POEA (polyoxyethylene tallow amine) is a surfactant with known toxic effects on aquatic organisms. POEA was added to the original formulation of the herbicide glyphosate to aid in its application and effectiveness at controlling weeds. U.S. Geological Survey (USGS) scientists developing methods to measure POEA in the environment have shown that it’s a complex and variable mixture of related compounds, and that POEA is still a common additive in several newer agricultural and household glyphosate formulations.
Since glyphosate is one of the most widely used pesticides in the United States, the findings could indicate that POEA may be widely available for transport into surface water and groundwater. Such additives in pesticide formulations are commonly called "inert" ingredients or adjuvants, and little is known about these ingredients and their occurrence and transport in, and effects on, the environment. This USGS study is the first step in investigating the environmental fate and effects of POEA in herbicide applications.
This study was funded by the USGS Toxic Substances Hydrology Program.
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Characterization of polyoxyethylene tallow amine surfactants in technical mixtures and glyphosate formulations using ultra-high performance liquid chromatography and triple quadrupole mass spectrometry
- Overview
POEA (polyoxyethylene tallow amine) is a surfactant with known toxic effects on aquatic organisms. POEA was added to the original formulation of the herbicide glyphosate to aid in its application and effectiveness at controlling weeds. U.S. Geological Survey (USGS) scientists developing methods to measure POEA in the environment have shown that it’s a complex and variable mixture of related compounds, and that POEA is still a common additive in several newer agricultural and household glyphosate formulations.
USGS scientists used advanced analytical equipment to investigate the composition of POEA (polyoxyethylene tallow amine). Since glyphosate is one of the most widely used pesticides in the United States, the findings could indicate that POEA may be widely available for transport into surface water and groundwater. Such additives in pesticide formulations are commonly called "inert" ingredients or adjuvants, and little is known about these ingredients and their occurrence and transport in, and effects on, the environment. This USGS study is the first step in investigating the environmental fate and effects of POEA in herbicide applications.
This study was funded by the USGS Toxic Substances Hydrology Program.
- Science
Related science listed below.
Organic Geochemistry Research — Lawrence, Kansas
About the ResearchThe Environmental Health Program collaborates with chemists and geologists at the Kansas Water Science Center's Organic Geochemistry Research Laboratory (OGRL) to develop targeted and non-targeted analytical methods for the identification and quantitation of chemicals that can impact the health of humans and other organisms and use bioassays to screen for receptor inhibition. The...Scientists Start at the Base of the Food Chain to Understand Contaminant Affects on Energy Cycling in Streams
Study examines the potential adverse effects of fungicides on leaf decomposition by microbes and aquatic invertebrates.Organic Geochemistry Research Laboratory Scored High on Proficiency Testing for Glyphosate
In a recent inter–laboratory comparison of 28 international laboratories, the U.S. Geological Survey (USGS) Organic Geochemistry Research Laboratory (OGRL) scored A's for the analysis of glyphosate and aminomethylphosphonic acid (AMPA) in this proficiency testing.Recognition for a USGS Scientist in Service to Others
U.S. Geological Survey (USGS) scientist Dr. Michael T. Meyer has had a prolific career, publishing 60 journal articles and 45 USGS publications. Mike's publication record has recently led to his designation as a Thomson Reuters Highly Cited Researcher, ranking among the top 1 percent of researchers from 2002 to 2012 for most cited documents in their specific field (Environment/Ecology). He was...Neonicotinoid Insecticides Documented in Midwestern U.S. Streams
Three neonicotinoid insecticides (clothianidin, thiamethoxam and imidacloprid) were detected commonly throughout the growing season in water samples collected from nine Midwestern stream sites during the 2013 growing season according to a team of U.S. Geological Survey (USGS) scientists. Clothianidin was detected most frequently (75 percent) and at the highest maximum concentration (257 nanograms...Pesticides Found in Amphibians from Remote Areas in California
Amphibians from remote locations in California have accumulated several current-use pesticides, including fungicides, in their bodies. A team of U.S. Geological Survey (USGS) scientists recently reported on field results in the journal Environmental Toxicology and Chemistry. Two fungicides, pyraclostrobin and tebuconazole, and the herbicide simazine were detected frequently in amphibians from all...Contaminants Affect Fish and Wildlife in the Chesapeake Bay
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Chemical contaminants including herbicides, veterinary pharmaceuticals, and biogenic hormones have been detected at fish nesting sites in the Potomac River watershed where endocrine disruption in smallmouth bass (Micropterus dolomieu) was also observed. Although these contaminants are known to originate from a variety of human and animal-waste sources, results of a recent U.S. Geological Survey...Understudied Fungicides Common in U.S. Streams Draining Agricultural Land
U.S. Geological Survey (USGS) scientists have detected one or more fungicides in 20 of 29 streams across the United States that were sampled during 2005 and 2006 in areas where soybeans are grown. The number of fungicides used has increased significantly since 2002, and very little is known about their occurrence in the environment. For some of the fungicides this is the first data documenting...Glyphosate Herbicide Found in Many Midwestern Streams, Antibiotics Not Common
Researchers with the U.S. Geological Survey (USGS) recently investigated 51 streams in nine Midwestern States to determine the presence of a wide range of herbicides, their degradation byproducts and antibiotics. Herbicides were detected in most water samples, which were collected to coincide with runoff events following herbicide application, but antibiotics were detected in only 1 percent of the... - Publications
Related publications listed below.
Characterization of polyoxyethylene tallow amine surfactants in technical mixtures and glyphosate formulations using ultra-high performance liquid chromatography and triple quadrupole mass spectrometry
Little is known about the occurrence, fate, and effects of the ancillary additives in pesticide formulations. Polyoxyethylene tallow amine (POEA) is a non-ionic surfactant used in many glyphosate formulations, a widely applied herbicide both in agricultural and urban environments. POEA has not been previously well characterized, but has been shown to be toxic to various aquatic organisms. CharacteAuthorsDaniel Tush, Keith A. Loftin, Michael T. Meyer