When sulfurous, sulfuric, and nitric acids in polluted air and rain react with the calcite in marble and limestone, the calcite dissolves. In exposed areas of buildings and statues, we see roughened surfaces, removal of material, and loss of carved details. Stone surface material may be lost all over or only in spots that are more reactive.
You might expect that sheltered areas of stone buildings and monuments would not be affected by acid precipitation. However, sheltered areas on limestone and marble buildings and monuments show blackened crusts that have peeled off in some places, revealing crumbling stone beneath. This black crust is primarily composed of gypsum, a mineral that forms from the reaction between calcite, water, and sulfuric acid. Gypsum is soluble in water; although it can form anywhere on carbonate stone surfaces that are exposed to sulfur dioxide gas (SO2), it is usually washed away. It remains only on protected surfaces that are not directly washed by the rain.
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Can lakes near volcanoes become acidic enough to be dangerous to people and animals?
Yes. Crater lakes atop volcanoes are typically the most acid, with pH values as low as 0.1 (very strong acid). Normal lake waters, in contrast, have relatively neutral pH values near 7.0.The crater lake at El Chichon volcano in Mexico had a pH of 0.5 in 1983 and Mount Pinatubo's crater lake had a pH of 1.9 in 1992. The acid waters of these lakes are capable of causing burns to human skin but are...
How does mine drainage occur?
Mine drainage is surface water or groundwater that drains from an active or abandoned mine. In some cases, pyrite (an iron sulfide mineral) is exposed and reacts with air and water to form sulfuric acid and dissolved iron. Some or all of this iron can precipitate to form the red, orange, or yellow sediments in the bottom of streams containing mine drainage. The acid runoff further dissolves heavy...
Why does my drinking water look cloudy sometimes?
Once in a while you get a glass of water that looks cloudy; maybe milky is a better term. After a few seconds it miraculously clears up! The cloudiness is due to tiny air bubbles in the water. Like any bubbles, the air rises to the top of the water and goes into the air, clearing up the water. The water in the pipes coming into your house might be under a bit of pressure. This causes gases (air)...
What can cause our water to have an earthy odor or to smell like rotten eggs?
Naturally-occurring organic compounds are created when plant material decays in lakes and reservoirs. Those organic compounds frequently cause musty, earthy odors, especially toward the end of summer. The odors can be objectionable, but generally are not harmful to health. However, odors can be caused by other constituents as well, so you might want to call your local Health Department and mention...
Why are some lakes full of algae and thick plants?
Plants naturally grow in and around lakes, but sometimes lakes and ponds can get an overgrowth of plants, algae, or bacteria. In many cases, humans are responsible. Chemicals that are used on lawns and in agriculture (like nitrogen and potassium) wash into our water systems. Once there, plants and algae have a feast on this “food”. Sometimes overgrowths of cyanobacteria (called “blooms”) can make...
Why is our porcelain sink stained brown?
The brown stain is from a large amount of iron in your water. It is closely related to simple rust that you see on metal, which is iron oxide. Your water probably comes from groundwater that filtered through rocks containing iron-rich minerals on its way to the well. Learn more: Water Color USGS Drinking Water and Source Water Research
Famous building stones of our Nation's capital
National Acid Precipitation Assessment Program Report to Congress: An integrated assessment
Acid rain and our Nation's capital : a guide to effects on buildings and monuments
USGS Tracks Acid Rain
Acid rain weathering of Salem limestone; surface characterization of control material
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- FAQ
Can lakes near volcanoes become acidic enough to be dangerous to people and animals?
Yes. Crater lakes atop volcanoes are typically the most acid, with pH values as low as 0.1 (very strong acid). Normal lake waters, in contrast, have relatively neutral pH values near 7.0.The crater lake at El Chichon volcano in Mexico had a pH of 0.5 in 1983 and Mount Pinatubo's crater lake had a pH of 1.9 in 1992. The acid waters of these lakes are capable of causing burns to human skin but are...
How does mine drainage occur?
Mine drainage is surface water or groundwater that drains from an active or abandoned mine. In some cases, pyrite (an iron sulfide mineral) is exposed and reacts with air and water to form sulfuric acid and dissolved iron. Some or all of this iron can precipitate to form the red, orange, or yellow sediments in the bottom of streams containing mine drainage. The acid runoff further dissolves heavy...
Why does my drinking water look cloudy sometimes?
Once in a while you get a glass of water that looks cloudy; maybe milky is a better term. After a few seconds it miraculously clears up! The cloudiness is due to tiny air bubbles in the water. Like any bubbles, the air rises to the top of the water and goes into the air, clearing up the water. The water in the pipes coming into your house might be under a bit of pressure. This causes gases (air)...
What can cause our water to have an earthy odor or to smell like rotten eggs?
Naturally-occurring organic compounds are created when plant material decays in lakes and reservoirs. Those organic compounds frequently cause musty, earthy odors, especially toward the end of summer. The odors can be objectionable, but generally are not harmful to health. However, odors can be caused by other constituents as well, so you might want to call your local Health Department and mention...
Why are some lakes full of algae and thick plants?
Plants naturally grow in and around lakes, but sometimes lakes and ponds can get an overgrowth of plants, algae, or bacteria. In many cases, humans are responsible. Chemicals that are used on lawns and in agriculture (like nitrogen and potassium) wash into our water systems. Once there, plants and algae have a feast on this “food”. Sometimes overgrowths of cyanobacteria (called “blooms”) can make...
Why is our porcelain sink stained brown?
The brown stain is from a large amount of iron in your water. It is closely related to simple rust that you see on metal, which is iron oxide. Your water probably comes from groundwater that filtered through rocks containing iron-rich minerals on its way to the well. Learn more: Water Color USGS Drinking Water and Source Water Research
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Famous building stones of our Nation's capital
The buildings of our Nation's Capital are constructed with rocks from quarries located throughout the United States and many distant lands. The earliest Government buildings, however, were constructed with stones from nearby sources because it was too difficult and expensive to move heavy materials such as stone any great distance without the aid of modern transportation methods, including large cAuthorsNational Acid Precipitation Assessment Program Report to Congress: An integrated assessment
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No abstract available.AuthorsElaine S. McGeeUSGS Tracks Acid Rain
The U.S. Geological Survey (USGS) has been actively studying acid rain for the past 15 years. When scientists learned that acid rain could harm fish, fear of damage to our natural environment from acid rain concerned the American public. Research by USGS scientists and other groups began to show that the processes resulting in acid rain are very complex. Scientists were puzzled by the fact that inAuthorsJohn D. Gordon, Mark A. Nilles, LeRoy J. SchroderAcid rain weathering of Salem limestone; surface characterization of control material
No abstract available.AuthorsV.G. Mossotti, J.R. Lindsay, M.F. Hochella - News