Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 4098
In situ hydrogen consumption kinetics as an indicator of subsurface microbial activity In situ hydrogen consumption kinetics as an indicator of subsurface microbial activity
There are few methods available for broadly assessing microbial community metabolism directly within a groundwater environment. In this study, hydrogen consumption rates were estimated from in situ injection/withdrawal tests conducted in two geochemically varying, contaminated aquifers as an approach towards developing such a method. The hydrogen consumption first-order rates varied from...
Authors
S.H. Harris, Richard L. Smith, Joseph M. Suflita
Effects of intraborehole flow on groundwater age distribution Effects of intraborehole flow on groundwater age distribution
Environmental tracers are used to estimate groundwater ages and travel times, but the strongly heterogeneous nature of many subsurface environments can cause mixing between waters of highly disparate ages, adding additional complexity to the age-estimation process. Mixing may be exacerbated by the presence of wells because long open intervals or long screens with openings at multiple...
Authors
B.A. Zinn, Leonard F. Konikow
Characterizing dissolved Cu and Cd uptake in terms of the biotic ligand and biodynamics using enriched stable isotopes Characterizing dissolved Cu and Cd uptake in terms of the biotic ligand and biodynamics using enriched stable isotopes
The biotic ligand model considers the biological and geochemical complexities that affect metal exposure. It relates toxicity to the fraction of physiological active sites impacted by reactive metal species. The biodynamic model is a complementary construct that predicts bioaccumulation and assumes that toxicity occurs when influx rates exceed rates of loss and detoxification. In this...
Authors
Marie Noele Croteau, Samuel N. Luoma
Determining metal assimilation efficiency in aquatic invertebrates using enriched stable metal isotope tracers Determining metal assimilation efficiency in aquatic invertebrates using enriched stable metal isotope tracers
We employ a novel approach that combines pulse-chase feeding and multi-labelled stable isotopes to determine gut passage time (GPT), gut retention time (GRT), food ingestion rate (IR) and assimilation efficiency (AE) of three trace elements for a freshwater gastropod. Lettuce isotopically enriched in 53Cr, 65Cu and 106Cd was fed for 2 h to Lymnaea stagnalis. The release of tracers in...
Authors
Marie Noele Croteau, Samuel N. Luoma, B. Pellet
Role of hydrous iron oxide formation in attenuation and diel cycling of dissolved trace metals in a stream affected by acid rock drainage Role of hydrous iron oxide formation in attenuation and diel cycling of dissolved trace metals in a stream affected by acid rock drainage
Mining-impacted streams have been shown to undergo diel (24-h) fluctuations in concentrations of major and trace elements. Fisher Creek in south-central Montana, USA receives acid rock drainage (ARD) from natural and mining-related sources. A previous diel field study found substantial changes in dissolved metal concentrations at three sites with differing pH regimes during a 24-h period...
Authors
Stephen R. Parker, Chris Gammons, Clain A. Jones, David A. Nimick
Hydrologic significance of carbon monoxide concentrations in ground water Hydrologic significance of carbon monoxide concentrations in ground water
Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 μg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured‐bedrock aquifer in West Trenton, New Jersey, long‐term monitoring showed that CO...
Authors
Francis H. Chapelle, Paul M. Bradley
Freshwater-saltwater transition zone movement during aquifer storage and recovery cycles in Brooklyn and Queens, New York City, USA Freshwater-saltwater transition zone movement during aquifer storage and recovery cycles in Brooklyn and Queens, New York City, USA
Freshwater storage in deep aquifers of Brooklyn and Queens, New York, USA, is under consideration as an emergency water supply for New York City. The purpose of a New York City storage and recovery system is to provide an emergency water supply during times of drought or other contingencies and would entail longer-term storage phases than a typical annual cycle. There is concern amongst
Authors
Paul E. Misut, Clifford I. Voss
Role of chemotaxis in the transport of bacteria through saturated porous media Role of chemotaxis in the transport of bacteria through saturated porous media
Populations of chemotactic bacteria are able to sense and respond to chemical gradients in their surroundings and direct their migration toward increasing concentrations of chemicals that they perceive to be beneficial to their survival. It has been suggested that this phenomenon may facilitate bioremediation processes by bringing bacteria into closer proximity to the chemical...
Authors
R.M. Ford, Ronald W. Harvey
Formation of mixed Al-Fe colloidal sorbent and dissolved-colloidal partitioning of Cu and Zn in the Cement Creek - Animas River Confluence, Silverton, Colorado Formation of mixed Al-Fe colloidal sorbent and dissolved-colloidal partitioning of Cu and Zn in the Cement Creek - Animas River Confluence, Silverton, Colorado
Transport and chemical transformations of dissolved and colloidal Al, Fe, Cu and Zn were studied by detailed sampling in the mixing zone downstream from the confluence of Cement Creek (pH 4.1) with the Animas River (pH 7.6). Complete mixing resulted in circumneutral pH in the downstream reach of the 1300 m study area. All four metals were transported through this mixing zone without...
Authors
Laurence E. Schemel, Briant A. Kimball, Robert L. Runkel, Marisa H. Cox
Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream
The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by ~30% and is accompanied by net loss of channel discharge and extensive surface–subsurface...
Authors
C.R. Ruehl, A.T. Fisher, Huertos M. Los, Scott D. Wankel, C.G. Wheat, Carol Kendall, C.E. Hatch, C. Shennan
Integrated investigations of environmental effects of historical mining in the Animas River Watershed, San Juan County, Colorado Integrated investigations of environmental effects of historical mining in the Animas River Watershed, San Juan County, Colorado
This publication comprises a Volume Contents of chapters (listed below) and a CD-ROM of data (contents shown in column at right). The Animas River watershed in southwest Colorado is one of many watersheds in the western United States where historical mining has left a legacy of acid mine drainage and elevated concentrations of potentially toxic trace elements in surface streams. U.S...
Reproductive responses of male fathead minnows exposed to wastewater treatment plant effluent, effluent treated with XAD8 resin, and an environmentally relevant mixture of alkylphenol compounds Reproductive responses of male fathead minnows exposed to wastewater treatment plant effluent, effluent treated with XAD8 resin, and an environmentally relevant mixture of alkylphenol compounds
On-site, continuous-flow experiments were conducted during August and October 2002 at a major metropolitan wastewater treatment plant (WWTP) to determine if effluent exposure induced endocrine disruption as manifested in the reproductive competence of sexually mature male fathead minnows (Pimephales promelas). The fathead minnows were exposed in parallel experiments to WWTP effluent and...
Authors
Larry B. Barber, Kathy Lee, Deborah L. Swackhamer, Heiko L. Schoenfuss