Publications

Solute transport simulations quantitatively constrained hydrologic and geochemical hypotheses about field observations of a pH modification in an acid mine drainage stream. Carbonate chemistry, the formation of solid phases, and buffering interactions with the stream bed were important factors in explaining the behavior of pH, aluminum, and iron. The precipitation of microcrystalline...

Over 100 samples were collected off the west coast of North America during 1991–1993 to determine the relation between wind‐driven upwelling and nearshore concentrations of dissolved silicate (Si), phosphate (P), and cadmium (Cd). Highly enriched in deep water offshore, these constituents are sensitive indicators of upwelling. Coastal water was sampled from the shore in January and June...

Seleniferous agricultural drainage wastewater has become a new major source of pollution in the world. In the USA, large areas of farmland in 17 western states, generate contaminated salinized drainage with Se concentrations much higher than 5 ??g/l, the US Environmental Protection Agency water-quality criterion for the protection of aquatic life; Se values locally reach 4200 ??g/l in...

A series of downhole and surface water samples were taken from the 1‐km‐deep KP‐1 borehole located on the eastern flank of the island of Hawaii. Early samples from depths of more than 700 m showed salinities nearly equivalent to seawater but having anomalous cation concentrations that are attributed to ion exchange between formation fluids and residual drilling mud clays. Later deep...

Data are presented on long-term salinity behaviour in San Francisco Bay, California. A two-level, width averaged model of the tidally averaged salinity and circulation has been written in order to interpret the long-term (days to decades) salinity variability. The model has been used to simulate daily averaged salinity in the upper and lower levels of a 51 segment discretization of the...

Alachlor and its metabolite, 2-[(2',6'-diethylphenyl)- (methoxymethyl)amino]-2-oxoethanesulfonate (ESA), were identified in 76 reservoirs in the midwestern United States using immunoassay, liquid chromatography, and gas chromatography/mass spectrometry. The median concentration of ESA (0.48 ??g/L) exceeded the median concentration of alachlor (

As part of the Hawaii Scientific Drilling Project, Kahi Puka Well 1 penetrated about 275 m of Mauna Loa basalts overlying a sequence of Mauna Kea flow units as it was drilled and cored to a total depth of 1053 m below land surface. A borehole televiewer (BHTV) was run in most of the well in successive stages prior to casing in order to obtain magnetically oriented acoustic images of the...

The transport of many solutes in groundwater is dependent upon the relative rates of physical flow and microbial metabolism. Quantifying rates of microbial processes under subsurface conditions is difficult and is most commonly approximated using laboratory studies with aquifer materials. In this study, we measured in situ rates of denitrification in a nitrate-contaminated aquifer using...

Laboratory experiments employing radiotracer methodology were conducted to determine the assimilation efficiencies from ingested natural seston, the influx rates from the dissolved phase and the efflux rates of 6 trace elements (Ag, Am, Cd, Co, Se and Zn) in the mussel Mytilus edulis. A kinetic model was then employed to predict trace element concentration in mussel tissues in 2...

Temperature and formation resistivity logs obtained in borehole KP-1 of the Hawaii Scientific Drilling Project indicate that the adjacent formation is characterized by several zones of distinctly different average temperature and water salinity. A series of hydraulic analyses and water sampling programs were conducted to rule out the possibility of local hydraulic effects associated with...

The distribution and fate of chlorinated pesticides, biomarkers, and polycyclic aromatic hydrocarbons (PAHs) in surficial sediments along a contamination gradient in the Lauritzen Canal and Richmond Harbor in San Francisco Bay was investigated. Compounds were identified and quantified using gas chromatography-ion trap mass spectrometry. Biomarkers and PAHs were derived primarily from...

Several future research topics for herbicide metabolites in surface and ground water are outlined in this chapter. They are herbicide usage, chemical analysis of metabolites, and fate and transport of metabolites in surface and ground water. These three ideas follow the themes in this book, which are the summary of a symposium of the American Chemical Society on herbicide metabolites in...