Publications

Several geochemical properties of an aquifer sediment that control metal-ion adsorption were investigated to determine their potential use as indicators of the spatial variability of metal adsorption. Over the length of a 4.5-m-long core from a sand and gravel aquifer, lead (Pb2+) and zinc (Zn2+) adsorption at constant chemical conditions (pH 5.3) varied by a factor of 2 and 4...

Quantitative analysis of geophysical logs in ground-water studies often involves at least as broad a range of applications and variation in lithology as is typically encountered in petroleum exploration, making such logs difficult to calibrate and complicating inversion problem formulation. At the same time, data inversion and analysis depend on inversion model formulation and refinement...

A nonnormal and heteroscedastic Tobit model is used to determine the primary factors that affect nitrate concentrations in near-surface aquifers, using data from the U.S. Geological Survey collected in 1991. Both normality and homoscedasticity of errors are rejected, justifying the use of a nonnormal and heteroscedastic model. The following factors are found to have significant impacts...

Uranium adsorption on ferrihydrite was studied as a function of pH in systems equilibrated with air, in the presence and absence of added phosphate and humic acid (HA). The objective was to determine the influence of PO43- and HA on uranium uptake. Below pH 7, the sorption of UO22+ typically increases with increasing pH (the 'low pH sorption edge'), with a sharp decrease in sorption...

The reaction kinetics for the covalent binding of aniline with reconstituted IHSS humic and fulvic acids, unfractionated DOM isolated from Suwannee River water, and whole samples of Suwannee River water have been investigated. The reaction kinetics in each of these systems can be adequately described by a simple second-order rate expression. The effect of varying the initial...

Detailed vertical sampling is useful in aquifers where vertical mixing is limited and steep vertical gradients in chemical concentrations are expected. Samples can be collected at closely spaced vertical intervals from nested wells with short screened intervals. However, this approach may not be appropriate in all situations. An easy-to-construct and easy-to-install multiport sampling...

Ground water in terrace deposits of the South Platte River alluvial aquifer near Greeley, Colorado, USA, had a median nitrate concentration of 1857 μmol l−1. Median nitrate concentrations in ground water from adjacent floodplain deposits (468 μmol l−1) and riverbed sediments (461 μmol l−1), both of which are downgradient from the terrace deposits, were lower than the median concentration...

No abstract available.

Marine ecosystems include a subset in which at least some interrelated geochemical, biochemical, physiological, population and community characteristics are changed by pollutants. Moderate contamination is relatively widespread in coastal and estuarine ecosystems, so the subset of ecosystems with at least some processes affected could be relatively large. Pollutant influences have...

Phytoplankton blooms are prominent features of biological variability in shallow coastal ecosystems such as estuaries, lagoons, bays, and tidal rivers. Long-term observation and research in San Francisco Bay illustrates some patterns of phytoplankton spatial and temporal variability and the underlying mechanisms of this variability. Blooms are events of rapid production and accumulation...

No abstract available.

Ground-water flow in glacial sediments and bedrock at Picatinny Arsenal, N.J., was simulated by use of a three-dimensional finite-difference ground- water-flow model. The modeled area includes a 4.3-square-mile area that extends from Picatinny Lake to the Rockaway River. Most of the study area is bounded by the natural hydrologic boundaries of the ground-water system. eophysical logs...