The project objective is to develop and apply solution and in situ isotopic and trace element methods to emerging research opportunities to gain a better understanding of the processes controlling critical mineral deposits, metal mobility, and other geological inquiries.
Science Issue and Relevance
Critical minerals are essential for technology including green energy, defense, and communication, but our Nation is dependent on sources that may have potential supply chain disruptions. Identifying the sources of critical minerals and the chemical and physical processes that concentrate them is a primary objective of the Mineral Resources Program. This is a major task because it is a new focus in economic geology and a complex problem. To make significant strides towards this goal, innovative applied research techniques must be coupled with more traditional tools. Advancement in analytical capability beyond nontraditional stable isotopes has presented the opportunity to focus on specific analytical method development and application of high precision isotope ratio and trace metal measurements by laser ablation and solution introduction.
Methods to Address Issue
The project objective is to develop and apply solution and in situ isotopic and trace element methods that have emerging applications in understanding processes controlling critical mineral deposits, metal mobility, and other geological problems. We will use solution multicollector-inductively coupled plasma-mass spectrometry (MC-ICP-MS), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), and laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) expertise to develop precise and accurate simultaneous or stand-alone trace metal and isotope measurements and multiple solution isotope systematics. The significance of our new capability for in situ split flow measurements focuses on concurrent processes in otherwise complex systems. The project:
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provides new capabilities for constraining chemical and geological processes that influence mineral deposit formation,
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develops a better understanding of heavy metal mobilization, migration and pathways into the ecosystems and waterways,
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works in collaboration with existing projects to support USGS goals.
Project work is conducted through several tasks:
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Laboratory facility management
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High spatial resolution single and dual isotopic analyses determining chemical and geological processes related to ore deposit formation
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Trace metals, ligands and concurrent isotope ratios measurements in complex mineral systems of potentially strategic significance
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High precision solution isotope ratios for mineral deposit and metal transformation and mobility studies
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Assessing metal mobility and migration in ore deposits, waters, and abandoned mine areas
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Innovative isotopic applications to constraining ore-forming processes of REE deposits
Other USGS research projects related to our work
Non-Traditional Stable Isotopes
Systems Approach to Critical Minerals Inventory, Research, and Assessment
Macro and Micro Analytical Methods Development
Data releases from our project.
Strontium isotopic data from the Mount Emmons-Redwell area, Crested Butte, Colorado
Hg Concentrations of Fish Tissue Samples in the Vicinity of Yellow Pine, Idaho
Project publications.
Increased mercury and reduced insect diversity in linked stream-riparian food webs downstream of a historical mercury mine
Nanoscale isotopic evidence resolves origins of giant Carlin-type ore deposits
Lead speciation, bioaccessibility and source attribution in Missouri's Big River watershed
Assessing mercury distribution using isotopic fractionation of mercury processes and sources adjacent and downstream of a legacy mine district in Tuscany, Italy
Magmatic-hydrothermal gold mineralization at the Lone Tree Mine, Battle Mountain district, Nevada
Other partners in addition to the USGS New Mexico and New England Water Science Centers.
- Overview
The project objective is to develop and apply solution and in situ isotopic and trace element methods to emerging research opportunities to gain a better understanding of the processes controlling critical mineral deposits, metal mobility, and other geological inquiries.
Science Issue and Relevance
Nu Instruments NP3 model of Multi Collector ICP Mass Spectrometer (MC-ICP-MS), Denver High Resolution Laboratory. Critical minerals are essential for technology including green energy, defense, and communication, but our Nation is dependent on sources that may have potential supply chain disruptions. Identifying the sources of critical minerals and the chemical and physical processes that concentrate them is a primary objective of the Mineral Resources Program. This is a major task because it is a new focus in economic geology and a complex problem. To make significant strides towards this goal, innovative applied research techniques must be coupled with more traditional tools. Advancement in analytical capability beyond nontraditional stable isotopes has presented the opportunity to focus on specific analytical method development and application of high precision isotope ratio and trace metal measurements by laser ablation and solution introduction.
Methods to Address Issue
The project objective is to develop and apply solution and in situ isotopic and trace element methods that have emerging applications in understanding processes controlling critical mineral deposits, metal mobility, and other geological problems. We will use solution multicollector-inductively coupled plasma-mass spectrometry (MC-ICP-MS), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), and laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) expertise to develop precise and accurate simultaneous or stand-alone trace metal and isotope measurements and multiple solution isotope systematics. The significance of our new capability for in situ split flow measurements focuses on concurrent processes in otherwise complex systems. The project:
-
provides new capabilities for constraining chemical and geological processes that influence mineral deposit formation,
-
develops a better understanding of heavy metal mobilization, migration and pathways into the ecosystems and waterways,
-
works in collaboration with existing projects to support USGS goals.
Multi Collector ICP Mass Spectrometer (MC-ICP-MS) plasma shield upgrade between models NP2 to NP3 (Nu Instruments). Project work is conducted through several tasks:
-
Laboratory facility management
-
High spatial resolution single and dual isotopic analyses determining chemical and geological processes related to ore deposit formation
-
Trace metals, ligands and concurrent isotope ratios measurements in complex mineral systems of potentially strategic significance
-
High precision solution isotope ratios for mineral deposit and metal transformation and mobility studies
-
Assessing metal mobility and migration in ore deposits, waters, and abandoned mine areas
-
Innovative isotopic applications to constraining ore-forming processes of REE deposits
Laser ablation sport sizes: 65 µm, 35 µm, 10 µm, 5 µm, and 3 µm. The resolution approaches 3 micron resolution for sulfur isotope ratios measurements in sulfides. The short video is of a post laser ablation crater using a nanosecond 193nm laser ablation system of a glass slide using a 210 micron spot diameter and 250 shots. It shows a flat bottom crater indicative of a homogenized laser beam, though the measured diameter of the crater appears to be 25 microns smaller the diameter set. The 3D crater image was created using a Keyence 3D digital microscope. -
- Science
Other USGS research projects related to our work
Non-Traditional Stable Isotopes
Understanding the genesis of ore deposits and their behavior in the environment is a subject of great importance to the Nation. A relatively new tool to aid in these efforts to investigate the origin and environmental effects of ore deposits is the use of "heavy" metal stable isotopes. Our research objectives are to utilize various isotopic systems to advance our understanding of ore genesis and...Systems Approach to Critical Minerals Inventory, Research, and Assessment
This project supports the Earth Mapping Resources Initiative (EarthMRI) by developing a mineral systems approach for defining focus areas. This project is investigating domestic sources of critical minerals in three sequential stages: inventory, research, and assessment. 1) Inventory the abundance of critical minerals in ore, minerals, and processed materials from major deposits in each system...Macro and Micro Analytical Methods Development
The Macro and Micro Analytical Methods Development Project (MMAMD) provides access to the expertise of highly experienced research scientists and state of the art analytical instrumentation to develop new and unique analytical capabilities to solve complex problems beyond routine analysis. - Data
Data releases from our project.
Strontium isotopic data from the Mount Emmons-Redwell area, Crested Butte, Colorado
This U.S. Geological Survey (USGS) data release contains strontium isotopic data from water and rock samples collected between 2000 and 2019 from the Mount Emmons area, central Colorado. The data include strontium isotopic compositions, 87Sr/86Sr, for surface- and groundwater samples collected from streams, springs, draining mines, piezometers, and drill holes and for leachates of rock samples colHg Concentrations of Fish Tissue Samples in the Vicinity of Yellow Pine, Idaho
The USGS examined mercury (Hg) concentrations in fish populations inhabiting impacted and reference streams as part of an investigation into the transport of trace metals in a watershed impacted by legacy mercury mining downstream from the Cinnabar mine site, Valley County, ID. Fish were sampled through an electrofishing survey utilizing a two-pass quantitative depletion approach where possible. F - Publications
Project publications.
Increased mercury and reduced insect diversity in linked stream-riparian food webs downstream of a historical mercury mine
Historical mining left a legacy of abandoned mines and waste rock in remote headwaters of major river systems in the western United States. Understanding the influence of these legacy mines on culturally and ecological important downstream ecosystems is not always straight-forward because of elevated natural levels of mineralization in mining-impacted watersheds. To test the ecological effects ofAuthorsJohanna M. Kraus, JoAnn Holloway, Michael Pribil, Ben N. Mcgee, Craig A. Stricker, Danny Rutherford, Andrew S. ToddNanoscale isotopic evidence resolves origins of giant Carlin-type ore deposits
The western North American Great Basin's Carlin-type deposits represent the largest accumulation of gold in the Northern Hemisphere. The controversy over their origins echoes the debate between Neptunists and Plutonists at the birth of modern geology: were the causative processes meteoric or magmatic? Sulfur isotopes have long been considered key to decoding metal cycling in the Earth's crust, butAuthorsElizabeth A. Holley, Alexandria M Fulton, C Jilly-Rehak, Craig A. Johnson, Michael PribilLead speciation, bioaccessibility and source attribution in Missouri's Big River watershed
The Southeast Missouri Lead District is among the most productive lead deposits exploited in modern times. Intensive mining conducted prior to regulations resulted in a legacy of lead contaminated soil, large piles of mine tailings and elevated childhood blood lead levels. This study seeks to identify the source of the lead contamination in the Big River and inform risk to the public. Isotopic anaAuthorsMatthew Noerpel, Michael Pribil, Danny Rutherford, Preston Law, Karen Bradham, Clay Nelson, Rob Weber, Gene Gunn, Kirk G. ScheckelAssessing mercury distribution using isotopic fractionation of mercury processes and sources adjacent and downstream of a legacy mine district in Tuscany, Italy
Mercury (Hg) concentrations and isotopic compositions in a range of sample types collected from the legacy Abbadia San Salvatore Mine (ASSM) area were used to evaluate the distribution of Hg in the region. The district generated more than 100,000 metric tons of Hg releasing extensive amounts of gaseous Hg emissions and producing large amounts of mine waste calcine from which Hg can be mobilized iAuthorsMichael Pribil, Valentina Rimondi, Pilario Costagliola, Pierfranco Lattanzi, Danny RutherfordMagmatic-hydrothermal gold mineralization at the Lone Tree Mine, Battle Mountain district, Nevada
The Lone Tree deposit is located in the northern Battle Mountain mining district, Nevada. Prior to mine closure in 2006, Santa Fe Pacific Gold and Newmont produced 4.2 Moz of gold at an average grade of 2.06 g/t at Lone Tree, primarily from the N-S– to NNW-SSE–striking Wayne zone. The ore is located between the Roberts Mountain and Golconda thrusts in siliciclastic rocks of the Ordovician Valmy FoAuthorsElizabeth A. Holley, Justin Lowe, Craig A. Johnson, Michael Pribil - Partners
Other partners in addition to the USGS New Mexico and New England Water Science Centers.