferous, oil-shale-bearing Heath Formation (Upper Mississippian), central Montana
Geochemistry of host rocks in the Howards Pass district, Yukon-Northwest Territories, Canada: implications for sedimentary environments of Zn-Pb and phosphate mineralization
Re-Os systematics and age of pyrite associated with stratiform Zn-Pb mineralization in the Howards Pass district, Yukon and Northwest Territories, Canada
Depositional conditions for the Kuna Formation, Red Dog Zn-PB-Ag-Barite District, Alaska, inferred from isotopic and chemical proxies
Hydrothermal, biogenic, and seawater components in metalliferous black shales of the Brooks Range, Alaska: Synsedimentary metal enrichment in a carbonate ramp setting
Below are partners associated with this project.