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Geochemical heterogeneity of a gasoline-contaminated aquifer Geochemical heterogeneity of a gasoline-contaminated aquifer

The scale of biogeochemical reactions was studied in a physically and chemically heterogeneous surficial Coastal Plain aquifer contaminated by a gasoline spill. The physical heterogeneity of the aquifer is manifested in two hydrologic units, a shallow local aquifer of perched water and a regional sandy aquifer. Over the studied vertical interval of 21.3 ft (6.5 m), concentrations of...
Authors
Isabelle Cozzarelli, Janet Herman, Mary Baedecker, Jeffrey M. Fischer

Ground water contamination by crude oil near Bemidji, Minnesota Ground water contamination by crude oil near Bemidji, Minnesota

Ground-water contamination by crude oil, and other petroleum-based liquids, is a widespread problem. An average of 83 crude-oil spills occurred per year during 1994-96 in the United States, each spilling about 50,000 barrels of crude oil (U.S. Office of Pipeline Safety, electronic commun., 1997). An understanding of the fate of organic contaminants (such as oil and gasoline) in the...
Authors
G. N. Delin, H.I. Essaid, I.M. Cozzarelli, M.H. Lahvis, B.A. Bekins

Simulation of aerobic and anaerobic biodegradation processes at a crude oil spill site Simulation of aerobic and anaerobic biodegradation processes at a crude oil spill site

A two-dimensional, multispecies reactive solute transport model with sequential aerobic and anaerobic degradation processes was developed and tested. The model was used to study the field-scale solute transport and degradation processes at the Bemidji, Minnesota, crude oil spill site. The simulations included the biodegradation of volatile and nonvolatile fractions of dissolved organic...
Authors
Hedeff Essaid, Barbara Bekins, E. Godsy, Ean Warren, Mary Baedecker, Isabelle Cozzarelli

Fate of microbial metabolites of hydrocarbons in a coastal plain aquifer: The role of electron acceptors Fate of microbial metabolites of hydrocarbons in a coastal plain aquifer: The role of electron acceptors

A combined field and laboratory study was undertaken to understand the distribution and geochemical conditions that influence the prevalence of low molecular weight organic acids in groundwater of a shallow aquifer contaminated with gasoline. Aromatic hydrocarbons from gasoline were degraded by microbially mediated oxidation-reduction reactions, including reduction of nitrate, sulfate...
Authors
I.M. Cozzarelli, J.S. Herman, M. Baedecker

U.S. Geological Survey yearbook, fiscal year 1993: At work across the Nation U.S. Geological Survey yearbook, fiscal year 1993: At work across the Nation

The need for earth science has never been more paramount. The devastating flooding of the Mississippi River this past year, strikingly portrayed on the cover and discussed in detail in this report (p. 37-42), was a sobering reminder of nature's elemental power. As a Nation, we face many environmental and economic challenges, such as natural hazards, that can be addressed effectively only...
Authors
Water Resources Division U.S. Geological Survey

The geochemical evolution of low-molecular-weight organic acids derived from the degradation of petroleum contaminants in groundwater The geochemical evolution of low-molecular-weight organic acids derived from the degradation of petroleum contaminants in groundwater

The geochemical evolution of low-molecular-weight organic acids in groundwater downgradient from a crude-oil spill near Bemidji, Minnesota, was studied over a five year period (1986–1990). The organic acids are metabolic intermediates of the degradation of components of the crude oil and are structurally related to hydrocarbon precursors. The concentrations of organic acids, particularly...
Authors
I.M. Cozzarelli, M.J. Baedecker, R.P. Eganhouse, D.F. Goerlitz

Crude oil in a shallow sand and gravel aquifer-II. Organic geochemistry Crude oil in a shallow sand and gravel aquifer-II. Organic geochemistry

Crude oil spilled from a pipeline break in a remote area of north-central Minnesota has contaminated a shallow glacial outwash aquifer. Part of the oil was sprayed over a large area to the west of the pipeline and part of it accumulated in an oil body that floats at the water table to the east of the point of discharge. Total dissolved organic carbon (TDOC) concentrations in shallow...
Authors
R.P. Eganhouse, M.J. Baedecker, I.M. Cozzarelli, G. R. Aiken, K. Thorn, T.F. Dorsey

Crude oil in a shallow sand and gravel aquifer-III. Biogeochemical reactions and mass balance modeling in anoxic groundwater Crude oil in a shallow sand and gravel aquifer-III. Biogeochemical reactions and mass balance modeling in anoxic groundwater

Crude oil floating on the water table in a sand and gravel aquifer provides a constant source of hydrocarbons to the groundwater at a site near Bemidji, Minnesota. The degradation of hydrocarbons affects the concentrations of oxidized and reduced aqueous species in the anoxic part of the contaminant plume that developed downgradient from the oil body. The concentrations of Fe2+, Mn2+ and...
Authors
M.J. Baedecker, I.M. Cozzarelli, R.P. Eganhouse, D. Siegel, P.C. Bennett
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