We are studying environmental issues related to mining, and potential mining, in the Great Lakes region, continuing the study of characterizing baseline geochemistry of several watersheds in Minnesota and Michigan, examining the potential for aquatic toxicity from metals, and examining the acid-neutralizing and acid-generating potentials of mine waste, and the environmental, and possible human health, effects of waste generated by past iron mining and steel-making.
Science Issue and Relevance
The Lake Superior region is the focus of widespread mineral exploration and startup mining activity, due to its promising geologic settings for more deposits of minerals critical to the U.S. economy. However, local communities have concern about potential for environmental harm caused by mining, as some past mining activities here have impacted water quality. Concerns are often voiced about the dangers of “sulfide mining". This is an over-simplified perception of mining. This region has a unique climate, and the landscape is dominated by lakes, rivers and wetlands. Preventing environmental impact requires full consideration of the influences of geology, hydrology, climate, mining methods, ore-processing methods, and continued evolution of environmental management practices on environmental risks of unique deposit types. Our science looks beyond acid-generating potential of the ores, and includes the assessment of potential risks to human health and aquatic ecosystems from trace metals.
Methodology to Address Issue
- We are studying environmental issues related to mining, and potential mining, in the Great Lakes region. Our study areas are recently proposed metal mining ventures in the Lake Superior region, including:
- deposits located within the basal zone of the Duluth Complex,
- deposits in the Ironwood Iron Formation,
- and deposits associated with the Nonesuch Shale.
- We are continuing the study of characterizing baseline geochemistry of several watersheds in Minnesota and Michigan, and examining the potential for aquatic toxicity from metals.
- We are examining the acid-neutralizing and acid-generating potentials of mine waste, and the environmental, and possible human health, effects of waste generated by past iron mining and steel-making, a priority brought to light by discussions with our collaborators and stakeholders.
Current Activities
Watershed Baseline Chemistry and Copper Toxicity Study: We will determine the pre-mining chemistry of watersheds near copper-nickel-platinum group element deposits in Minnesota, and copper deposits in the Upper Peninsula of Michigan. Two methods have been used by regulatory agencies in this region to assess copper toxicity to aquatic organisms; these include calculating water quality criteria based on hardness and based on the Biotic Ligand Model. We will compare the predictions of potential toxicity from both methods at sites in Minnesota and Michigan. Next, we will evaluate our predictions, based on the results from toxicity tests done in collaboration with the USGS Columbia Environmental Research Center.
Iron Life Cycle Studies: We will analyze and help predict the source, transport, and fate of products from iron mining in the Gogebic Range of northern Michigan and Wisconsin, and from iron and steelmaking slag in the Chicago region of Illinois and Indiana. Analyses will include:
- Fibrous amphibole minerals – a notable human health risk – which have been identified in parts of the Duluth Complex, and in parts of the Ironwood Iron Formation (Wisconsin)
- Sulfide oxidation, acid generation, acid neutralization, and trace element release from potential mine waste, and rock or soil overlying a mineral deposit, which may influence water quality
- Sulfate sources in watersheds that may be influenced by mining (high concentrations of sulfate may be toxic to wild rice, an important subsistence crop for Native Americans)
- Iron and steel slag is present in large volumes, and is known to be an environmental liability. However, it is also a beneficial resource for road construction and has potential for use in the removal of phosphate and nitrogen from waste water and agricultural water

Mine Waste Prediction: We will determine how potential mine waste from mining deposits in the Duluth Complex (northeastern Minnesota) may release trace elements into the environment, and inform communities and stakeholders of best mine waste management practices. We will also refine our ability to predict (via mineralogical and chemical studies, as well as reaction pathway geochemical modeling) the potential for silicate minerals in the Duluth Complex ore to neutralize acid. Rocks that host the mineralization in the Complex (and will become the waste during mining) are unusual, in that
- they are essentially devoid of carbonate minerals — hence they lack carbonate-neutralizing potential, and
- they have a quantifiable, yet low, acid-generating potential.
However, there is potential for beneficial acid-neutralization from the silicate minerals that make up most of the rock hosting the metals of interest.
Completed Activity - Environmental Geochemistry to Evaluate Risks Associated with Past and Future Mining in the Lake Superior Region
This project was a geoenvironmental assessment to support development of responsible mining methods in the unique Lake Superior region. This benefitted all stakeholders in decision-making regarding future mining: land managers, the mining industry, regulatory agencies, non-government organizations, and citizens. We studied the two kinds of deposits most likely to be developed here:
- nickel, copper, and platinum-group metal deposits in the Duluth Complex of northeastern Minnesota,
- sediment-hosted copper deposits of the Porcupine Mountains area, Michigan.
Examples of environmental problems we addressed:
- Do conditions currently exist from metals in waters of unmined mineralized watersheds, that may be toxic to aquatic organisms?
- Can we make predictions regarding the potential environmental risks from mining and mine waste for these deposits?

Our results make the planning and permitting process for future mines more efficient, and facilitate a scientifically sound dialog about future mining. Project accomplishments include:
- We built a Geographic Information System (GIS) of ecosystem data sets – the basis for dialogue about potential environmental risks associated with future mining. Data layers include geologic, geochemical, hydrologic, climatic, ecological, demographic information.
- We sampled and tested surface water and stream sediment in watersheds affected by the two dominant deposit types, for pre-mining baseline geochemical characterization. We coordinated specific sampling areas with the Midwest Area Mining Initiative, for access to water resource data sets that otherwise would have been less than easy to use, and world-class stream gaging data for the affected watersheds. We analyzed different methods used by regulatory agencies for assessing the surface-water toxicity of copper, as well as methods used for assessing metal toxicity in sediments.
The sulfate budget of these watersheds was of particular interest due to the Minnesota wild rice water-quality standard for sulfate. We compared the stable isotope signatures of dissolved sulfate with known values for mineralized rocks, to fingerprint the sulfate sources. - We developed geoenvironmental models for various deposit types, customized to the Lake Superior region, which include both pre-mining baseline conditions and the signatures associated with mine waste and drainage. These models enable environmental risks to be ranked and addressed. We evaluated how several factors (such as geology, local hydrology, geochemistry, climate) affect trace elements released to the environment from mining. Deposit-specific details included mineralogic hosts of trace elements, acid-base accounting characteristics, and leaching properties of unmined rock, waste rock, and mine wastes.
Return to Mineral Resources Program
Below are data releases associated with this project.
Major, Minor, and Trace Element Compositions of Bulk Drill Core Samples from the Duluth Complex, Minnesota
Below are multimedia items associated with this project.
Below are publications associated with this project.
Hydrologic balance, water quality, chemical-mass balance, and geochemical modeling of hyperalkaline ponds at Big Marsh, Chicago, Illinois, 2016–17
Applied Geochemistry Special Issue on Environmental geochemistry of modern mining
Characteristics and environmental aspects of slag: a review
Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes
Copper toxicity and organic matter: Resiliency of watersheds in the Duluth Complex, Minnesota, USA
Reaction modeling of drainage quality in the Duluth Complex, northern Minnesota, USA
Magmatic sulfide-rich nickel-copper deposits related to picrite and (or) tholeiitic basalt dike-sill complexes: A preliminary deposit model
Below are news stories associated with this project.
In addition to the USGS Columbia Environmental Resource Center and Water Science Centers in Illinois, Indiana, Minnesota, and Wisconsin, below are external partners associated with this project.
- Overview
We are studying environmental issues related to mining, and potential mining, in the Great Lakes region, continuing the study of characterizing baseline geochemistry of several watersheds in Minnesota and Michigan, examining the potential for aquatic toxicity from metals, and examining the acid-neutralizing and acid-generating potentials of mine waste, and the environmental, and possible human health, effects of waste generated by past iron mining and steel-making.
Scientists sampling water and measuring streamflow in Keeley Creek, a stream in northern Minnesota that is in the vicinity of copper-nickel-platinum group element deposits. (Credit: Perry Jones, USGS. Public domain.) Science Issue and Relevance
The Lake Superior region is the focus of widespread mineral exploration and startup mining activity, due to its promising geologic settings for more deposits of minerals critical to the U.S. economy. However, local communities have concern about potential for environmental harm caused by mining, as some past mining activities here have impacted water quality. Concerns are often voiced about the dangers of “sulfide mining". This is an over-simplified perception of mining. This region has a unique climate, and the landscape is dominated by lakes, rivers and wetlands. Preventing environmental impact requires full consideration of the influences of geology, hydrology, climate, mining methods, ore-processing methods, and continued evolution of environmental management practices on environmental risks of unique deposit types. Our science looks beyond acid-generating potential of the ores, and includes the assessment of potential risks to human health and aquatic ecosystems from trace metals.
Methodology to Address Issue
- We are studying environmental issues related to mining, and potential mining, in the Great Lakes region. Our study areas are recently proposed metal mining ventures in the Lake Superior region, including:
- deposits located within the basal zone of the Duluth Complex,
- deposits in the Ironwood Iron Formation,
- and deposits associated with the Nonesuch Shale.
- We are continuing the study of characterizing baseline geochemistry of several watersheds in Minnesota and Michigan, and examining the potential for aquatic toxicity from metals.
- We are examining the acid-neutralizing and acid-generating potentials of mine waste, and the environmental, and possible human health, effects of waste generated by past iron mining and steel-making, a priority brought to light by discussions with our collaborators and stakeholders.
Current Activities
USGS scientists sampling the Ironwood Iron-Formation, Gogebic Iron Range in northern Wisconsin.(Credit: Robert Seal II, USGS. Public domain.) Watershed Baseline Chemistry and Copper Toxicity Study: We will determine the pre-mining chemistry of watersheds near copper-nickel-platinum group element deposits in Minnesota, and copper deposits in the Upper Peninsula of Michigan. Two methods have been used by regulatory agencies in this region to assess copper toxicity to aquatic organisms; these include calculating water quality criteria based on hardness and based on the Biotic Ligand Model. We will compare the predictions of potential toxicity from both methods at sites in Minnesota and Michigan. Next, we will evaluate our predictions, based on the results from toxicity tests done in collaboration with the USGS Columbia Environmental Research Center.
Iron Life Cycle Studies: We will analyze and help predict the source, transport, and fate of products from iron mining in the Gogebic Range of northern Michigan and Wisconsin, and from iron and steelmaking slag in the Chicago region of Illinois and Indiana. Analyses will include:
- Fibrous amphibole minerals – a notable human health risk – which have been identified in parts of the Duluth Complex, and in parts of the Ironwood Iron Formation (Wisconsin)
- Sulfide oxidation, acid generation, acid neutralization, and trace element release from potential mine waste, and rock or soil overlying a mineral deposit, which may influence water quality
- Sulfate sources in watersheds that may be influenced by mining (high concentrations of sulfate may be toxic to wild rice, an important subsistence crop for Native Americans)
- Iron and steel slag is present in large volumes, and is known to be an environmental liability. However, it is also a beneficial resource for road construction and has potential for use in the removal of phosphate and nitrogen from waste water and agricultural water
Sources/Usage: Public Domain. Visit Media to see details.Geologic map and sampling locations near mineral deposits associated with the Duluth Complex in northern Minnesota.(Public domain.) Mine Waste Prediction: We will determine how potential mine waste from mining deposits in the Duluth Complex (northeastern Minnesota) may release trace elements into the environment, and inform communities and stakeholders of best mine waste management practices. We will also refine our ability to predict (via mineralogical and chemical studies, as well as reaction pathway geochemical modeling) the potential for silicate minerals in the Duluth Complex ore to neutralize acid. Rocks that host the mineralization in the Complex (and will become the waste during mining) are unusual, in that
- they are essentially devoid of carbonate minerals — hence they lack carbonate-neutralizing potential, and
- they have a quantifiable, yet low, acid-generating potential.
However, there is potential for beneficial acid-neutralization from the silicate minerals that make up most of the rock hosting the metals of interest.
Scientists standing on an outcrop of the Ironwood Iron-Formation, Gogebic Iron Range in northern Wisconsin. (Credit: Robert Seal II, USGS. Public domain.) Completed Activity - Environmental Geochemistry to Evaluate Risks Associated with Past and Future Mining in the Lake Superior Region
This project was a geoenvironmental assessment to support development of responsible mining methods in the unique Lake Superior region. This benefitted all stakeholders in decision-making regarding future mining: land managers, the mining industry, regulatory agencies, non-government organizations, and citizens. We studied the two kinds of deposits most likely to be developed here:
- nickel, copper, and platinum-group metal deposits in the Duluth Complex of northeastern Minnesota,
- sediment-hosted copper deposits of the Porcupine Mountains area, Michigan.
Examples of environmental problems we addressed:
- Do conditions currently exist from metals in waters of unmined mineralized watersheds, that may be toxic to aquatic organisms?
- Can we make predictions regarding the potential environmental risks from mining and mine waste for these deposits?
Sources/Usage: Public Domain. Visit Media to see details.Geologic map and sampling locations for the watershed baseline chemistry and copper toxicity study, near copper deposits in the Porcupine Mountains, Michigan.(Public domain.) Our results make the planning and permitting process for future mines more efficient, and facilitate a scientifically sound dialog about future mining. Project accomplishments include:
- We built a Geographic Information System (GIS) of ecosystem data sets – the basis for dialogue about potential environmental risks associated with future mining. Data layers include geologic, geochemical, hydrologic, climatic, ecological, demographic information.
- We sampled and tested surface water and stream sediment in watersheds affected by the two dominant deposit types, for pre-mining baseline geochemical characterization. We coordinated specific sampling areas with the Midwest Area Mining Initiative, for access to water resource data sets that otherwise would have been less than easy to use, and world-class stream gaging data for the affected watersheds. We analyzed different methods used by regulatory agencies for assessing the surface-water toxicity of copper, as well as methods used for assessing metal toxicity in sediments.
The sulfate budget of these watersheds was of particular interest due to the Minnesota wild rice water-quality standard for sulfate. We compared the stable isotope signatures of dissolved sulfate with known values for mineralized rocks, to fingerprint the sulfate sources. - We developed geoenvironmental models for various deposit types, customized to the Lake Superior region, which include both pre-mining baseline conditions and the signatures associated with mine waste and drainage. These models enable environmental risks to be ranked and addressed. We evaluated how several factors (such as geology, local hydrology, geochemistry, climate) affect trace elements released to the environment from mining. Deposit-specific details included mineralogic hosts of trace elements, acid-base accounting characteristics, and leaching properties of unmined rock, waste rock, and mine wastes.
Return to Mineral Resources Program
- We are studying environmental issues related to mining, and potential mining, in the Great Lakes region. Our study areas are recently proposed metal mining ventures in the Lake Superior region, including:
- Data
Below are data releases associated with this project.
Major, Minor, and Trace Element Compositions of Bulk Drill Core Samples from the Duluth Complex, Minnesota
This table reports major, minor, and trace element compositions of bulk drill core samples from the Duluth Complex, Minnesota. Major elements were measured using wavelength dispersive X-ray fluorescence (XRF) and inductively coupled plasma atomic emission spectrometry (ICP-AES); minor and trace elements were determined using ICP-AES, inductively coupled plasma mass spectrometry (ICP-MS), and hydri - Multimedia
Below are multimedia items associated with this project.
- Publications
Below are publications associated with this project.
Hydrologic balance, water quality, chemical-mass balance, and geochemical modeling of hyperalkaline ponds at Big Marsh, Chicago, Illinois, 2016–17
Hyperalkaline (pH greater than 12) ponds and groundwater exist at Big Marsh near Lake Calumet, Chicago, Illinois, a site used by the steel industry during the mid-1900s to deposit steel- and iron-making waste, in particular, slag. The hyperalkaline ponds may pose a hazard to human health and the environment. The U.S. Geological Survey (USGS), in cooperation with the Environmental Protection AgencyAuthorsAmy M. Gahala, Robert R. Seal, Nadine M. PiatakApplied Geochemistry Special Issue on Environmental geochemistry of modern mining
Environmental geochemistry is an integral part of the mine-life cycle, particularly for modern mining. The critical importance of environmental geochemistry begins with pre-mining baseline characterization and the assessment of environmental risks related to mining, continues through active mining especially in water and waste management practices, and culminates in mine closure. The enhanced signAuthorsRobert R. Seal, D. Kirk NordstromCharacteristics and environmental aspects of slag: a review
Slag is a waste product from the pyrometallurgical processing of various ores. Based on over 150 published studies, this paper provides an overview of mineralogical and geochemical characteristics of different types of slag and their environmental consequences, particularly from the release of potentially toxic elements to water. This chapter reviews the characteristics of both ferrous (steel andAuthorsNadine M. Piatak, Michael B. Parsons, Robert R. SealEvaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes
A comparison study of selected static leaching and acid–base accounting (ABA) methods using a mineralogically diverse set of 12 modern-style, metal mine waste samples was undertaken to understand the relative performance of the various tests. To complement this study, in-depth mineralogical studies were conducted in order to elucidate the relationships between sample mineralogy, weathering featureAuthorsPhilip L. Hageman, Robert R. Seal, Sharon F. Diehl, Nadine M. Piatak, Heather LowersCopper toxicity and organic matter: Resiliency of watersheds in the Duluth Complex, Minnesota, USA
We estimated copper (Cu) toxicity in surface water with high dissolved organic matter (DOM) for unmined mineralized watersheds of the Duluth Complex using the Biotic Ligand Model (BLM), which evaluates the effect of DOM, cation competition for biologic binding sites, and metal speciation. A sediment-based BLM was used to estimate stream-sediment toxicity; this approach factors in the cumulative efAuthorsNadine M. Piatak, Robert Seal, Perry M. Jones, Laurel G. WoodruffReaction modeling of drainage quality in the Duluth Complex, northern Minnesota, USA
Reaction modeling can be a valuable tool in predicting the long-term behavior of waste material if representative rate constants can be derived from long-term leaching tests or other approaches. Reaction modeling using the REACT program of the Geochemist’s Workbench was conducted to evaluate long-term drainage quality affected by disseminated Cu-Ni-(Co-)-PGM sulfide mineralization in the basal zonAuthorsRobert Seal, Kim Lapakko, Nadine M. Piatak, Laurel G. WoodruffMagmatic sulfide-rich nickel-copper deposits related to picrite and (or) tholeiitic basalt dike-sill complexes: A preliminary deposit model
Magmatic sulfide deposits containing nickel (Ni) and copper (Cu), with or without (±) platinum-group elements (PGEs), account for approximately 60 percent of the world’s Ni production and are active exploration targets in the United States and elsewhere. On the basis of their principal metal production, magmatic sulfide deposits in mafic rocks can be divided into two major types: those that are suAuthorsKlaus J. Schulz, Val W. Chandler, Suzanne W. Nicholson, Nadine M. Piatak, Robert R. Seal, Laurel G. Woodruff, Michael L. Zientek - News
Below are news stories associated with this project.
- Partners
In addition to the USGS Columbia Environmental Resource Center and Water Science Centers in Illinois, Indiana, Minnesota, and Wisconsin, below are external partners associated with this project.