Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 4098
Nitrate is a preferred electron acceptor for growth of freshwater selenate-respiring bacteria Nitrate is a preferred electron acceptor for growth of freshwater selenate-respiring bacteria
An anaerobic, freshwater enrichment grew with either nitrate or selenate as an electron acceptor. With both ions present, nitrate reduction preceded selenate reduction. An isolate from the enrichment grew on either ion, but the presence of nitrate precluded the reduction of selenate. Stock cultures of denitrifiers grew anaerobically on nitrate but not on selenate.
Authors
Nisan A. Steinberg, Jodi Switzer Blum, Lawrence Hochstein, Ronald S. Oremland
Tensiometers: Theory, construction, and use Tensiometers: Theory, construction, and use
Standard tensiometers are used to measure matric potential as low as −870 cm of water in the unsaturated zone by creating a saturated hydraulic link between the soil water and a pressure sensor. The direction and, in some cases, quantity of water flux can be determined using multiple installations. A variety of commercial and fabricated tensiometers are commonly used. Saturated porous...
Authors
D.I. Stannard
Geochemical heterogeneity in a sand and gravel aquifer: Effect of sediment mineralogy and particle size on the sorption of chlorobenzenes Geochemical heterogeneity in a sand and gravel aquifer: Effect of sediment mineralogy and particle size on the sorption of chlorobenzenes
The effect of particle size, mineralogy and sediment organic carbon (SOC) on sorption of tetrachlorobenzene and pentachlorobenzene was evaluated using batch-isotherm experiments on sediment particle-size and mineralogical fractions from a sand and gravel aquifer, Cape Cod, Massachusetts. Concentration of SOC and sorption of chlorobenzenes increase with decreasing particle size. For a...
Authors
Larry B. Barber, E. Michael Thurman, Donald D. Runnells
Nitrogen-15 and carbon-13 NMR investigation of hydroxylamine-derivatized humic substances Nitrogen-15 and carbon-13 NMR investigation of hydroxylamine-derivatized humic substances
No abstract available.
Authors
Kevin A. Thorn, Jeffrey B. Arterburn, Michael A. Mikita
Sampling vadose-zone water for a volatile organic compound at Picatinny Arsenal, New Jersey Sampling vadose-zone water for a volatile organic compound at Picatinny Arsenal, New Jersey
A new method of collecting samples of unsaturated-zone water for quantitative analysis for a volatile organic compound, trichloroethene (TCE), was compared to three other, previously described sampling methodologies in the laboratory and in the field. In the laboratory, prepared water samples containing TCE in a known concentration (20 µg/L) were sampled repeatedly by using each of the...
Authors
James A. Smith, H. Jean Cho, Peter R. Jaffe, Cecilia L. MacLeod, Susan A. Koehnlein
A critical review of inductively coupled plasma-mass spectrometry for geoanalysis, geochemistry and hydrology, Part 1. Analytical performance A critical review of inductively coupled plasma-mass spectrometry for geoanalysis, geochemistry and hydrology, Part 1. Analytical performance
Present-day inductively coupled plasma-mass spectrometry (ICP-MS) instrumentation is described briefly. Emphasis is placed on performance characteristics for geoanalysis, geochemistry, and hydrology. Applications where ICP-MS would be indispensable are indicated. Determination of geochemically diagnostic trace elements (such as the rare earth elements [REE], U and Th), of isotope ratios...
Authors
I.B. Brenner, Howard E. Taylor
Associations of free-living bacteria and dissolved organic compounds in a plume of contaminated groundwater Associations of free-living bacteria and dissolved organic compounds in a plume of contaminated groundwater
Associations of free-living bacteria (FLB) and dissolved organic contaminants in a 4-km-long plume of sewage-contaminated groundwater were investigated. Abundance of FLB in the core of the plume (as delineated by maximum specific conductance) steadily decreased in the direction of flow from a point 0.25 km downgradient from the source to the toe of the plume. At 0.25 km downgradient, FLB...
Authors
Ronald W. Harvey, Larry B. Barber
Bioaccumulation of hydrocarbons derived from terrestrial and anthropogenic sources in the Asian clam, Potamocorbula amurensis, in San Francisco Bay estuary Bioaccumulation of hydrocarbons derived from terrestrial and anthropogenic sources in the Asian clam, Potamocorbula amurensis, in San Francisco Bay estuary
An assessment was made in Suisun Bay, California, of the distributions of hydrocarbons in estuarine bed and suspended sediments and in the recently introduced asian clam, Potamocorbula amurensis. Sediments and clams were contaminated with hydrocarbons derived from petrogenic and pyrogenic sources. Distributions of alkanes and of hopane and sterane biomarkers in sediments and clams were...
Authors
Wilfred E. Pereira, Frances D. Hostettler, John B. Rapp
Sources of nitrogen and phosphorus to Northern San Francisco Bay Sources of nitrogen and phosphorus to Northern San Francisco Bay
We studied nutrient sources to the Sacramento River and Suisun Bay (northern San Francisco Bay) and the influence which these sources have on the distributions of dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP) in the river and bay. We found that agricultural return flow drains and a municipal wastewater treatment plant were the largest sources of nutrients to...
Authors
S.W. Hager, L. E. Schemel
Analytical interferences of mercuric chloride preservative in environmental water samples: Determination of organic compounds isolated by continuous liquid-liquid extraction or closed-loop stripping Analytical interferences of mercuric chloride preservative in environmental water samples: Determination of organic compounds isolated by continuous liquid-liquid extraction or closed-loop stripping
Analytical interferences were observed during the determination of organic compounds in groundwater samples preserved with mercuric chloride. The nature of the interference was different depending on the analytical isolation technique employed. (1) Water samples extracted with dichloromethane by continuous liquid-liquid extraction (CLLE) and analyzed by gas chromatography/mass...
Authors
W.T. Foreman, S.D. Zaugg, L.M. Falres, M.G. Werner, T.J. Leiker, P.F. Rogerson
Methanogenic biodegradation of creosote contaminants in natural and simulated ground-water ecosystems Methanogenic biodegradation of creosote contaminants in natural and simulated ground-water ecosystems
Wastes from a wood preserving plant in Pensacola, Florida have contaminated the near‐surface sand‐and‐gravel aquifer with creosote‐derived compounds and pentachlorophenol. Contamination resulted from the discharge of plant waste waters to and subsequent seepage from unlined surface impoundments that were in direct hydraulic contact with the ground water. Two distinct phases resulted when...
Authors
E. Michael Godsy, Donald Goerlitz, Dunja Grbic-Galic
GIS-assisted regression analysis to identify sources of selenium in streams GIS-assisted regression analysis to identify sources of selenium in streams
Using a geographic information system, a regression model has been developed to identify and to assess potential sources of selenium in the Kendrick Reclamation Project Area, Wyoming. A variety of spatially distributed factors was examined to determine which factors are most likely to affect selenium discharge in tributaries to the North Platte River. Areas of Upper Cretaceous Cody Shale...
Authors
Randolph B. See, David L. Naftz, Charles L. Qualls