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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

Novel silver tubing method for quantitative introduction of water into high temperature conversion systems for stable hydrogen and oxygen isotopic measurements Novel silver tubing method for quantitative introduction of water into high temperature conversion systems for stable hydrogen and oxygen isotopic measurements

A new method to seal water in silver tubes for use in a TC/EA reduction unit using a semi-automated sealing apparatus can yield reproducibilities (1 standard deviation) of δ2H and &delta18O measurements of 1.0 ‰ and 0.06 ‰, respectively. These silver tubes containing reference waters may be preferred for calibration of H- and O-bearing materials analyzed with a TC/EA reduction unit. The...
Authors
Haiping Qi, Manfred Groning, Tyler B. Coplen, Bryan Buck, Stanley J. Mroczkowski, Willi A. Brand, Heike Geilmann, Matthias Gehre

Isotope reference materials Isotope reference materials

Measurement of the same isotopically homogeneous sample by any laboratory worldwide should yield the same isotopic composition within analytical uncertainty. International distribution of light element isotopic reference materials by the International Atomic Energy Agency and the U.S. National Institute of Standards and Technology enable laboratories to achieve this goal.
Authors
Tyler B. Coplen

Mortality of centrarchid fishes in the Potomac drainage: Survey results and overview of potential contributing factors Mortality of centrarchid fishes in the Potomac drainage: Survey results and overview of potential contributing factors

Skin lesions and spring mortality events of smallmouth bass Micropterus dolomieu and selected other species were first noted in the South Branch of the Potomac River in 2002. Since that year morbidity and mortality have also been observed in the Shenandoah and Monocacy rivers. Despite much research, no single pathogen, parasite, or chemical cause for the lesions and mortality has been...
Authors
Vicki Blazer, Luke R. Iwanowicz, Clifford E. Starliper, Steven D. Zaugg, Mark R. Burkhardt, P. Barbash, J.D. Hedrick, S.J. Reeser, J.E. Mullican, J. Kelble

Development of a new toxic-unit model for the bioassessment of metals in streams Development of a new toxic-unit model for the bioassessment of metals in streams

Two toxic-unit models that estimate the toxicity of trace-metal mixtures to benthic communities were compared. The chronic criterion accumulation ratio (CCAR), a modification of biotic ligand model (BLM) outputs for use as a toxic-unit model, accounts for the modifying and competitive influences of major cations (Ca2+, Mg2+, Na+, K+, H+), anions (HCO3−, CO32−,SO42−, Cl−, S2−) and...
Authors
Travis S. Schmidt, W.H. Clements, K.A. Mitchell, Stanley E. Church, Richard B. Wanty, David L. Fey, Philip L. Verplanck, Carma A. San Juan

Anthropogenic tracers, endocrine disrupting chemicals, and endocrine disruption in Minnesota lakes Anthropogenic tracers, endocrine disrupting chemicals, and endocrine disruption in Minnesota lakes

Concentrations of endocrine disrupting chemicals and endocrine disruption in fish were determined in 11 lakes across Minnesota that represent a range of trophic conditions and land uses (urban, agricultural, residential, and forested) and in which wastewater treatment plant discharges were absent. Water, sediment, and passive polar organic integrative samplers (POCIS) were analyzed for...
Authors
J.H. Writer, L. B. Barber, G.K. Brown, Howard E. Taylor, R.L. Kiesling, M.L. Ferrey, N.D. Jahns, S.E. Bartell, H.L. Schoenfuss

Redox transformations and transport of cesium and iodine (-1, 0, +5) in oxidizing and reducing zones of a sand and gravel aquifer Redox transformations and transport of cesium and iodine (-1, 0, +5) in oxidizing and reducing zones of a sand and gravel aquifer

Tracer tests were performed in distinct biogeochemical zones of a sand and gravel aquifer in Cape Cod, MA, to study the redox chemistry (I) and transport (Cs, I) of cesium and iodine in a field setting. Injection of iodide (I -) into an oxic zone of the aquifer resulted in oxidation of I - to molecular iodine (I2) and iodate (IO3-) over transport distances of several meters. Oxidation is
Authors
Patricia M. Fox, Douglas B. Kent, James A. Davis

Measurement and modeling of polychlorinated biphenyl bioaccumulation from sediment for the marine polychaete neanthes arenaceodentata and response to sorbent amendment Measurement and modeling of polychlorinated biphenyl bioaccumulation from sediment for the marine polychaete neanthes arenaceodentata and response to sorbent amendment

Bioaccumulation rates of polychlorinated biphenyls (PCBs) for the marine polychaete Neanthes arenaceodentata were characterized, including PCB uptake rates from water and sediment, and the effect of sorbent amendment to the sediment on PCB bioavailability, organism growth, and lipid content. Physiological parameters were incorporated into a biodynamic model to predict contaminant uptake...
Authors
E.M.-L. Janssen, Marie Noele Croteau, S. N. Luoma, R.G. Luthy

Cyanotoxin mixtures and taste-and-odor compounds in cyanobacterial blooms from the midwestern united states Cyanotoxin mixtures and taste-and-odor compounds in cyanobacterial blooms from the midwestern united states

The mixtures of toxins and taste-and-odor compounds present during cyanobacterial blooms are not well characterized and of particular concern when evaluating potential human health risks. Cyanobacterial blooms were sampled in twenty-three Midwestern United States lakes and analyzed for community composition, thirteen cyanotoxins by liquid chromatography/mass spectrometry and immunoassay...
Authors
Jennifer L. Graham, Keith A. Loftin, Michael T. Meyer, Andrew C. Ziegler

Relative vulnerability of public supply wells to VOC contamination in hydrologically distinct regional aquifers Relative vulnerability of public supply wells to VOC contamination in hydrologically distinct regional aquifers

A process-based methodology was used to compare the vulnerability of public supply wells tapping seven study areas in four hydrologically distinct regional aquifers to volatile organic compound (VOC) contamination. This method considers (1) contributing areas and travel times of groundwater flowpaths converging at individual supply wells, (2) the oxic and/or anoxic conditions encountered...
Authors
Leon J. Kauffman, Francis H. Chapelle

Influence of organic carbon loading, sediment associated metal oxide content and sediment grain size distributions upon Cryptosporidium parvum removal during riverbank filtration operations, Sonoma County, CA Influence of organic carbon loading, sediment associated metal oxide content and sediment grain size distributions upon Cryptosporidium parvum removal during riverbank filtration operations, Sonoma County, CA

This study assessed the efficacy for removing Cryptosporidium parvum oocysts of poorly sorted, Fe- and Al-rich, subsurface sediments collected from 0.9 to 4.9 and 1.7–13.9 m below land surface at an operating riverbank filtration (RBF) site (Russian River, Sonoma County, CA). Both formaldehyde-killed oocysts and oocyst-sized (3 μm) microspheres were employed in sediment-packed flow...
Authors
D.W. Metge, R.W. Harvey, G. R. Aiken, R. Anders, G. Lincoln, James Jasperse

Polycyclic aromatic hydrocarbons in soil of the Canadian River floodplain in Oklahoma Polycyclic aromatic hydrocarbons in soil of the Canadian River floodplain in Oklahoma

The accumulation of polycyclic aromatic hydrocarbons (PAH) in soil, plants, and water may impart negative effects on ecosystem and human health. We quantified the concentration and distribution of 41 PAH (n = 32), organic C, total N, and S (n = 140) and investigated PAH sources using a chronosequence of floodplain soils under a natural vegetation succession. Soil samples were collected...
Authors
F. Sartori, T.L. Wade, J.L. Sericano, B.P. Mohanty, Karen A. Smith

A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models A shallow subsurface controlled release facility in Bozeman, Montana, USA, for testing near surface CO2 detection techniques and transport models

A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO2 transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO2 release rates were chosen to be relevant to developing monitoring strategies for geological carbon storage. The field site was characterized before...
Authors
L.H. Spangler, L.M. Dobeck, K.S. Repasky, A.R. Nehrir, S.D. Humphries, C.J. Keith, J.A. Shaw, J.H. Rouse, A.B. Cunningham, S.M. Benson, C.M. Oldenburg, J.L. Lewicki, A.W. Wells, J.R. Diehl, B.R. Strazisar, J.E. Fessenden, T.A. Rahn, J.E. Amonette, J.L. Barr, W.L. Pickles, J.D. Jacobson, E. A. Silver, E.J. Male, H.W. Rauch, K.S. Gullickson, R. Trautz, Yousif K. Kharaka, J. Birkholzer, L. Wielopolski
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