Publications

As part of the investigation of groundwater contamination at a uranium-scrap recovery plant at Wood River Junction, Rhode Island, laboratory experiments led to the development of a model for predicting the transport of strontium 90 in glacial outwash sediments based on an approximate mechanism for ion exchange. The multicomponent system was simplified to two components by regarding all

We model the transport of a simply reactive contaminant through an infiltration bed and underlying shallow, one-dimensional, unconfined aquifer with a plane, steeply sloping bottom in the assumed absence of dispersion and downgradient dilution. The effluent discharge and ambient groundwater flow under the infiltration beds are presumed to form a vertically mixed plume marked by an...

Hydrogeologic studies commonly include the development, calibration, and application of a deterministic simulation model. To help assess the value of using such models to make predictions, a postaudit was conducted on a previously studied area in the Salt River and lower Santa Cruz River basins in central Arizona. A deterministic, distributed-parameter model of the ground-water system in...

No abstract available.

This chapter focuses on the physic-chemical processes affecting copper, zinc, and tin toxicity to algae. Both Cu and Zn are essential algal micronutrients, cofactors in numerous biochemical processes. The availability of a nutrient or toxic substance can be significantly affected by precipitation. Methods for modeling the effects of adsorption–desorption reactions have been previously...

No abstract available.

Seven samples of commercial "humic acids", purchased from five different suppliers, were studied, and their characteristics were compared with humic and fulvic acids isolated from streams, soils, peat, leonardite, and a dopplerite sample. Cross-polarization and magic-angle spinning 13C NMR spectroscopy clearly shows pronounced differences between the commercial materials and all other...

The Mill Run watershed is a structurally‐controlled synclinal basin on the eastern limb of the Massanutten Mountain complex of northwestern Virginia. Bedrock contacts are obscured by coarse sandstone debris from exposures near basin divides. Colluvium blankets more than half the basin, masking geomorphic surfaces, affecting vegetation patterns, and contributing to the convexity of the...

Denitrification in aquatic sediments was measured by an N2O reductase assay. Sediments consumed small added quantities of N2O over short periods (a few hours). In experiments with sediment slurries, N2O reductase activity was inhibited by O2, C2H2, heat treatment, and by high levels of nitrate (1 mM) or sulfide (10 mM). However, ambient levels of nitrate (

Many parts of the Great Basin have thick zones of unsaturated alluvium which might be suitable for disposing of high-level radioactive wastes. A mathematical model accounting for the coupled transport of energy, water (vapor and liquid), and dry air was used to analyze one-dimensional, vertical transport above and below an areally extensive repository. Numerical simulations were...

Chemical data from three different series of diagenetic illite/smectites (I/S), analyzed statistically by two regresion techniques, indicate that the content of fixed-K per illite layer is not constant, but ranges from ∼0.55 per O10(OH)2 for illite layers in randomly interstratified I/S (R=0; > 50% smectite layers) to ∼1.0 per O10(OH)2 for illite layers formed in ordered I/S (R>0;

Changes in salinity and nitrate concentration in groundwater and surface water in the semiarid Arkansas River valley of southeastern Colorado, USA were related primarily to irrigation practices. Water is applied to fields by flood irrigation through ditches and furrows. Irrigation water is derived in nearly equal amounts from surface water and groundwater pumped from the shallow alluvial...