This Project integrates several geochemical tools—stable isotope geochemistry, noble gas geochemistry, active gas geochemistry, single fluid inclusion chemistry, and fluid inclusion solute chemistry—in studies of the processes that form mineral deposits and the processes that disrupt them during mining or natural weathering. Research is directed toward fundamental scientific questions or, in collaboration with other Mineral Resources Projects, toward case studies of individual deposits, deposit types, or districts. The ultimate objective is to improve the scientific basis for mineral deposit models, and thereby improve the accuracy of assessments of the Nation’s mineral wealth.
Science Issue and Relevance
The core mandate of the Mineral Resources Program is to inform decision-makers on matters related to mineral resources on the Nation’s lands, including the consequences of mining and consequences natural weathering. To fulfill this mandate, genetic and geoenvironmental models must be developed for the various types of mineral deposits based on the best-available scientific understanding. This Project integrates several geochemical tools—stable isotope geochemistry, noble gas geochemistry, active gas geochemistry, single fluid inclusion chemistry, and fluid inclusion solute chemistry—in studies of the processes that form mineral deposits and the processes that destroy them during mining or natural weathering. Research is directed toward fundamental scientific questions or, in collaboration with other Mineral Resources Projects, toward case studies of individual deposits, deposit types, or districts. The ultimate objective is to improve the scientific basis for mineral deposit models, and thereby improve the accuracy of assessments of the Nation’s mineral wealth. The tools supported by this Project are applicable over a broad spectrum of Earth science research, so the Project also performs reimbursable work for other Programs consistent with the mandate of the USGS Science Strategy to leverage USGS skills in integrated studies that examine the Earth as a whole. This Project succeeds a similar Project that was summarized in U.S. Geological Survey Circular 1343.
Methods to Address Issue
Several labortories support the project objectives:
Stable Isotope Laboratory: Stable isotope geochemistry involves isotopic analysis of carbon, hydrogen, nitrogen, oxygen, and sulfur. These elements are abundant in common minerals and rocks, and they are the building blocks of most geologic fluids (surface waters, magmatic waters, hydrocarbon fluids, and others) and most biological compounds. Geologic metal deposits are in most cases precipitates from hot fluids. Stable isotope measurements can help to determine the source of the fluids, the sources of dissolved constituents, physicochemical parameters of ore formation such as temperature, and the trigger for metal precipitation. Stable isotope analysis can also reveal the broader geologic environment of ore formation, an essential part of any mineral deposit model.
Noble Gas Laboratory: Helium, neon, argon, krypton, xenon, and radon are inert "gases" that have multiple isotopes. The relative abundances of the isotopes can reveal whether rock or water constituents came from the mantle, the deep crust, the shallow crust, or the atmosphere. In studies of mineral deposits, noble gas analyses are complementary to other types of chemical or isotopic analyses because they reveal how ore-forming systems fit into larger frameworks of crustal evolution and magma generation.
Active gases contained in hydrothermal minerals also give insights on ore formation. Active gases that are routinely measured include N2, CO2, CH2, H2, H2S, SO2, HCl, HF, H2O, and the light hydrocarbons. The data can reveal volatile evolution in hydrothermal systems, magma degassing histories, and fluid-rock chemical buffering.
Single Fluid Inclusion & Melt Inclusion Laboratory: Inclusions trapped in hydrothermal minerals can contain remnants of the waters from which the minerals precipitated. Chemical and isotopic analysis of these miniscule inclusions provides a wealth of information on ancient hydrothermal systems and their role in the formation of mineral deposits. A variety of important parameters can be determined, including the mass of fluid required to produce the deposit, the chemical species that carried the metals, and the trigger that led to metal precipitation.
Fluid Inclusion Solute Laboratory: Certain cations and anions in fluid inclusions within hydrothermal minerals can be diagnostic of the source and history of the mineral-forming fluid. Particularly insightful are the abundances of the alkali metals lithium, sodium, and potassium, and the halides fluoride, chloride, bromide, and iodide. Analyses of these ions can reveal periods of evaporation, water-rock reactions within aquifers, and mixing of multiple fluids, all important inputs for mineral deposit models.
Return to Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
Below are other science projects associated with this project.
Metal Transport in Mineralized Mountain Watersheds
Iron Oxide-Copper-Cobalt-Gold-Rare Earth Element Deposits of Southeast Missouri—From the Ore Deposit Scale to a Global Deposit Model
Antimony In and Around the Yellow Pine Deposit, Central Idaho
Magmas to Metals: Melt Inclusion Insights into the Formation of Critical Element-Bearing Ore Deposits
Below are data or web applications associated with this project.
Sulfur isotope data for: Intermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran
Fluid Inclusion Noble Gas Data From Goldfield and Tonopah Epithermal Au-Ag Deposits
Below are publications associated with this project.
Geology and genesis of the Shalipayco evaporite-related Mississippi Valley-type Zn–Pb deposit, Central Peru: 3D geological modeling and C–O–S–Sr isotope constraints
The Zn–Pb mineralization of Florida Canyon, an evaporite-related Mississippi Valley-type deposit in Bongará district, northern Peru
Timing and genesis of ore formation in the Qarachilar Cu-Mo-Au deposit, Ahar-Arasbaran metallogenic zone, NW Iran: Evidence from geology, fluid inclusions, O–S isotopes and Re–Os geochronology
Quartz solubility in the H2O-NaCl system: A framework for understanding vein formation in porphyry copper deposits
Sulfur isotopes of host strata for Howards Pass (Yukon–Northwest Territories) Zn-Pb deposits implicate anaerobic oxidation of methane, not basin stagnation
Determination of δ13C, δ15N, or δ34S by isotope-ratio-monitoring mass spectrometry using an elemental analyzer
Intermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran
Barite (Barium)
Transgressive-regressive cycles in the metalliferous, oil-shale-bearing Heath Formation (Upper Mississippian), central Montana
Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source
Isotopic data for Late Cretaceous intrusions and associated altered and mineralized rocks in the Big Belt Mountains, Montana
Origin and evolution of mineralizing fluids and exploration of the Cerro Quema Au-Cu deposit (Azuero Peninsula, Panama) from a fluid inclusion and stable isotope perspective
Below are partners associated with this project.
- Overview
This Project integrates several geochemical tools—stable isotope geochemistry, noble gas geochemistry, active gas geochemistry, single fluid inclusion chemistry, and fluid inclusion solute chemistry—in studies of the processes that form mineral deposits and the processes that disrupt them during mining or natural weathering. Research is directed toward fundamental scientific questions or, in collaboration with other Mineral Resources Projects, toward case studies of individual deposits, deposit types, or districts. The ultimate objective is to improve the scientific basis for mineral deposit models, and thereby improve the accuracy of assessments of the Nation’s mineral wealth.
Field work at the Pilot Knob iron mine, Missouri.(Credit: Craig Johnson, USGS. Public domain.) Science Issue and Relevance
The core mandate of the Mineral Resources Program is to inform decision-makers on matters related to mineral resources on the Nation’s lands, including the consequences of mining and consequences natural weathering. To fulfill this mandate, genetic and geoenvironmental models must be developed for the various types of mineral deposits based on the best-available scientific understanding. This Project integrates several geochemical tools—stable isotope geochemistry, noble gas geochemistry, active gas geochemistry, single fluid inclusion chemistry, and fluid inclusion solute chemistry—in studies of the processes that form mineral deposits and the processes that destroy them during mining or natural weathering. Research is directed toward fundamental scientific questions or, in collaboration with other Mineral Resources Projects, toward case studies of individual deposits, deposit types, or districts. The ultimate objective is to improve the scientific basis for mineral deposit models, and thereby improve the accuracy of assessments of the Nation’s mineral wealth. The tools supported by this Project are applicable over a broad spectrum of Earth science research, so the Project also performs reimbursable work for other Programs consistent with the mandate of the USGS Science Strategy to leverage USGS skills in integrated studies that examine the Earth as a whole. This Project succeeds a similar Project that was summarized in U.S. Geological Survey Circular 1343.
Methods to Address Issue
Several labortories support the project objectives:
Stable Isotope Laboratory: Stable isotope geochemistry involves isotopic analysis of carbon, hydrogen, nitrogen, oxygen, and sulfur. These elements are abundant in common minerals and rocks, and they are the building blocks of most geologic fluids (surface waters, magmatic waters, hydrocarbon fluids, and others) and most biological compounds. Geologic metal deposits are in most cases precipitates from hot fluids. Stable isotope measurements can help to determine the source of the fluids, the sources of dissolved constituents, physicochemical parameters of ore formation such as temperature, and the trigger for metal precipitation. Stable isotope analysis can also reveal the broader geologic environment of ore formation, an essential part of any mineral deposit model.
Zinc ore from the Sterling Hill mine, New Jersey.(Credit: Craig Johnson, USGS. Public domain.) Ore from the Sterling Hill mine luminescing under ultraviolet light.(Credit: Craig Johnson, USGS. Public domain.) Noble Gas Laboratory: Helium, neon, argon, krypton, xenon, and radon are inert "gases" that have multiple isotopes. The relative abundances of the isotopes can reveal whether rock or water constituents came from the mantle, the deep crust, the shallow crust, or the atmosphere. In studies of mineral deposits, noble gas analyses are complementary to other types of chemical or isotopic analyses because they reveal how ore-forming systems fit into larger frameworks of crustal evolution and magma generation.
Active gases contained in hydrothermal minerals also give insights on ore formation. Active gases that are routinely measured include N2, CO2, CH2, H2, H2S, SO2, HCl, HF, H2O, and the light hydrocarbons. The data can reveal volatile evolution in hydrothermal systems, magma degassing histories, and fluid-rock chemical buffering.
Preserved samples of ore-forming fluids within a quartz crystal; note vapor bubbles and daughter crystals.(Credit: Gary Landis, USGS. Public domain.) Single Fluid Inclusion & Melt Inclusion Laboratory: Inclusions trapped in hydrothermal minerals can contain remnants of the waters from which the minerals precipitated. Chemical and isotopic analysis of these miniscule inclusions provides a wealth of information on ancient hydrothermal systems and their role in the formation of mineral deposits. A variety of important parameters can be determined, including the mass of fluid required to produce the deposit, the chemical species that carried the metals, and the trigger that led to metal precipitation.
Fluid Inclusion Solute Laboratory: Certain cations and anions in fluid inclusions within hydrothermal minerals can be diagnostic of the source and history of the mineral-forming fluid. Particularly insightful are the abundances of the alkali metals lithium, sodium, and potassium, and the halides fluoride, chloride, bromide, and iodide. Analyses of these ions can reveal periods of evaporation, water-rock reactions within aquifers, and mixing of multiple fluids, all important inputs for mineral deposit models.
Vanadium-rich rocks of the Gibellini prospect, Nevada. (Credit: Craig Johnson, USGS. Public domain.) Microscopic view of skarn minerals associated with the Sterling Hill zinc deposit, New Jersey. (Credit: Craig Johnson, USGS. Public domain.) Heap leach operation at the Standard Hill gold mine near Mojave, California. (Credit: David Grimes, USGS. Public domain.) The Red Dog open pit mine in northwestern Alaska, a major zinc producer. (Credit: Karen Duttweiler Kelley, USGS. Public domain.) Return to Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
- Science
Below are other science projects associated with this project.
Metal Transport in Mineralized Mountain Watersheds
The central objective of this project is to develop a greater understanding of deep bedrock groundwater circulation and its contribution to surface water metal loads in mineralized mountain blocks composed of sedimentary rocks. This work is being performed in cooperation with Lawrence Berkeley National Laboratory as part of a broader research program aimed at understanding processes controlling...Iron Oxide-Copper-Cobalt-Gold-Rare Earth Element Deposits of Southeast Missouri—From the Ore Deposit Scale to a Global Deposit Model
The project main objectives are to: 1) geologically, characterize the setting and origin of the iron-copper-cobalt-gold-rare earth element deposits, and advance the knowledge of rare earth element and Co potential within iron oxide-copper-gold (IOCG) deposits of southeast Missouri, and 2) geophysically delineate and characterize the subsurface Precambrian geology using existing ground and new...Antimony In and Around the Yellow Pine Deposit, Central Idaho
Project objectives are to document the origin of the Yellow Pine gold-antimony deposit and, by extension, the origin of this deposit type. Our goal is to understand the structural, tectonic, and magmatic setting of the deposit, the character of the ore-transporting fluids, the conditions of ore deposition, and the regional stratigraphic framework and geochemical ore controls of metasedimentary...Magmas to Metals: Melt Inclusion Insights into the Formation of Critical Element-Bearing Ore Deposits
This project applies innovative melt inclusion and mineralogical techniques to characterize several distinctive magma types occurring together with prodigious, critical rare earth elements (REE) and gold-(antimony-tellurium) ore deposits within the U.S. We will characterize the pre-eruptive/pre-emplacement magmatic conditions in several districts. The goal is to determine the role of magmatism in... - Data
Below are data or web applications associated with this project.
Sulfur isotope data for: Intermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran
These data represent sulfur isotope analyses of chalcopyrite from a base metal deposit in the Aliabad-Khanchy area in northwestern Iran. Rock samples were collected from outcrops, and chalcopyrite was separated for analysis by hand picking. The separates were analyzed for the ratio 34-S/32-S by elemental analyzer-isotope ratio monitoring mass spectrometry. Standardization was performed by analyzinFluid Inclusion Noble Gas Data From Goldfield and Tonopah Epithermal Au-Ag Deposits
Twenty-five ore and gangue mineral separates from the Miocene-age Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada were analyzed to determine the helium, neon, and argon (He, Ne, and Ar) isotopic compositions contained in fluid inclusions. Four mineral separates from the Butte Main Stage vein deposit and two from the Bingham pyrite-enargite vein deposits were also analyzed. F - Publications
Below are publications associated with this project.
Filter Total Items: 73Geology and genesis of the Shalipayco evaporite-related Mississippi Valley-type Zn–Pb deposit, Central Peru: 3D geological modeling and C–O–S–Sr isotope constraints
The Shalipayco Zn–Pb deposit, in central Peru, is composed of several stratabound orebodies, the largest of which are the Resurgidora and Intermedios, contained in carbonate rocks of the Upper Triassic Chambará Formation, Pucará group. Petrography suggests that a single ore-forming episode formed sphalerite and galena within vugs, open spaces, and fractures. Three-dimensional (3D) geological modelAuthorsSaulo B de Oliveira, Craig A. Johnson, Caetano Juliani, Lena VS Monteiro, David L Leach, Marianna G.N. CaranThe Zn–Pb mineralization of Florida Canyon, an evaporite-related Mississippi Valley-type deposit in Bongará district, northern Peru
The Florida Canyon evaporite-related Zn–Pb sulfide deposit, in northern Peru, is one of the largest Mississippi Valley-type (MVT) deposits in South America. Triassic carbonate and former evaporite-bearing rocks of the Pucará Group host the ore bodies that comprise two different styles: (i) predominantly stratabound ore associated with hydrocarbon-rich porous dolostones and evaporite dissolution brAuthorsSaulo B de Oliveira, David L Leach, Caetano Juliani, Lena VS Monteiro, Craig A. JohnsonTiming and genesis of ore formation in the Qarachilar Cu-Mo-Au deposit, Ahar-Arasbaran metallogenic zone, NW Iran: Evidence from geology, fluid inclusions, O–S isotopes and Re–Os geochronology
In the Qarachilar Cu-Mo-Au deposit of the Ahar–Arasbaran metallogenic zone (AAMZ), northwest Iran, mineralization occurs as three quartz-sulfide veins that cut granodiorite-quartz monzodiorite rocks of the Qaradagh batholith (QDB). Ore formation can be divided into three stages, with chalcopyrite, molybdenite, and gold-bearing pyrite appearing mainly in the first two stages. The main wall-rock altAuthorsHossein Kouhestani, Mir Ali Asghar Mokhtari, Zhaoshan Chang, Holly J. Stein, Craig A. JohnsonQuartz solubility in the H2O-NaCl system: A framework for understanding vein formation in porphyry copper deposits
Porphyry copper deposits consist of low-grade stockwork and disseminated sulfide zones that contain characteristic vein generations formed during the evolution of the magmatic-hydrothermal systems. The present contribution proposes an interpretive framework for the formation of porphyry veins that is based on quartz solubility calculations in the H2O-NaCl system at temperatures of 100° to 1,000°CAuthorsThomas Monecke, Jochen Monecke, T James Reynolds, Subaru Tsuruoka, Mitchell M. Bennett, Wiley B Skewes, Richard M. PalinSulfur isotopes of host strata for Howards Pass (Yukon–Northwest Territories) Zn-Pb deposits implicate anaerobic oxidation of methane, not basin stagnation
A new sulfur isotope stratigraphic profile has been developed for Ordovician-Silurian mudstones that host the Howards Pass Zn-Pb deposits (Canada) in an attempt to reconcile the traditional model of a stagnant euxinic basin setting with new contradictory findings. Our analyses of pyrite confirm the up-section 34S enrichment reported previously, but additional observations show parallel depletion oAuthorsCraig A. Johnson, John F. Slack, Julie A. Dumoulin, Karen Duttweiler Kelley, Hendrik FalckDetermination of δ13C, δ15N, or δ34S by isotope-ratio-monitoring mass spectrometry using an elemental analyzer
This report describes procedures used in the Geology, Geophysics, and Geochemistry Science Center of the U.S. Geological Survey in Denver, Colorado, to determine the stable-isotope ratios 13C/12C, 15N/14N, and 34S/32S in solid materials. The procedures use elemental analyzers connected directly to gas-source isotope-ratio mass spectrometers. A different elemental–analyzer–mass-spectrometer systemAuthorsCraig A. Johnson, Craig A. Stricker, Cayce A. Gulbransen, Matthew P. EmmonsIntermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran
The Aliabad-Khanchy epithermal base metal deposit is located in the Tarom-Hashtjin metallogenic belt (THMB) of northwest Iran. The mineralization occurs as Cu-bearing brecciated quartz veins hosted by Eocene volcanic and volcaniclastic rocks of the Karaj Formation. Ore formation can be divided into five stages, with most ore minerals, such as pyrite and chalcopyrite being formed in the early stageAuthorsHossein Kouhestani, Mir Ali Asghar Mokhtari, Zhaoshan Chang, Craig A. JohnsonBarite (Barium)
Barite (barium sulfate, BaSO4) is vital to the oil and gas industry because it is a key constituent of the mud used to drill oil and gas wells. Elemental barium is an additive in optical glass, ceramic glazes, and other products. Within the United States, barite is produced mainly from mines in Nevada. Imports in 2011 (the latest year for which complete data were available) accounted for 78 percenAuthorsCraig A. Johnson, Nadine M. Piatak, M. Michael MillerTransgressive-regressive cycles in the metalliferous, oil-shale-bearing Heath Formation (Upper Mississippian), central Montana
The Upper Mississippian Heath Formation, which accumulated in the Big Snowy Trough of central Montana, has been known for three decades to contain mudrocks highly enriched in Zn, V, Mo, Ni and other metals, and source rocks for oil. The unit has more recently been recognized as a prospective tight oil play. Here we present petrographic, paleontologic, geochemical, and carbon and sulfur isotope datAuthorsJulie A. Dumoulin, Craig A. Johnson, Karen D. Kelley, Palma J. Botterell, Paul C. Hackley, Clint Scott, John F. SlackNoble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source
The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected 3He/4He ratios (with atmospheric He removed) range widely from 0.05 to 3AuthorsAndrew H. Manning, Albert H. HofstraIsotopic data for Late Cretaceous intrusions and associated altered and mineralized rocks in the Big Belt Mountains, Montana
The quartz monzodiorite of Mount Edith and the concentrically zoned intrusive suite of Boulder Baldy constitute the principal Late Cretaceous igneous intrusions hosted by Mesoproterozoic sedimentary rocks of the Newland Formation in the Big Belt Mountains, Montana. These calc-alkaline plutonic masses are manifestations of subduction-related magmatism that prevailed along the western edge of NorthAuthorsEdward A. du Bray, Daniel M. Unruh, Albert H. HofstraOrigin and evolution of mineralizing fluids and exploration of the Cerro Quema Au-Cu deposit (Azuero Peninsula, Panama) from a fluid inclusion and stable isotope perspective
Cerro Quema is a high sulfidation epithermal Au-Cu deposit with a measured, indicated and inferred resource of 35.98 Mt. @ 0.77 g/t Au containing 893,600 oz. Au (including 183,930 oz. Au equiv. of Cu ore). It is characterized by a large hydrothermal alteration zone which is interpreted to represent the lithocap of a porphyry system. The innermost zone of the lithocap is constituted by vuggy quartzAuthorsIsaac Corral, Esteve Cardellach, Merce Corbella, Angels Canals, Albert Griera, David Gomez-Gras, Craig A. Johnson - Partners
Below are partners associated with this project.