Publications

While the existence of relatively fresh groundwater sequestered within permeable, porous sediments beneath the Atlantic continental shelf of North and South America has been known for some time, these waters have never been assessed as a potential resource. This fresh water was likely emplaced during Pleistocene sea-level low stands when the shelf was exposed to meteoric recharge and by...

The prevalence of organic wastewater compounds in surface waters of the United States has been reported in a number of recent studies. In karstic areas, surface contaminants might be transported to groundwater and, ultimately, cave ecosystems, where they might impact resident biota. In this study, polar organic chemical integrative samplers (POCISs) and semipermeable membrane devices...

An extensive continuous waterborne electrical imaging (CWEI) survey was conducted along the Columbia River corridor adjacent to the U.S. Department of Energy (DOE) Hanford 300 Area, WA, in order to improve the conceptual model for exchange between surface water and U‐contaminated groundwater. The primary objective was to determine spatial variability in the depth to the Hanford‐Ringold...

The potable water system at Fort Knox is threatened by brine contamination from improperly abandoned natural gas exploration wells. The Fort Knox well field is located near the town of West Point, Kentucky, in the flood plain of the Ohio River. At the site, unconsolidated sediments approximately 30 – 40 m thick, overlie shale and porous limestone. Brine is believed to flow vertically...

Perchlorate (ClO4−) has been detected widely in groundwater and soils of the southwestern United States. Much of this ClO4− appears to be natural, and it may have accumulated largely through wet and dry atmospheric deposition. This study evaluates the isotopic composition of natural ClO4− indigenous to the southwestern U.S. Stable isotope ratios were measured in ClO4− (δ18O, Δ17O, δ37Cl)...

In this work, we use stable Zn and Cu isotopes to identify the sources and timing of the deposition of these metals in a sediment core from Lake Ballinger near Seattle, Washington, USA. The base of the Lake Ballinger core predates settlement in the region, while the upper sections record the effects of atmospheric emissions from a nearby smelter and rapid urbanization of the watershed...

This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na...

A new ion chromatography electrospray tandem mass spectrometry (IC-ESI/MS/MS) method has been developed for quantification and confirmation of chlorate (ClO3−) in environmental samples. The method involves the electro-chemical generation of isotopically labeled chlorate internal standard (Cl18O3−) using 18O water (H218O). The standard was added to all samples prior to analysis thereby...

How groundwater flow varies when long-term external conditions change is little documented. Geochemical evidence shows that sea-level rise at the end of the last glacial period led to a shift in the flow patterns of coastal groundwater beneath Florida.

No abstract available.

Solid-phase microextraction (SPME) has shown potential as an in situ passive-sampling technique in aquatic environments. The reliability of this method depends upon accurate determination of the partition coefficient between the fiber coating and water (Kf). For some hydrophobic organic compounds (HOCs), Kf values spanning 4 orders of magnitude have been reported for polydimethylsiloxane...

The restoration of 18 acres of historic tidal marsh at Crissy Field has had great success in terms of public outreach and visibility, but less success in terms of revegetated marsh sustainability. Native cordgrass (Spartina foliosa) has experienced dieback and has failed to recolonize following extended flooding events during unintended periodic closures of its inlet channel, which...