Mine Drainage and Water Quality Research
Completed
By Pennsylvania Water Science Center
February 18, 2025
USGS conducts research on geochemical and hydrological processes that control water quality, including the sources, transport, and attenuation of metals and nutrients in undisturbed and mining-impacted watersheds and aquifers.
Results apply to scientific and regulatory programs for the prevention and remediation of aquatic contamination.
Media
Sources/Usage: Public Domain. View Media Details
Treatment Stage:
0-Untreated
1-Sedimentation Pond
2-Aeration Cascade
3-Aerobic Pond
4-Aeration Cascade
5-Aerobic Pond
6-Riprap Cascade
7-Aerobic Wetland
8-Riprap Cascade
9-Aerobic Wetland
10-Riprap
Filter Total Items: 27
AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume
Alkaline chemicals are commonly added to discharges from coal mines to increase pH and decrease concentrations of acidity and dissolved aluminum, iron, manganese, and associated metals. The annual cost of chemical treatment depends on the type and quantities of chemicals added and sludge produced. The AMDTreat computer program, initially developed in 2003, is widely used to compute such...
Authors
Charles A. Cravotta, Brent P Means, Willam Arthur, Robert M McKenzie, David L. Parkhurst
Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA
Clean sampling and analysis procedures were used to quantify more than 70 inorganic constituents, including 35 potentially toxic or hazardous constituents, organic carbon, and other characteristics of untreated (influent) and treated (effluent) coal-mine discharges (CMD) at 38 permitted coal-mining or coal-processing facilities in the bituminous coalfield and 4 facilities in the...
Authors
III Cravotta, Keith B.C. Brady
Spectral masking of goethite in abandoned mine drainage systems: implications for Mars Spectral masking of goethite in abandoned mine drainage systems: implications for Mars
Remote sensing studies of the surface of Mars use visible- to near-infrared (VNIR) spectroscopy to identify hydrated and hydroxylated minerals, which can be used to constrain past environmental conditions on the surface of Mars. However, due to differences in optical properties, some hydrated phases can mask others in VNIR spectra, complicating environmental interpretations. Here, we...
Authors
Selby Cull, Charles A. Cravotta, Julia Grace Klinges, Chloe Weeks
Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA
Streams crossing underground coal mines may lose flow, while abandoned mine drainage (AMD) restores flow downstream. During 2005-12, discharge from the Pine Knot Mine Tunnel, the largest AMD source in the upper Schuylkill River Basin, had near-neutral pH and elevated concentrations of iron, manganese, and sulfate. Discharge from the tunnel responded rapidly to recharge but exhibited a...
Authors
Charles A. Cravotta, Daniel J. Goode, Michael D. Bartles, Dennis W. Risser, Daniel G. Galeone
Evolution of the chemistry of Fe bearing waters during CO2 degassing Evolution of the chemistry of Fe bearing waters during CO2 degassing
The rates of Fe(II) oxidation and precipitation from groundwater are highly pH dependent. Elevated levels of dissolved CO2 can depress pH and cause difficulty in removing dissolved Fe and associated metals during treatment of ferruginous water. This paper demonstrates interdependent changes in pH, dissolved inorganic C species, and Fe(II) oxidation rates that occur as a result of the...
Authors
J.N. Geroni, C.A. Cravotta, D.J. Sapsford
Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs
This report, prepared in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), the Eastern Pennsylvania Coalition for Abandoned Mine Reclamation, and the Dauphin County Conservation District, provides estimates of water budgets and groundwater volumes stored in abandoned underground mines in the Western Middle Anthracite Coalfield, which encompasses an area of...
Authors
Daniel J. Goode, Charles A. Cravotta, Roger J. Hornberger, Michael A. Hewitt, Robert E. Hughes, Daniel J. Koury, Lee W. Eicholtz
Utilization of AMD sludges from the anthracite region of Pennsylvania for removal of phosphorus from wastewater Utilization of AMD sludges from the anthracite region of Pennsylvania for removal of phosphorus from wastewater
Excess phosphorus (P) inputs from human sewage, animal feeding operations, and nonpoint source discharges to the environment have resulted in the eutrophication of sensitive receiving bodies of water such as the Great Lakes and Chesapeake Bay. Phosphorus loads in wastewater discharged from such sources can be decreased by conventional treatment with iron and aluminum salts but these
Authors
P.L. Sibrell, C.A. Cravotta, W.G. Lehman, W. Reichert
A geochemical module for "AMDTreat" to compute caustic quantity, effluent quantity, and sludge volume A geochemical module for "AMDTreat" to compute caustic quantity, effluent quantity, and sludge volume
Treatment with caustic chemicals typically is used to increase pH and decrease concentrations of dissolved aluminum, iron, and/or manganese in largevolume, metal-laden discharges from active coal mines. Generally, aluminum and iron can be removed effectively at near-neutral pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment cost depends...
Authors
Charles A. Cravotta, David L. Parkhurst, Brent P Means, Bob McKenzie, Harry Morris, Bill Arthur
Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems
A variety of passive and semi-passive treatment systems were constructed by state and local agencies to neutralize acidic mine drainage (AMD) and reduce the transport of dissolved metals in the upper Swatara Creek Basin in the Southern Anthracite Coalfield in eastern Pennsylvania. To evaluate the effectiveness of selected treatment systems installed during 1995–2001, the US Geological...
Authors
Charles A. Cravotta
Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 1. stream quality trends coinciding with the return of fish Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 1. stream quality trends coinciding with the return of fish
Acidic mine drainage (AMD) from legacy anthracite mines has contaminated Swatara Creek in eastern Pennsylvania. Intermittently collected base-flow data for 1959–1986 indicate that fish were absent immediately downstream from the mined area where pH ranged from 3.5 to 7.2 and concentrations of sulfate, dissolved iron, and dissolved aluminum were as high as 250, 2.0, and 4.7 mg/L...
Authors
Charles A. Cravotta, Robin A. Brightbill, Michael J. Langland
Characterization of rock samples and mineralogical controls on leachates Characterization of rock samples and mineralogical controls on leachates
Rocks associated with coal beds typically include shale, sandstone, and (or) limestone. In addition to common rock-forming minerals, all of these rock types may contain sulfide and sulfate minerals, various carbonate minerals, and organic material. These different minerals have inherently different solubility characteristics, as well as different acid-generating or acid-neutralizing...
Authors
Jane M. Hammarstrom, Charles A. Cravotta, Daniel G. Galeone, John C. Jackson, Frank T. Dulong
Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded anthracite mine, Pennsylvania, USA: 2. Laboratory evaluation Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded anthracite mine, Pennsylvania, USA: 2. Laboratory evaluation
Acidic mine drainage (AMD) containing elevated concentrations of dissolved iron and other metals can be neutralized to varying degrees by reactions with limestone in passive treatment systems. We evaluated the chemical and mineralogical characteristics and the effectiveness of calcitic and dolomitic limestone for the neutralization of net-acidic, oxic, iron-laden AMD from a flooded...
Authors
C.A. Cravotta, S.J. Ward, J. M. Hammarstrom
USGS conducts research on geochemical and hydrological processes that control water quality, including the sources, transport, and attenuation of metals and nutrients in undisturbed and mining-impacted watersheds and aquifers.
Results apply to scientific and regulatory programs for the prevention and remediation of aquatic contamination.
Media
Sources/Usage: Public Domain. View Media Details
Treatment Stage:
0-Untreated
1-Sedimentation Pond
2-Aeration Cascade
3-Aerobic Pond
4-Aeration Cascade
5-Aerobic Pond
6-Riprap Cascade
7-Aerobic Wetland
8-Riprap Cascade
9-Aerobic Wetland
10-Riprap
Filter Total Items: 27
AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume AMDTreat 5.0+ with PHREEQC titration module to compute caustic chemical quantity, effluent quality, and sludge volume
Alkaline chemicals are commonly added to discharges from coal mines to increase pH and decrease concentrations of acidity and dissolved aluminum, iron, manganese, and associated metals. The annual cost of chemical treatment depends on the type and quantities of chemicals added and sludge produced. The AMDTreat computer program, initially developed in 2003, is widely used to compute such...
Authors
Charles A. Cravotta, Brent P Means, Willam Arthur, Robert M McKenzie, David L. Parkhurst
Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA
Clean sampling and analysis procedures were used to quantify more than 70 inorganic constituents, including 35 potentially toxic or hazardous constituents, organic carbon, and other characteristics of untreated (influent) and treated (effluent) coal-mine discharges (CMD) at 38 permitted coal-mining or coal-processing facilities in the bituminous coalfield and 4 facilities in the...
Authors
III Cravotta, Keith B.C. Brady
Spectral masking of goethite in abandoned mine drainage systems: implications for Mars Spectral masking of goethite in abandoned mine drainage systems: implications for Mars
Remote sensing studies of the surface of Mars use visible- to near-infrared (VNIR) spectroscopy to identify hydrated and hydroxylated minerals, which can be used to constrain past environmental conditions on the surface of Mars. However, due to differences in optical properties, some hydrated phases can mask others in VNIR spectra, complicating environmental interpretations. Here, we...
Authors
Selby Cull, Charles A. Cravotta, Julia Grace Klinges, Chloe Weeks
Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA
Streams crossing underground coal mines may lose flow, while abandoned mine drainage (AMD) restores flow downstream. During 2005-12, discharge from the Pine Knot Mine Tunnel, the largest AMD source in the upper Schuylkill River Basin, had near-neutral pH and elevated concentrations of iron, manganese, and sulfate. Discharge from the tunnel responded rapidly to recharge but exhibited a...
Authors
Charles A. Cravotta, Daniel J. Goode, Michael D. Bartles, Dennis W. Risser, Daniel G. Galeone
Evolution of the chemistry of Fe bearing waters during CO2 degassing Evolution of the chemistry of Fe bearing waters during CO2 degassing
The rates of Fe(II) oxidation and precipitation from groundwater are highly pH dependent. Elevated levels of dissolved CO2 can depress pH and cause difficulty in removing dissolved Fe and associated metals during treatment of ferruginous water. This paper demonstrates interdependent changes in pH, dissolved inorganic C species, and Fe(II) oxidation rates that occur as a result of the...
Authors
J.N. Geroni, C.A. Cravotta, D.J. Sapsford
Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs
This report, prepared in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), the Eastern Pennsylvania Coalition for Abandoned Mine Reclamation, and the Dauphin County Conservation District, provides estimates of water budgets and groundwater volumes stored in abandoned underground mines in the Western Middle Anthracite Coalfield, which encompasses an area of...
Authors
Daniel J. Goode, Charles A. Cravotta, Roger J. Hornberger, Michael A. Hewitt, Robert E. Hughes, Daniel J. Koury, Lee W. Eicholtz
Utilization of AMD sludges from the anthracite region of Pennsylvania for removal of phosphorus from wastewater Utilization of AMD sludges from the anthracite region of Pennsylvania for removal of phosphorus from wastewater
Excess phosphorus (P) inputs from human sewage, animal feeding operations, and nonpoint source discharges to the environment have resulted in the eutrophication of sensitive receiving bodies of water such as the Great Lakes and Chesapeake Bay. Phosphorus loads in wastewater discharged from such sources can be decreased by conventional treatment with iron and aluminum salts but these
Authors
P.L. Sibrell, C.A. Cravotta, W.G. Lehman, W. Reichert
A geochemical module for "AMDTreat" to compute caustic quantity, effluent quantity, and sludge volume A geochemical module for "AMDTreat" to compute caustic quantity, effluent quantity, and sludge volume
Treatment with caustic chemicals typically is used to increase pH and decrease concentrations of dissolved aluminum, iron, and/or manganese in largevolume, metal-laden discharges from active coal mines. Generally, aluminum and iron can be removed effectively at near-neutral pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment cost depends...
Authors
Charles A. Cravotta, David L. Parkhurst, Brent P Means, Bob McKenzie, Harry Morris, Bill Arthur
Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems
A variety of passive and semi-passive treatment systems were constructed by state and local agencies to neutralize acidic mine drainage (AMD) and reduce the transport of dissolved metals in the upper Swatara Creek Basin in the Southern Anthracite Coalfield in eastern Pennsylvania. To evaluate the effectiveness of selected treatment systems installed during 1995–2001, the US Geological...
Authors
Charles A. Cravotta
Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 1. stream quality trends coinciding with the return of fish Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 1. stream quality trends coinciding with the return of fish
Acidic mine drainage (AMD) from legacy anthracite mines has contaminated Swatara Creek in eastern Pennsylvania. Intermittently collected base-flow data for 1959–1986 indicate that fish were absent immediately downstream from the mined area where pH ranged from 3.5 to 7.2 and concentrations of sulfate, dissolved iron, and dissolved aluminum were as high as 250, 2.0, and 4.7 mg/L...
Authors
Charles A. Cravotta, Robin A. Brightbill, Michael J. Langland
Characterization of rock samples and mineralogical controls on leachates Characterization of rock samples and mineralogical controls on leachates
Rocks associated with coal beds typically include shale, sandstone, and (or) limestone. In addition to common rock-forming minerals, all of these rock types may contain sulfide and sulfate minerals, various carbonate minerals, and organic material. These different minerals have inherently different solubility characteristics, as well as different acid-generating or acid-neutralizing...
Authors
Jane M. Hammarstrom, Charles A. Cravotta, Daniel G. Galeone, John C. Jackson, Frank T. Dulong
Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded anthracite mine, Pennsylvania, USA: 2. Laboratory evaluation Downflow limestone beds for treatment of net-acidic, oxic, iron-laden drainage from a flooded anthracite mine, Pennsylvania, USA: 2. Laboratory evaluation
Acidic mine drainage (AMD) containing elevated concentrations of dissolved iron and other metals can be neutralized to varying degrees by reactions with limestone in passive treatment systems. We evaluated the chemical and mineralogical characteristics and the effectiveness of calcitic and dolomitic limestone for the neutralization of net-acidic, oxic, iron-laden AMD from a flooded...
Authors
C.A. Cravotta, S.J. Ward, J. M. Hammarstrom