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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4098

A method to estimate groundwater depletion from confining layers A method to estimate groundwater depletion from confining layers

Although depletion of storage in low‐permeability confining layers is the source of much of the groundwater produced from many confined aquifer systems, it is all too frequently overlooked or ignored. This makes effective management of groundwater resources difficult by masking how much water has been derived from storage and, in some cases, the total amount of water that has been...
Authors
Leonard F. Konikow, Christopher E. Neuzil

Identifying sources of nitrogen to Hanalei Bay, Kauai, utilizing the nitrogen isotope signature of macroalgae Identifying sources of nitrogen to Hanalei Bay, Kauai, utilizing the nitrogen isotope signature of macroalgae

Sewage effluent, storm runoff, discharge from polluted rivers, and inputs of groundwater have all been suggested as potential sources of land derived nutrients into Hanalei Bay, Kauai. We determined the nitrogen isotopic signatures (δ15N) of different nitrate sources to Hanalei Bay along with the isotopic signature recorded by 11 species of macroalgal collected in the Bay. The macroalgae...
Authors
E. Derse, K.L. Knee, Scott D. Wankel, Carol Kendall, Carl J. Berg, A. Paytan

The oxygen-18 isotope approach for measuring aquatic metabolism in high-productivity waters The oxygen-18 isotope approach for measuring aquatic metabolism in high-productivity waters

We examined the utility of δ18O2 measurements in estimating gross primary production (P), community respiration (R), and net metabolism (P : R) through diel cycles in a productive agricultural stream located in the midwestern U.S.A. Large diel swings in O2(±200 µmol L−1) were accompanied by large diel variation in δ18O2 (±10‰). Simultaneous gas transfer measurements and laboratory...
Authors
Craig R. Tobias, John Karl Bohlke, Judson W. Harvey

Modeling the movement of a pH perturbation and its impact on adsorbed zinc and phosphate in a wastewater‐contaminated aquifer Modeling the movement of a pH perturbation and its impact on adsorbed zinc and phosphate in a wastewater‐contaminated aquifer

[1] Chemical conditions were perturbed in an aquifer with an ambient pH of 5.9 and wastewater-derived adsorbed zinc (Zn) and phosphate (P) contamination by injecting a pulse of amended groundwater. The injected groundwater had low concentrations of dissolved Zn and P, a pH value of 4.5 resulting from equilibration with carbon dioxide gas, and added potassium bromide (KBr). Downgradient...
Authors
Douglas B. Kent, J.A. Wilkie, J.A. Davis

Biological effects of anthropogenic contaminants in the San Francisco Estuary Biological effects of anthropogenic contaminants in the San Francisco Estuary

Concentrations of many anthropogenic contaminants in the San Francisco Estuary exist at levels that have been associated with biological effects elsewhere, so there is a potential for them to cause biological effects in the Estuary. The purpose of this paper is to summarize information about biological effects on the Estuary's plankton, benthos, fish, birds, and mammals, gathered since...
Authors
B. Thompson, T. Adelsbach, Cynthia L. Brown, J. Hunt, James S. Kuwabara, J. Neale, H. Ohlendorf, Steven E. Schwarzbach, R. Spies, K. Taberski

Efficiency of conventional drinking-water-treatment processes in removal of pharmaceuticals and other organic compounds Efficiency of conventional drinking-water-treatment processes in removal of pharmaceuticals and other organic compounds

Samples of water and sediment from a conventional drinking-water-treatment (DWT) plant were analyzed for 113 organic compounds (OCs) that included pharmaceuticals, detergent degradates, flame retardants and plasticizers, polycyclic aromatic hydrocarbons (PAHs), fragrances and flavorants, pesticides and an insect repellent, and plant and animal steroids. 45 of these compounds were...
Authors
Paul E. Stackelberg, Jacob Gibs, Edward T. Furlong, Michael T. Meyer, Steven D. Zaugg, R.L. Lippincott

Reconstructing sediment age profiles from historical bathymetry changes in San Pablo Bay, California Reconstructing sediment age profiles from historical bathymetry changes in San Pablo Bay, California

Sediment age profiles reconstructed from a sequence of historical bathymetry changes are used to investigate the subsurface distribution of historical sediments in a subembayment of the San Francisco Estuary. Profiles are created in a grid-based GIS modeling program that stratifies historical deposition into temporal horizons. The model's reconstructions are supported by comparisons to...
Authors
Shawn A. Higgins, Bruce E. Jaffe, Christopher C. Fuller

Groundwater flow with energy transport and water-ice phase change: Numerical simulations, benchmarks, and application to freezing in peat bogs Groundwater flow with energy transport and water-ice phase change: Numerical simulations, benchmarks, and application to freezing in peat bogs

In northern peatlands, subsurface ice formation is an important process that can control heat transport, groundwater flow, and biological activity. Temperature was measured over one and a half years in a vertical profile in the Red Lake Bog, Minnesota. To successfully simulate the transport of heat within the peat profile, the U.S. Geological Survey's SUTRA computer code was modified...
Authors
J.M. McKenzie, Clifford I. Voss, D. I. Siegel

Quasi-horizontal circulation cells in 3D seawater intrusion Quasi-horizontal circulation cells in 3D seawater intrusion

The seawater intrusion process is characterized by the difference in freshwater and seawater density that causes freshwater to float on seawater. Many confined aquifers have a large horizontal extension with respect to thickness. In these cases, while buoyancy acts in the vertical direction, flow is confined between the upper and bottom boundaries and the effect of gravity is controlled...
Authors
E. Abarca, J. Carrera, X. Sanchez-Vila, Clifford I. Voss

Evidence of CFC degradation in groundwater under pyrite-oxidizing conditions Evidence of CFC degradation in groundwater under pyrite-oxidizing conditions

A detailed local-scale monitoring network was used to assess CFC distribution in an unconfined sand aquifer in southwestern Ontario where the zone of 1–5-year-old groundwater was known with certainty because of prior use of a bromide tracer. Groundwater ⩽5 years old was confined to an aerobic zone at ⩽5 m depth and had CFC concentrations consistent with modern atmospheric mixing ratios...
Authors
L.A. Sebol, W.D. Robertson, Eurybiades Busenberg, Niel Plummer, M.C. Ryan, S.L. Schiff

Simple predictions of maximum transport rate in unsaturated soil and rock Simple predictions of maximum transport rate in unsaturated soil and rock

In contrast with the extreme variability expected for water and contaminant fluxes in the unsaturated zone, evidence from 64 field tests of preferential flow indicates that the maximum transport speed Vmax, adjusted for episodicity of infiltration, deviates little from a geometric mean of 13 m/d. A model based on constant‐speed travel during infiltration pulses of actual or estimated...
Authors
John R. Nimmo

Arsenic attenuation by oxidized aquifer sediments in Bangladesh Arsenic attenuation by oxidized aquifer sediments in Bangladesh

Recognition of arsenic (As) contamination of shallow fluvio-deltaic aquifers in the Bengal Basin has resulted in increasing exploitation of groundwater from deeper aquifers that generally contain low concentrations of dissolved As. Pumping-induced infiltration of high-As groundwater could eventually cause As concentrations in these aquifers to increase. This study investigates the...
Authors
Kenneth G. Stollenwerk, George N. Breit, Alan H. Welch, James C. Yount, John W. Whitney, Andrea L. Foster, M.N. Uddin, R.K. Majumder, N. Ahmed
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