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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4098

Potential for intrinsic bioremediation of a DNT-contaminated aquifer Potential for intrinsic bioremediation of a DNT-contaminated aquifer

Microorganisms indigenous to a shallow aquifer, which underlies an explosives-contaminated site, mineralized 28% of [U-ring-14C] 2,4–dinitrotoluene to 14CO2 within 28 days under aerobic conditions. Approximately 20% of added 2,4–dinitrotoluene remained undegraded at the end of the incubation while approximately 22% and 6% were transformed to 4–amino-2–nitrotoluene and 2–amino-4...
Authors
P. M. Bradley, F. H. Chapelle, J. E. Landmeyer, J.G. Schumacher

Effect of flagellates on free-living bacterial abundance in an organically contaminated aquifer Effect of flagellates on free-living bacterial abundance in an organically contaminated aquifer

Little is known about the role of protists in the saturated subsurface. Porous media microcosms containing bacteria and protists, were used to determine whether flagellates from an organically contaminated aquifer could substantively affect the number of free- living bacteria (FLB). When flagellates were present, the 3-40% maximum breakthrough of fluorescent y labelled FLB injected into...
Authors
N.E. Kinner, R.W. Harvey, M. Kazmierkiewicz-Tabaka

Nuclear magnetic resonance identification of new sulfonic acid metabolites of chloroacetanilide herbicides Nuclear magnetic resonance identification of new sulfonic acid metabolites of chloroacetanilide herbicides

The detection of the sulfonic acid metabolites of the chloroacetanilide herbicides acetochlor, alachlor, butachlor, propachlor, and, more recently, metolachlor in surface and ground water suggests that a common mechanism for dechlorination exists via the glutathione conjugation pathway. The identification of these herbicides and their metabolites is important due to growing public...
Authors
M.D. Morton, F.H. Walters, D.S. Aga, E.M. Thurman, C.K. Larive

Historical trends in organochlorine compounds in river basins identified using sediment cores from reservoirs Historical trends in organochlorine compounds in river basins identified using sediment cores from reservoirs

This study used chemical analyses of dated sediment cores from reservoirs to define historical trends in water quality in the influent river basins. This work applies techniques from paleolimnology to reservoirs, and in the process, highlights differences between sediment-core interpretations for reservoirs and natural lakes. Sediment cores were collected from six reservoirs in the...
Authors
P. C. Van Metre, E. Callender, C. C. Fuller

Multiphase flow modeling of a crude-oil spill site with a bimodal permeability distribution Multiphase flow modeling of a crude-oil spill site with a bimodal permeability distribution

Fluid saturation, particle-size distribution, and porosity measurements were obtained from 269 core samples collected from six boreholes along a 90-m transect at a subregion of a crude-oil spill site, the north pool, near Bemidji, Minnesota. The oil saturation data, collected 11 years after the spill, showed an irregularly shaped oil body that appeared to be affected by sediment spatial
Authors
Leslie A. Dillard, Hedeff I. Essaid, William N. Herkelrath

Constant-concentration boundary condition: Lessons from the HYDROCOIN variable-density groundwater benchmark problem Constant-concentration boundary condition: Lessons from the HYDROCOIN variable-density groundwater benchmark problem

In a solute-transport model, if a constant-concentration boundary condition is applied at a node in an active flow field, a solute flux can occur by both advective and dispersive processes. The potential for advective release is demonstrated by reexamining the Hydrologic Code Intercomparison (HYDROCOIN) project case 5 problem, which represents a salt dome overlain by a shallow...
Authors
Leonard F. Konikow, W. E. Sanford, P.J. Campbell

Relation of hydrogeologic characteristics to distribution of radioactivity in ground water, Newark Basin, New Jersey Relation of hydrogeologic characteristics to distribution of radioactivity in ground water, Newark Basin, New Jersey

The distribution of radioactivity in ground water in the Newark Basin is controlled by the lithology of the aquifer and the degree of contact between the water that flows through the fractured strata and the radioactive lithologic units. The primary water-bearing lithologic units of the Newark Basin that contain elevated levels of radioactivity are the arkosic sandstones of the Stockton...
Authors
Zoltan Szabo, Ticie A. Taylor, Dorothy F. Payne, Tamara Ivahnenko

Statistical modeling of agricultural chemical occurrence in midwestern rivers Statistical modeling of agricultural chemical occurrence in midwestern rivers

Agricultural chemicals in surface water may constitute a human health risk or have adverse effects on aquatic life. Recent research on unregulated rivers in the midwestern USA documents that elevated concentrations of herbicides occur for 1-4 months following application in late spring and early summer. In contrast, nitrate concentrations in unregulated rivers are elevated during fall...
Authors
W.A. Battaglin, D. A. Goolsby

Occurrence of selected herbicides and herbicide degradation products in Iowa's Ground Water, 1995 Occurrence of selected herbicides and herbicide degradation products in Iowa's Ground Water, 1995

Herbicide compounds were prevalent in ground water across Iowa, being detected in 70% of the 106 municipal wells sampled during the summer of 1995. Herbicide degradation products were three of the four most frequently detected compounds for this study. The degradation product alachlor ethanesulfonic acid was the most frequently detected compound (65.1%), followed by atrazine (40.6%), and...
Authors
D.W. Kolpin, S. J. Kalkhoff, D. A. Goolsby, D. A. Sneck-Fahrer, E.M. Thurman

Practical considerations for measuring hydrogen concentrations in groundwater Practical considerations for measuring hydrogen concentrations in groundwater

Several practical considerations for measuring concentrations of dissolved molecular hydrogen (H2) in groundwater including 1 sampling methods 2 pumping methods and (3) effects of well casing materials were evaluated. Three different sampling methodologies (a downhole sampler, a gas- stripping method, and a diffusion sampler) were compared. The downhole sampler and gas-stripping methods...
Authors
F. H. Chapelle, D.A. Vroblesky, J.C. Woodward, Derek R. Lovley

Physiological considerations in applying laboratory-determined buoyant densities to predictions of bacterial and protozoan transport in groundwater: Results of in-situ and laboratory tests Physiological considerations in applying laboratory-determined buoyant densities to predictions of bacterial and protozoan transport in groundwater: Results of in-situ and laboratory tests

Buoyant densities were determined for groundwater bacteria and microflagellates (protozoa) from a sandy aquifer (Cape Cod, MA) using two methods:  (1) density-gradient centrifugation (DGC) and (2) Stoke's law approximations using sedimentation rates observed during natural-gradient injection and recovery tests. The dwarf (average cell size, 0.3 μm), unattached bacteria inhabiting a...
Authors
R.W. Harvey, D.W. Metge, N. Kinner, N. Mayberry
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