The Hells Canyon Complex (HCC) is the largest privately owned hydroelectric power complex in the United States. Upstream are millions of acres of irrigated agricultural lands and Idaho’s largest metropolitan area clustered around the state capital Boise. Downstream lie confluences with the Salmon and Clearwater Rivers, critical habitat for threatened bull trout and fall chinook salmon.
Elevated concentrations of mercury and methylmercury in the water column, bottom sediments, and biota in this reach have resulted in two of the reservoirs, Brownlee and Hells Canyon, being listed as impaired for mercury by the state of Idaho, and the entire reach being listed as impaired for mercury by the state of Oregon. The objective of this study is to determine key processes controlling mercury transport, cycling, and bioaccumulation in the Hells Canyon Reach of the Snake River.

Although concentrations of inorganic mercury entering the HCC are typical in comparison to other sites in the U.S., biogeochemical conditions in Brownlee Reservoir, and to a lesser extent, Hells Canyon Reservoir, effectively promote the conversion of some of the mercury into the more toxic and bioaccumulative form, methylmercury. Fish tissue samples regularly exceed human health criteria for methylmercury set by states, such as Oregon and Idaho, and by the U.S. Environmental Protection Agency. Exposure to too much methylmercury can affect the human nervous system and can hamper a child’s development both in the womb and in early life.
A proposal to use cold water from Brownlee Reservoir’s lower layer to cool the Snake River downstream of the HCC raised concerns about exposing sensitive aquatic species to methylmercury-rich waters from deep in the reservoir. In 2012, the Idaho Water Science Center, with help from the Wisconsin Water Science Center, confirmed elevated mercury concentrations in water column and bed sediment core samples. In 2014, Idaho Power Company, the owner and operator of the HCC, asked the USGS for help to better understand the mercury dynamics in the reservoirs and how the proposed reservoir operations might affect downstream transport of methylmercury.
The scale of the study area and the multitude of research questions required a multidisciplinary approach. USGS Idaho Water Science Center hydrologist Greg Clark, who has since retired, invited Dave Krabbenhoft, leader of the USGS Mercury Research Laboratory, to help form a study team. As Dave puts it, “When Greg Clark and I started this effort, we had the opportunity to hand pick an all-star team, and we did!” Today, that team of USGS hydrologists, biologists, ecologists, chemists, and technicians from five states works alongside colleagues from the Idaho Power Company, Reed Harris Environmental, the University of Wisconsin, and Portland State University.
The hydrologic component of the study focuses on the mass loading of mercury and methylmercury into, within, and out of the HCC to better understand the hydrologic processes promoting methylmercury production and the fate of that methylmercury as the large reservoirs stratify and destratify seasonally. This part of the research team is composed primarily of scientists from the USGS Idaho and Wisconsin Water Science Centers and the Water Mission Area (WMA).

The biological component of the study is examining how methylmercury is bioaccumulating—and biomagnifying—through the food web from phytoplankton to predator sportfish such as largemouth bass. The biological research is led by Collin Eagles-Smith of the USGS Forest and Rangeland Ecosystem Science Center.
The geochemical component of the study is seeking to pinpoint mercury sources and to peer inside the processes of mercury methylation. This portion of the study is led by Dave Krabbenhoft, by Mark Marvin-DiPasquale of the USGS Water Resources Mission Area, and by Brett Poulin of the University of California-Davis.
The team is also developing a simulation model to help understand the present-day behavior of mercury in Hells Canyon Complex, especially factors leading to increases in fish mercury levels in the complex and predict the response of the system (and downstream) to future reservoir management scenarios. Mercury cycling is being added to CE-QUAL-W2, a well-established model originally developed by the US Army Corps of Engineers and maintained by Portland State University, that simulates hydrodynamics and water quality. The model will simulate mercury in water, sediments, and the food web.

As the Hells Canyon study continues, the project serves as a prime example of how integrated USGS science can bring nationwide expertise to bear on a significant issue of regional concern. It also shows how the USGS can collaborate effectively with academia and the private sector to help solve economic, environmental, and societal challenges.
Read our 2022 information sheet USGS Science to Protect Wildlife and Human Health (PDF)
The following data are associated with this project.
Mercury Stable Isotope Measurements in Water and Suspended Particulate Matter from Snake River Tributaries in Idaho and Oregon, USA
Hydrological, Chemical, and Biological Characterization of the Snake River and Associated Tributaries and Irrigation Drains from River Mile 448 to 346, 2022
Mercury in smallmouth bass from the Snake River, USA (ver. 2.0, January 2025)
Biomass and methylmercury concentrations in biweekly biological samples from Brownlee and Oxbow Reservoir outflows, Snake River Hells Canyon Complex (Idaho-Oregon), 2018-2019
Chemical characterization of water and suspended sediment of the Snake River and Hells Canyon Complex (Idaho, Oregon) (ver. 3.0, November 2023)
Biogeochemical Data for Mercury and other Constituents in Surface Sediment and Deep Cores from the Hells Canyon Reservoir Complex, Idaho and Oregon 2014-2018
The following publications are associated with this project.
Contrasting magnitude and timing of pulsed aqueous methylmercury bioaccumulation across a reservoir food web
Longitudinal and seasonal changes of organic matter sources through a semi-arid river-reservoir system
Riparian methylmercury production increases riverine mercury flux and food web concentrations
Reservoir stratification modulates the influence of impoundments on fish mercury concentrations along an arid land river system
Mercury sources and budget for the Snake River above a hydroelectric reservoir complex
Metabolically diverse microorganisms mediate methylmercury formation under nitrate-reducing conditions in a dynamic hydroelectric reservoir
In-reservoir physical processes modulate aqueous and biological methylmercury export from a seasonally anoxic reservoir
Seasonal dynamics and interannual variability in mercury concentrations and loads through a three-reservoir complex
Mercury cycling in the Hells Canyon Complex of the Snake River, Idaho and Oregon
Archive of digital chirp subbottom profile data collected during USGS Cruise 13GFP01, Brownlee Dam and Hells Canyon Reservoir, Idaho and Oregon, 2013
Seismic profile analysis of sediment deposits in Brownlee and Hells Canyon Reservoirs near Cambridge, Idaho
Water column and bed-sediment core samples collected from Brownlee Reservoir near Oxbow, Oregon, 2012
These news items are related to this study.
Below are partners associated with this project.
The Hells Canyon Complex (HCC) is the largest privately owned hydroelectric power complex in the United States. Upstream are millions of acres of irrigated agricultural lands and Idaho’s largest metropolitan area clustered around the state capital Boise. Downstream lie confluences with the Salmon and Clearwater Rivers, critical habitat for threatened bull trout and fall chinook salmon.
Elevated concentrations of mercury and methylmercury in the water column, bottom sediments, and biota in this reach have resulted in two of the reservoirs, Brownlee and Hells Canyon, being listed as impaired for mercury by the state of Idaho, and the entire reach being listed as impaired for mercury by the state of Oregon. The objective of this study is to determine key processes controlling mercury transport, cycling, and bioaccumulation in the Hells Canyon Reach of the Snake River.

Although concentrations of inorganic mercury entering the HCC are typical in comparison to other sites in the U.S., biogeochemical conditions in Brownlee Reservoir, and to a lesser extent, Hells Canyon Reservoir, effectively promote the conversion of some of the mercury into the more toxic and bioaccumulative form, methylmercury. Fish tissue samples regularly exceed human health criteria for methylmercury set by states, such as Oregon and Idaho, and by the U.S. Environmental Protection Agency. Exposure to too much methylmercury can affect the human nervous system and can hamper a child’s development both in the womb and in early life.
A proposal to use cold water from Brownlee Reservoir’s lower layer to cool the Snake River downstream of the HCC raised concerns about exposing sensitive aquatic species to methylmercury-rich waters from deep in the reservoir. In 2012, the Idaho Water Science Center, with help from the Wisconsin Water Science Center, confirmed elevated mercury concentrations in water column and bed sediment core samples. In 2014, Idaho Power Company, the owner and operator of the HCC, asked the USGS for help to better understand the mercury dynamics in the reservoirs and how the proposed reservoir operations might affect downstream transport of methylmercury.
The scale of the study area and the multitude of research questions required a multidisciplinary approach. USGS Idaho Water Science Center hydrologist Greg Clark, who has since retired, invited Dave Krabbenhoft, leader of the USGS Mercury Research Laboratory, to help form a study team. As Dave puts it, “When Greg Clark and I started this effort, we had the opportunity to hand pick an all-star team, and we did!” Today, that team of USGS hydrologists, biologists, ecologists, chemists, and technicians from five states works alongside colleagues from the Idaho Power Company, Reed Harris Environmental, the University of Wisconsin, and Portland State University.
The hydrologic component of the study focuses on the mass loading of mercury and methylmercury into, within, and out of the HCC to better understand the hydrologic processes promoting methylmercury production and the fate of that methylmercury as the large reservoirs stratify and destratify seasonally. This part of the research team is composed primarily of scientists from the USGS Idaho and Wisconsin Water Science Centers and the Water Mission Area (WMA).

The biological component of the study is examining how methylmercury is bioaccumulating—and biomagnifying—through the food web from phytoplankton to predator sportfish such as largemouth bass. The biological research is led by Collin Eagles-Smith of the USGS Forest and Rangeland Ecosystem Science Center.
The geochemical component of the study is seeking to pinpoint mercury sources and to peer inside the processes of mercury methylation. This portion of the study is led by Dave Krabbenhoft, by Mark Marvin-DiPasquale of the USGS Water Resources Mission Area, and by Brett Poulin of the University of California-Davis.
The team is also developing a simulation model to help understand the present-day behavior of mercury in Hells Canyon Complex, especially factors leading to increases in fish mercury levels in the complex and predict the response of the system (and downstream) to future reservoir management scenarios. Mercury cycling is being added to CE-QUAL-W2, a well-established model originally developed by the US Army Corps of Engineers and maintained by Portland State University, that simulates hydrodynamics and water quality. The model will simulate mercury in water, sediments, and the food web.

As the Hells Canyon study continues, the project serves as a prime example of how integrated USGS science can bring nationwide expertise to bear on a significant issue of regional concern. It also shows how the USGS can collaborate effectively with academia and the private sector to help solve economic, environmental, and societal challenges.
Read our 2022 information sheet USGS Science to Protect Wildlife and Human Health (PDF)
The following data are associated with this project.
Mercury Stable Isotope Measurements in Water and Suspended Particulate Matter from Snake River Tributaries in Idaho and Oregon, USA
Hydrological, Chemical, and Biological Characterization of the Snake River and Associated Tributaries and Irrigation Drains from River Mile 448 to 346, 2022
Mercury in smallmouth bass from the Snake River, USA (ver. 2.0, January 2025)
Biomass and methylmercury concentrations in biweekly biological samples from Brownlee and Oxbow Reservoir outflows, Snake River Hells Canyon Complex (Idaho-Oregon), 2018-2019
Chemical characterization of water and suspended sediment of the Snake River and Hells Canyon Complex (Idaho, Oregon) (ver. 3.0, November 2023)
Biogeochemical Data for Mercury and other Constituents in Surface Sediment and Deep Cores from the Hells Canyon Reservoir Complex, Idaho and Oregon 2014-2018
The following publications are associated with this project.
Contrasting magnitude and timing of pulsed aqueous methylmercury bioaccumulation across a reservoir food web
Longitudinal and seasonal changes of organic matter sources through a semi-arid river-reservoir system
Riparian methylmercury production increases riverine mercury flux and food web concentrations
Reservoir stratification modulates the influence of impoundments on fish mercury concentrations along an arid land river system
Mercury sources and budget for the Snake River above a hydroelectric reservoir complex
Metabolically diverse microorganisms mediate methylmercury formation under nitrate-reducing conditions in a dynamic hydroelectric reservoir
In-reservoir physical processes modulate aqueous and biological methylmercury export from a seasonally anoxic reservoir
Seasonal dynamics and interannual variability in mercury concentrations and loads through a three-reservoir complex
Mercury cycling in the Hells Canyon Complex of the Snake River, Idaho and Oregon
Archive of digital chirp subbottom profile data collected during USGS Cruise 13GFP01, Brownlee Dam and Hells Canyon Reservoir, Idaho and Oregon, 2013
Seismic profile analysis of sediment deposits in Brownlee and Hells Canyon Reservoirs near Cambridge, Idaho
Water column and bed-sediment core samples collected from Brownlee Reservoir near Oxbow, Oregon, 2012
These news items are related to this study.
Below are partners associated with this project.