Robert C Burruss (Former Employee)
Science and Products
Filter Total Items: 65
Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)
Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca (G. prisca) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location
Authors
Paul C. Hackley, Aaron M. Jubb, Robert Burruss, Amy E Beaven
Shift in the Raman symmetric stretching band of N2, CO2, and CH4 as a function of temperature, pressure, and density
The Raman spectra of pure N2, CO2, and CH4 were analyzed over the range 10 to 500 bars and from −160°C to 200°C (N2), 22°C to 350°C (CO2), and −100°C to 450°C (CH4). At constant temperature, Raman peak position, including the more intense CO2 peak (ν+), decreases (shifts to lower wave number) with increasing pressure for all three gases over the entire pressure and temperature (PT) range studied.
Authors
D. Matthew Sublett Jr., Eszter Sendula, Hector Lamadrid, Matthew Steele-MacInnis, Georg Spiekermann, Robert Burruss, Robert J. Bodnar
High microscale variability in Raman thermal maturity estimates from shale organic matter
Raman spectroscopy has recently received attention as a means to estimate thermal maturity of organic matter in petroleum generating source rocks to complement more traditional approaches such as vitrinite reflectance and programmed pyrolysis. While many studies have observed positive correlations between source rock thermal maturity and Raman spectral parameters, little attention has been given t
Authors
Aaron M. Jubb, Palma J. Botterell, Justin E. Birdwell, Robert C. Burruss, Paul C. Hackley, Brett J. Valentine, Javin J. Hatcherian, Stephen A. Wilson
Experimental investigation on thermochemical sulfate reduction in the presence of 1-pentanethiol at 200 and 250 °C: Implications for in situ TSR processes occurring in some MVT deposits
Organic sulfur compounds are ubiquitous in natural oil and gas fields and moderate-low temperature sulfide ore deposits. Previous studies have shown that organic sulfur compounds are important in enhancing the rates of thermochemical sulfate reduction (TSR) reactions, but the details of these reaction mechanisms remain unclear. In order to assess the extent of sulfate reduction in the presence of
Authors
Shunda Yuan, Geoffrey S. Ellis, I-Ming Chou, Robert Burruss
Depositional conditions for the Kuna Formation, Red Dog Zn-PB-Ag-Barite District, Alaska, inferred from isotopic and chemical proxies
Water column redox conditions, degree of restriction of the depositional basin, and other paleoenvironmental parameters have been determined for the Mississippian Kuna Formation of northwestern Alaska from stratigraphic profiles of Mo, Fe/Al, and S isotopes in pyrite, C isotopes in organic matter, and N isotopes in bulk rock. This unit is important because it hosts the Red Dog and Anarraaq Zn-Pb-A
Authors
Craig A. Johnson, Julie A. Dumoulin, Robert A. Burruss, John F. Slack
Using ground and intact coal Samples to evaluate hydrocarbon fate during supercritical CO2 injection into coal beds: effects of particle size and coal moisture
To investigate the potential for mobilizing organic compounds from coal beds during geologic carbon dioxide (CO2) storage (sequestration), a series of solvent extractions using dichloromethane (DCM) and using supercritical CO2 (40 °C and 10 MPa) were conducted on a set of coal samples collected from Louisiana and Ohio. The coal samples studied range in rank from lignite A to high volatile A bitumi
Authors
Jon Kolak, Paul C. Hackley, Leslie F. Ruppert, Peter D. Warwick, Robert Burruss
Raman spectroscopic characterization of CH4 density over a wide range of temperature and pressure
The positions of the CH4 Raman ν1 symmetric stretching bands were measured in a wide range of temperature (from −180 °C to 350 °C) and density (up to 0.45 g/cm3) using high-pressure optical cell and fused silica capillary capsule. The results show that the Raman band shift is a function of both methane density and temperature; the band shifts to lower wavenumbers as the density increases and the t
Authors
Linbo Shang, I-Ming Chou, Robert Burruss, Ruizhong Hu, Xianwu Bi
The use of solvent extractions and solubility theory to discern hydrocarbon associations in coal, with application to the coal-supercritical CO2 system
Samples of three high volatile bituminous coals were subjected to parallel sets of extractions involving solvents dichloromethane (DCM), carbon disulfide (CS2), and supercritical carbon dioxide (CO2) (40 °C, 100 bar) to study processes affecting coal–solvent interactions. Recoveries of perdeuterated surrogate compounds, n-hexadecane-d34 and four polycyclic aromatic hydrocarbons (PAHs), added as a
Authors
Jonathan J. Kolak, Robert A. Burruss
The geochemistry of oils and gases from the Cumberland overthrust sheet in Virginia and Tennessee
This study presents high-resolution gas chromatograms of oils and molecular and isotopic analyses of oil-associated gases from 17 wells producing in the Upper Cambrian to Lower Ordovician Knox Group, the Middle and Upper Ordovician Stones River Group, and the Upper Ordovician Trenton Limestone in the Cumberland overthrust sheet. The wells are located in the Ben Hur and Rose Hill fields in Lee Coun
Authors
Kristen O. Dennen, Mark Deering, Robert A. Burruss
Composition of natural gas and crude oil produced from 14 wells in the Lower Silurian "Clinton" Sandstone and Medina Group Sandstones, northeastern Ohio and northwestern Pennsylvania
The geochemical processes that control the distribution of hydrocarbons in the regional accumulation of natural gas and crude oil in reservoirs of Early Silurian age in the central Appalachian basin are not well understood. Gas and oil samples from 14 wells along a down-dip transect through the accumulation in northeastern Ohio and northwestern Pennsylvania were analyzed for molecular and stable i
Authors
Robert A. Burruss, Robert T. Ryder
Evidence for Cambrian petroleum source rocks in the Rome trough of West Virginia and Kentucky, Appalachian basin
A 130-foot-thick Cambrian black shale sampled from a core between 11,150 and 11,195 feet in the Exxon No. 1 Smith well in Wayne County, W. Va., has been identified as a good to very good source rock. The black shale is located in the Middle Cambrian Rogersville Shale of the Conasauga Group. Total organic carbon (TOC) values of four samples that range from 1.2 to 4.4 weight percent (average 2.6 wei
Authors
Robert T. Ryder, David C. Harris, Paul Gerome, Timothy J. Hainsworth, Robert A. Burruss, Paul G. Lillis, Daniel M. Jarvie, Mark J. Pawlewicz
Composition of natural gas and crude oil produced from 10 wells in the Lower Silurian "Clinton" Sandstone, Trumbull County, Ohio
Natural gases and associated crude oils in the “Clinton” sandstone, Medina Group sandstones, and equivalent Tuscarora Sandstone in the northern Appalachian basin are part of a regional, continuous-type or basin-centered accumulation. The origin of the hydrocarbon charge to regional continuoustype accumulations is poorly understood. We have analyzed the molecular and stable isotopic composition of
Authors
Robert A. Burruss, Robert T. Ryder
Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)
Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca (G. prisca) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location
High Microscale Variability in Raman Thermal Maturity Estimates from Shale Organic Matter - Data Release
Here the spatial variation in Raman estimates of thermal maturity within individual organic domains from several shale geologic reference materials originating from the Boquillas, Marcellus, Niobrara, and Woodford Formations are assessed from the respective Raman response. We show that for all four shales the thermal maturity parameters extracted from Raman spectra by iterative peak fitting can va
Science and Products
Filter Total Items: 65
Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)
Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca (G. prisca) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location
Authors
Paul C. Hackley, Aaron M. Jubb, Robert Burruss, Amy E Beaven
Shift in the Raman symmetric stretching band of N2, CO2, and CH4 as a function of temperature, pressure, and density
The Raman spectra of pure N2, CO2, and CH4 were analyzed over the range 10 to 500 bars and from −160°C to 200°C (N2), 22°C to 350°C (CO2), and −100°C to 450°C (CH4). At constant temperature, Raman peak position, including the more intense CO2 peak (ν+), decreases (shifts to lower wave number) with increasing pressure for all three gases over the entire pressure and temperature (PT) range studied.
Authors
D. Matthew Sublett Jr., Eszter Sendula, Hector Lamadrid, Matthew Steele-MacInnis, Georg Spiekermann, Robert Burruss, Robert J. Bodnar
High microscale variability in Raman thermal maturity estimates from shale organic matter
Raman spectroscopy has recently received attention as a means to estimate thermal maturity of organic matter in petroleum generating source rocks to complement more traditional approaches such as vitrinite reflectance and programmed pyrolysis. While many studies have observed positive correlations between source rock thermal maturity and Raman spectral parameters, little attention has been given t
Authors
Aaron M. Jubb, Palma J. Botterell, Justin E. Birdwell, Robert C. Burruss, Paul C. Hackley, Brett J. Valentine, Javin J. Hatcherian, Stephen A. Wilson
Experimental investigation on thermochemical sulfate reduction in the presence of 1-pentanethiol at 200 and 250 °C: Implications for in situ TSR processes occurring in some MVT deposits
Organic sulfur compounds are ubiquitous in natural oil and gas fields and moderate-low temperature sulfide ore deposits. Previous studies have shown that organic sulfur compounds are important in enhancing the rates of thermochemical sulfate reduction (TSR) reactions, but the details of these reaction mechanisms remain unclear. In order to assess the extent of sulfate reduction in the presence of
Authors
Shunda Yuan, Geoffrey S. Ellis, I-Ming Chou, Robert Burruss
Depositional conditions for the Kuna Formation, Red Dog Zn-PB-Ag-Barite District, Alaska, inferred from isotopic and chemical proxies
Water column redox conditions, degree of restriction of the depositional basin, and other paleoenvironmental parameters have been determined for the Mississippian Kuna Formation of northwestern Alaska from stratigraphic profiles of Mo, Fe/Al, and S isotopes in pyrite, C isotopes in organic matter, and N isotopes in bulk rock. This unit is important because it hosts the Red Dog and Anarraaq Zn-Pb-A
Authors
Craig A. Johnson, Julie A. Dumoulin, Robert A. Burruss, John F. Slack
Using ground and intact coal Samples to evaluate hydrocarbon fate during supercritical CO2 injection into coal beds: effects of particle size and coal moisture
To investigate the potential for mobilizing organic compounds from coal beds during geologic carbon dioxide (CO2) storage (sequestration), a series of solvent extractions using dichloromethane (DCM) and using supercritical CO2 (40 °C and 10 MPa) were conducted on a set of coal samples collected from Louisiana and Ohio. The coal samples studied range in rank from lignite A to high volatile A bitumi
Authors
Jon Kolak, Paul C. Hackley, Leslie F. Ruppert, Peter D. Warwick, Robert Burruss
Raman spectroscopic characterization of CH4 density over a wide range of temperature and pressure
The positions of the CH4 Raman ν1 symmetric stretching bands were measured in a wide range of temperature (from −180 °C to 350 °C) and density (up to 0.45 g/cm3) using high-pressure optical cell and fused silica capillary capsule. The results show that the Raman band shift is a function of both methane density and temperature; the band shifts to lower wavenumbers as the density increases and the t
Authors
Linbo Shang, I-Ming Chou, Robert Burruss, Ruizhong Hu, Xianwu Bi
The use of solvent extractions and solubility theory to discern hydrocarbon associations in coal, with application to the coal-supercritical CO2 system
Samples of three high volatile bituminous coals were subjected to parallel sets of extractions involving solvents dichloromethane (DCM), carbon disulfide (CS2), and supercritical carbon dioxide (CO2) (40 °C, 100 bar) to study processes affecting coal–solvent interactions. Recoveries of perdeuterated surrogate compounds, n-hexadecane-d34 and four polycyclic aromatic hydrocarbons (PAHs), added as a
Authors
Jonathan J. Kolak, Robert A. Burruss
The geochemistry of oils and gases from the Cumberland overthrust sheet in Virginia and Tennessee
This study presents high-resolution gas chromatograms of oils and molecular and isotopic analyses of oil-associated gases from 17 wells producing in the Upper Cambrian to Lower Ordovician Knox Group, the Middle and Upper Ordovician Stones River Group, and the Upper Ordovician Trenton Limestone in the Cumberland overthrust sheet. The wells are located in the Ben Hur and Rose Hill fields in Lee Coun
Authors
Kristen O. Dennen, Mark Deering, Robert A. Burruss
Composition of natural gas and crude oil produced from 14 wells in the Lower Silurian "Clinton" Sandstone and Medina Group Sandstones, northeastern Ohio and northwestern Pennsylvania
The geochemical processes that control the distribution of hydrocarbons in the regional accumulation of natural gas and crude oil in reservoirs of Early Silurian age in the central Appalachian basin are not well understood. Gas and oil samples from 14 wells along a down-dip transect through the accumulation in northeastern Ohio and northwestern Pennsylvania were analyzed for molecular and stable i
Authors
Robert A. Burruss, Robert T. Ryder
Evidence for Cambrian petroleum source rocks in the Rome trough of West Virginia and Kentucky, Appalachian basin
A 130-foot-thick Cambrian black shale sampled from a core between 11,150 and 11,195 feet in the Exxon No. 1 Smith well in Wayne County, W. Va., has been identified as a good to very good source rock. The black shale is located in the Middle Cambrian Rogersville Shale of the Conasauga Group. Total organic carbon (TOC) values of four samples that range from 1.2 to 4.4 weight percent (average 2.6 wei
Authors
Robert T. Ryder, David C. Harris, Paul Gerome, Timothy J. Hainsworth, Robert A. Burruss, Paul G. Lillis, Daniel M. Jarvie, Mark J. Pawlewicz
Composition of natural gas and crude oil produced from 10 wells in the Lower Silurian "Clinton" Sandstone, Trumbull County, Ohio
Natural gases and associated crude oils in the “Clinton” sandstone, Medina Group sandstones, and equivalent Tuscarora Sandstone in the northern Appalachian basin are part of a regional, continuous-type or basin-centered accumulation. The origin of the hydrocarbon charge to regional continuoustype accumulations is poorly understood. We have analyzed the molecular and stable isotopic composition of
Authors
Robert A. Burruss, Robert T. Ryder
Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)
Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca (G. prisca) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location
High Microscale Variability in Raman Thermal Maturity Estimates from Shale Organic Matter - Data Release
Here the spatial variation in Raman estimates of thermal maturity within individual organic domains from several shale geologic reference materials originating from the Boquillas, Marcellus, Niobrara, and Woodford Formations are assessed from the respective Raman response. We show that for all four shales the thermal maturity parameters extracted from Raman spectra by iterative peak fitting can va