Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 4098
The interaction of natural organic matter with iron in a wetland (Tennessee Park, Colorado) receiving acid mine drainage The interaction of natural organic matter with iron in a wetland (Tennessee Park, Colorado) receiving acid mine drainage
Pore water from a wetland receiving acid mine drainage was studied for its iron and natural organic matter (NOM) geochemistry on three different sampling dates during summer 1994. Samples were obtained using a new sampling technique that is based on screened pipes of varying length (several centimeters), into which dialysis vessels can be placed and that can be screwed together to allow...
Authors
Stefan Peiffer, Katherine Walton-Day, Donald L. Macalady
Geochemical heterogeneity of a gasoline-contaminated aquifer Geochemical heterogeneity of a gasoline-contaminated aquifer
The scale of biogeochemical reactions was studied in a physically and chemically heterogeneous surficial Coastal Plain aquifer contaminated by a gasoline spill. The physical heterogeneity of the aquifer is manifested in two hydrologic units, a shallow local aquifer of perched water and a regional sandy aquifer. Over the studied vertical interval of 21.3 ft (6.5 m), concentrations of...
Authors
Isabelle M. Cozzarelli, Janet S. Herman, Mary Jo Baedecker, Jeffrey M. Fischer
Seasonal and annual load of herbicides from the Mississippi River Basin to the Gulf of Mexico Seasonal and annual load of herbicides from the Mississippi River Basin to the Gulf of Mexico
Water samples collected from rivers in the Mississippi River Basin were analyzed for selected herbicides to evaluate their discharge to the Gulf of Mexico and to identify their predominant source areas within the basin. Samples were collected from the Mississippi River at Baton Rouge, LA from 1991 to 1997 and from sites on the upper Mississippi, the Missouri, and the Ohio Rivers from...
Authors
G. M. Clark, D. A. Goolsby, W.A. Battaglin
Bacteriophage PRD1 and silica colloid transport and recovery in an iron oxide-coated sand aquifer Bacteriophage PRD1 and silica colloid transport and recovery in an iron oxide-coated sand aquifer
Bacteriophage PRD1 and silica colloids were co-injected into sewage-contaminated and uncontaminated zones of an iron oxide-coated sand aquifer on Cape Cod, MA, and their transport was monitored over distances up to 6 m in three arrays. After deposition, the attached PRD1 and silica colloids were mobilized by three different chemical perturbations (elevated pH, anionic surfactant, and...
Authors
J. N. Ryan, M. Elimelech, R.A. Ard, R.W. Harvey, P.R. Johnson
Movement of road salt to a small New Hampshire lake Movement of road salt to a small New Hampshire lake
Runoff of road salt from an interstate highway in New Hampshire has led to contamination of a lake and a stream that flows into the lake, in spite of the construction of a diversion berm to divert road salt runoff out of the lake drainage basin. Chloride concentration in the stream has increased by over an order of magnitude during the 23 yr since the highway was opened, and chloride...
Authors
D.O. Rosenberry, P.A. Bukaveckas, D.C. Buso, G.E. Likens, A.M. Shapiro, T. C. Winter
The relationship between soil heterotrophic activity, soil dissolved organic carbon (DOC) leachate, and catchment-scale DOC export in headwater catchments The relationship between soil heterotrophic activity, soil dissolved organic carbon (DOC) leachate, and catchment-scale DOC export in headwater catchments
Dissolved organic carbon (DOC) from terrestrial sources forms the major component of the annual carbon budget in many headwater streams. In high-elevation catchments in the Rocky Mountains, DOC originates in the upper soil horizons and is flushed to the stream primarily during spring snowmelt. To identify controls on the size of the mobile soil DOC pool available to be transported during...
Authors
P. D. Brooks, Diane M. McKnight, K.E. Bencala
Distribution and transport of selected anthropogenic lipophilic organic compounds associated with Mississippi River suspended sediment, 1989-1990 Distribution and transport of selected anthropogenic lipophilic organic compounds associated with Mississippi River suspended sediment, 1989-1990
In the first study on this scale, distribution and transport of selected hydrophobic halogenated organic compounds associated with suspended sediment from the lower Mississippi River and its principal tributaries were determined during two spring and two summer cruises. Lipophilic organic compounds identified on the suspended sediment included hexachlorobenzene, pentachlorobenzene
Authors
C.E. Rostad, W. E. Pereira, T.J. Leiker
Oxidation of ammonia and methane in an alkaline, saline lake Oxidation of ammonia and methane in an alkaline, saline lake
The oxidation of ammonia (NH3) and methane (CH4) was investigated in an alkaline saline lake, Mono Lake, California (U.S.A.). Ammonia oxidation was examined in April and July 1995 by comparing dark 14CO2 fixation rates in the presence or absence of methyl fluoride (MeF), an inhibitor of NH3 oxidation. Ammonia oxidizer‐mediated dark 14CO2fixation rates were similar in surface (5–7 m) and...
Authors
S.B. Joye, T.L. Connell, L.G. Miller, R.S. Oremland, R.S. Jellison
Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater
The atmosphere as a source of volatile organic compounds (VOCs) in shallow groundwater was evaluated over an area in southern New Jersey. Chloroform, methyl tertbutyl ether (MTBE), 1,1,1‐trichloroethane, tetrachloroethylene (PCE), and carbon disulfide (not a VOC) were detected frequently at low‐level concentrations in a network of 78 shallow wells in the surficial Kirkwood‐Cohansey...
Authors
Arthur L. Baehr, Paul E. Stackelberg, Ronald J. Baker
Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms
Microorganisms indigenous to the stream-bed sediments at two gasoline- contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-14C]-MTBE and 84% of [U-14C]-TBA were degraded to 14CO2 under mixed aerobic/anaerobic conditions. No significant mineralization was observed under...
Authors
P. M. Bradley, J. E. Landmeyer, F. H. Chapelle
Metolachlor and its metabolites in tile drain and stream runoff in the canajoharie creek watershed Metolachlor and its metabolites in tile drain and stream runoff in the canajoharie creek watershed
Water samples collected during April−November 1997 from tile drains beneath cultivated fields in central New York indicate that two metabolites of the herbicide metolachlormetolachlor ESA (ethanesulfonic acid) and OA (oxanilic acid)can persist in agricultural soils for 4 or more years after application and that fine-grained soils favor the transport of metolachlor ESA over metolachlor...
Authors
P. J. Phillips, G. R. Wall, E.M. Thurman, D. A. Eckhardt, J. Vanhoesen
Historical trends of metals in the sediments of San Francisco Bay, California Historical trends of metals in the sediments of San Francisco Bay, California
Concentrations of Ag, Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn were determined in six sediment cores from San Francisco Bay (SFB) and one sediment core in Tomales Bay (TB), a reference estuary. SFB cores were collected from between the head of the estuary and its mouth (Grizzly Bay, GB; San Pablo Bay, SP; Central Bay, CB; Richardson Bay, RB, respectively) and ranged in length from 150 to...
Authors
Michelle I. Hornberger, S. N. Luoma, A. VanGeen, C. Fuller, R. Anima