Global Marine Mineral Resources Active
Mineral-laden water emerging from a hydrothermal vent
Hydrothermal vent chimney from the southwest Pacific Ocean
Ferromanganese crust from the south Pacific Ocean
Ferromanganese nodule being sampled from the North Atlantic seafloor
Researching seafloor mineral resources that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions.
Research Overview
The Global Marine Mineral Resources project researches deep ocean minerals within the U.S. Exclusive Economic Zone and throughout the Earth’s oceans. Our research concerns the setting, genesis, and metal enrichment processes of mineral deposits, the relationship between marine minerals related and deep-sea biota, and the potential geochemical footprint of any seafloor mining. We aim to provide stakeholders with the best available science regarding potential resources and environmental impacts associated with accessing those resources.
Project objectives include:
- Geochemical characterization of mineral samples, including mineralogy and metal concentrations, and their variability regionally and globally
- Correlation of oceanographic and geographic parameters with mineralogy and metal content to elucidate the controls on mineral formation and element enrichment, and to map prospective mineral regions within the global ocean
- Investigation of mineral stability and metal mobility with exposure to seawater over time through experimental geochemistry to constrain geochemical effects of mineral disturbance
- Collaboration with biologists to determine associations between minerals and the biological communities which inhabit and surround them
Our findings inform stakeholders, including the public, government, industry, academics and NGOs, about mineral wealth and its environmental setting within the vast offshore territory of the U.S. and helps them determine which regions and deposits may warrant further research.
Seafloor Mineral Deposits
There are a wide variety of deep-sea mineral categories; however, our team focuses on those marine mineral categories that have the greatest resource potential.
Seafloor pavements and encrusted rocks are known as ferromanganese crusts (also called cobalt-rich crusts). These crusts grow very slowly, at several millimeters per million years, and precipitate onto exposed rock surfaces throughout the global ocean—they do not form where sediment blankets the seafloor. In the oldest parts of the seafloor in the northwest Pacific Ocean, some crusts have been forming for over 70 million years and can be over 20 centimeters thick. Crusts act as a sponge of sorts, adsorbing metals and other elements from seawater over these long periods of time, and are especially enriched in cobalt, manganese, rare metals such as tellurium, precious metals such as platinum, and rare earth elements.
Over millions of years, spheroidal rocks called manganese nodules (or polymetallic nodules) form atop sediment covering the abyssal plains of the global ocean. These nodules form by the accretion of iron and manganese oxides around a tiny nucleus, such as a large grain of sand, a shark tooth, or older nodule fragment. Manganese nodules are usually golf-ball to baseball size and grow very slowly like ferromanganese crusts if they acquire all their metals directly from seawater, or they grow faster if they also acquire their metals from the pore-waters of the sediment on which they sit. Nodules are currently of great interest for mining due to high concentrations of manganese, nickel, copper, and sometimes lithium, as well as the straightforward nature of quantifying their distribution and density.
Seafloor massive sulfides (also called polymetallic sulfides) form at hydrothermal vents when seawater penetrates the ocean’s crust and becomes heated and chemically modified through interaction with crustal rocks and, sometimes, by input of magmatic fluids. The hot hydrothermal fluids then rise back toward the seafloor and precipitate minerals as they cool along flow paths and upon mixing with seawater. A wide variety of minerals form through hydrothermal activity, but seafloor massive sulfides are formed from reduced sulfur and may be enriched in copper, zinc, iron, gold, and silver. Hydrothermal vents exist along mid-ocean ridge spreading centers, extensional systems associated with subduction zones, volcanoes, and intraplate hotspots. Yet, seafloor massive sulfides likely extend beyond these active hydrothermal zones. We know the minerals persist after removal from the heat source because of the presence of volcanogenic massive sulfide deposits on land.
Marine phosphorites primarily occur along continental margins where upwelling of cold, nutrient-rich, deep water is strong. These areas include the Peru-Chile margin, on plateaus such as Chatham Rise offshore New Zealand, and the Blake-Bahamas Plateau off the southeast United States; but they can also form on seamounts where ferromanganese crusts grow. Phosphorites form when abundant phosphate in seawater replaces carbonate in calcareous sediments or precipitates in situ as apatite to form hardgrounds, phosphatic nodules, or cements in breccias of multiple rock types. Marine phosphorites are sources of phosphate used as fertilizer for agriculture and phosphoric acid in the food industry. Phosphorites can also contain high concentrations of valuable, heavy, rare earth elements that may be economically recoverable and can contain up to 4% fluorine.
Marine Mining Context
The oceans cover nearly three quarters of the surface of the earth, and in the U.S., the area of seafloor comprising the Exclusive Economic Zone is greater than the land area on shore. This enormous ocean realm hosts many types of minerals that differ from those occurring terrestrially. Ferromanganese crusts, manganese nodules, phosphorites, and hydrothermal vent deposits, which occur from the Arctic to the Antarctic, are enriched in many metals including those currently deemed societally critical. It is therefore important to understand these minerals and the role they may play as future mineral resources.
People around the world demand metals and mineral resources for many uses, including technology, electronics, and green energy infrastructure such as wind turbines and electric cars. Critical minerals are defined as those that are essential to the economic and national security of a nation but that have a supply-chain vulnerable to disruption. In 2018, the Department of the Interior released a list of 54 critical minerals that was further refined to 35 based on Executive Order 13817, with the list to be reconsidered biannually. Across the USGS, research is underway to define and prioritize focus areas throughout the United States with resource potential for these 35 critical minerals. The Global Marine Mineral Resources project specifically informs the marine component.
To date, there is no mining of deep-sea minerals. In Areas Beyond National Jurisdiction, any marine mining is governed by the International Seabed Authority, which is currently drafting exploitation regulations. The Global Marine Mineral Resources project has provided scientific advice to the U.S. State Department and has served as a member of the U.S. delegation to the International Seabed Authority as an Observer Nation for the last 20 years. Japan completed equipment testing offshore of Okinawa in the fall of 2017, recovering 4 tons of metal sulfide. For comparison, it has been suggested that an economic seafloor massive sulfide (SMS) mine would recover on the order of 1 million tons of metal sulfide minerals. There is one permitted mine for copper, gold, and silver offshore Papua New Guinea, on 0.1 square kilometer of seafloor; and the Cook Islands are revising regulations for manganese nodules mining.
Below are other studies related to this project.
Below are data or web applications associated with this project.
Below are multimedia items associated with this project.
Below are publications associated with this project.
Impacts of hydrothermal plume processes on oceanic metal cycles and transport
Genesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
Defining active, inactive, and extinct seafloor massive sulfide deposits
Mapping metabolic activity at single cell resolution in intact volcanic fumarole soil
Geographic and oceanographic influences on ferromanganese crust composition along a Pacific Ocean meridional transect, 14N to 14S
The role of nanoparticles in mediating element deposition and transport at hydrothermal vents
Iron and sulfide nanoparticle formation and transport in nascent hydrothermal vent plumes
Mineral phase-element associations based on sequential leaching of ferromanganese crusts, Amerasia Basin Arctic Ocean
Formation and occurrence of ferromanganese crusts: Earth’s storehouse for critical metals
Mineralization at oceanic transform faults and fracture zones
Boiling-induced formation of colloidal gold in black smoker hydrothermal fluids
Arctic deep-water ferromanganese-oxide deposits reflect the unique characteristics of the Arctic Ocean
Below are news stories associated with this project.
- Overview
Researching seafloor mineral resources that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions.
Research Overview
The Global Marine Mineral Resources project researches deep ocean minerals within the U.S. Exclusive Economic Zone and throughout the Earth’s oceans. Our research concerns the setting, genesis, and metal enrichment processes of mineral deposits, the relationship between marine minerals related and deep-sea biota, and the potential geochemical footprint of any seafloor mining. We aim to provide stakeholders with the best available science regarding potential resources and environmental impacts associated with accessing those resources.
Project objectives include:
- Geochemical characterization of mineral samples, including mineralogy and metal concentrations, and their variability regionally and globally
- Correlation of oceanographic and geographic parameters with mineralogy and metal content to elucidate the controls on mineral formation and element enrichment, and to map prospective mineral regions within the global ocean
- Investigation of mineral stability and metal mobility with exposure to seawater over time through experimental geochemistry to constrain geochemical effects of mineral disturbance
- Collaboration with biologists to determine associations between minerals and the biological communities which inhabit and surround them
Our findings inform stakeholders, including the public, government, industry, academics and NGOs, about mineral wealth and its environmental setting within the vast offshore territory of the U.S. and helps them determine which regions and deposits may warrant further research.
Seafloor Mineral Deposits
There are a wide variety of deep-sea mineral categories; however, our team focuses on those marine mineral categories that have the greatest resource potential.
Seafloor pavements and encrusted rocks are known as ferromanganese crusts (also called cobalt-rich crusts). These crusts grow very slowly, at several millimeters per million years, and precipitate onto exposed rock surfaces throughout the global ocean—they do not form where sediment blankets the seafloor. In the oldest parts of the seafloor in the northwest Pacific Ocean, some crusts have been forming for over 70 million years and can be over 20 centimeters thick. Crusts act as a sponge of sorts, adsorbing metals and other elements from seawater over these long periods of time, and are especially enriched in cobalt, manganese, rare metals such as tellurium, precious metals such as platinum, and rare earth elements.
Over millions of years, spheroidal rocks called manganese nodules (or polymetallic nodules) form atop sediment covering the abyssal plains of the global ocean. These nodules form by the accretion of iron and manganese oxides around a tiny nucleus, such as a large grain of sand, a shark tooth, or older nodule fragment. Manganese nodules are usually golf-ball to baseball size and grow very slowly like ferromanganese crusts if they acquire all their metals directly from seawater, or they grow faster if they also acquire their metals from the pore-waters of the sediment on which they sit. Nodules are currently of great interest for mining due to high concentrations of manganese, nickel, copper, and sometimes lithium, as well as the straightforward nature of quantifying their distribution and density.
Seafloor massive sulfides (also called polymetallic sulfides) form at hydrothermal vents when seawater penetrates the ocean’s crust and becomes heated and chemically modified through interaction with crustal rocks and, sometimes, by input of magmatic fluids. The hot hydrothermal fluids then rise back toward the seafloor and precipitate minerals as they cool along flow paths and upon mixing with seawater. A wide variety of minerals form through hydrothermal activity, but seafloor massive sulfides are formed from reduced sulfur and may be enriched in copper, zinc, iron, gold, and silver. Hydrothermal vents exist along mid-ocean ridge spreading centers, extensional systems associated with subduction zones, volcanoes, and intraplate hotspots. Yet, seafloor massive sulfides likely extend beyond these active hydrothermal zones. We know the minerals persist after removal from the heat source because of the presence of volcanogenic massive sulfide deposits on land.
Marine phosphorites primarily occur along continental margins where upwelling of cold, nutrient-rich, deep water is strong. These areas include the Peru-Chile margin, on plateaus such as Chatham Rise offshore New Zealand, and the Blake-Bahamas Plateau off the southeast United States; but they can also form on seamounts where ferromanganese crusts grow. Phosphorites form when abundant phosphate in seawater replaces carbonate in calcareous sediments or precipitates in situ as apatite to form hardgrounds, phosphatic nodules, or cements in breccias of multiple rock types. Marine phosphorites are sources of phosphate used as fertilizer for agriculture and phosphoric acid in the food industry. Phosphorites can also contain high concentrations of valuable, heavy, rare earth elements that may be economically recoverable and can contain up to 4% fluorine.
Marine Mining Context
The oceans cover nearly three quarters of the surface of the earth, and in the U.S., the area of seafloor comprising the Exclusive Economic Zone is greater than the land area on shore. This enormous ocean realm hosts many types of minerals that differ from those occurring terrestrially. Ferromanganese crusts, manganese nodules, phosphorites, and hydrothermal vent deposits, which occur from the Arctic to the Antarctic, are enriched in many metals including those currently deemed societally critical. It is therefore important to understand these minerals and the role they may play as future mineral resources.
People around the world demand metals and mineral resources for many uses, including technology, electronics, and green energy infrastructure such as wind turbines and electric cars. Critical minerals are defined as those that are essential to the economic and national security of a nation but that have a supply-chain vulnerable to disruption. In 2018, the Department of the Interior released a list of 54 critical minerals that was further refined to 35 based on Executive Order 13817, with the list to be reconsidered biannually. Across the USGS, research is underway to define and prioritize focus areas throughout the United States with resource potential for these 35 critical minerals. The Global Marine Mineral Resources project specifically informs the marine component.
To date, there is no mining of deep-sea minerals. In Areas Beyond National Jurisdiction, any marine mining is governed by the International Seabed Authority, which is currently drafting exploitation regulations. The Global Marine Mineral Resources project has provided scientific advice to the U.S. State Department and has served as a member of the U.S. delegation to the International Seabed Authority as an Observer Nation for the last 20 years. Japan completed equipment testing offshore of Okinawa in the fall of 2017, recovering 4 tons of metal sulfide. For comparison, it has been suggested that an economic seafloor massive sulfide (SMS) mine would recover on the order of 1 million tons of metal sulfide minerals. There is one permitted mine for copper, gold, and silver offshore Papua New Guinea, on 0.1 square kilometer of seafloor; and the Cook Islands are revising regulations for manganese nodules mining.
- Science
Below are other studies related to this project.
- Data
Below are data or web applications associated with this project.
- Multimedia
Below are multimedia items associated with this project.
- Publications
Below are publications associated with this project.
Filter Total Items: 55Impacts of hydrothermal plume processes on oceanic metal cycles and transport
Chemical, physical and biological processes in hydrothermal plumes control the flux of elements from hydrothermal vents to the global oceans. The timescales of these processes range from less than a second, as the hydrothermal fluid mixes with seawater at the seafloor, to decades, as the plume disperses over thousands of kilometers. Integrating hydrothermal geochemistry throughout the lifetime ofAuthorsAmy Gartman, Alyssa J. FindlayGenesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825 m) Fe–Mn cAuthorsMariana Benites, James R. Hein, Kira Mizell, Terrence Blackburn, Luigi JovaneDefining active, inactive, and extinct seafloor massive sulfide deposits
Hydrothermal activity results in the formation of hydrothermal mineral deposits, including seafloor massive sulfide deposits, at oceanic spreading ridges, arcs, and back-arcs. As hydrothermal systems age, the mineral deposits eventually become severed from the heat source and fluid-flow pathways responsible for their formation and become extinct. The timescales and processes by which this cessatioAuthorsJohn W. Jamieson, Amy GartmanMapping metabolic activity at single cell resolution in intact volcanic fumarole soil
Interactions among microorganisms and their mineralogical substrates govern the structure, function, and emergent properties of microbial communities. These interactions are predicated on spatial relationships, which dictate metabolite exchange and access to key substrates. To quantitatively assess links between spatial relationships and metabolic activity, this study presents a novel approach toAuthorsJeffrey J. Marlow, Isabella Colocci, Sean Jungbluth, Nils Moritz Weber, Amy Gartman, Jens KallmeyerGeographic and oceanographic influences on ferromanganese crust composition along a Pacific Ocean meridional transect, 14N to 14S
The major controls on the variability of ferromanganese (FeMn) crust composition have been generally described over the past 40 years; however, most compilation studies lack quantitative statistics and are limited to a small region of several seamounts or compare FeMn crusts from disparate areas of the global oceans. This study provides the first detailed research to address the geographic and oceaAuthorsKira Mizell, James R. Hein, Phoebe J. Lam, Anthony A.P. Koppers, Hubert StaudigelThe role of nanoparticles in mediating element deposition and transport at hydrothermal vents
Precipitation processes in hydrothermal fluids exert a primary control on the eventual distribution of elements, whether that sink is in the subseafloor, hydrothermal chimneys, near-field metalliferous sediments, or more distal in the ocean basin. Recent studies demonstrating abundant nanoparticles in hydrothermal fluids raise questions as to the importance of these nanoparticles relative to macroAuthorsAmy Gartman, Alyssa J. Findlay, Mark D. Hannington, Dieter Garbe-Schönberg, John W. Jamieson, Tom KwasnitschkaIron and sulfide nanoparticle formation and transport in nascent hydrothermal vent plumes
Deep-sea hydrothermal vents are a significant source of dissolved metals to the global oceans, producing midwater plumes enriched in metals that are transported thousands of kilometers from the vent source. Extensive particle precipitation upon emission of hydrothermal fluids, due to temperature and pH changes during mixing with ambient seawater, controls metal speciation and the magnitude of metaAuthorsAlyssa J. Findlay, Emily Estes, Amy Gartman, Alexey Kamyshny, Mustafa Yucel, George W. LutherMineral phase-element associations based on sequential leaching of ferromanganese crusts, Amerasia Basin Arctic Ocean
Ferromanganese (FeMn) crusts from Mendeleev Ridge, Chukchi Borderland, and Alpha Ridge, in the Amerasia Basin, Arctic Ocean, are similar based on morphology and chemical composition. The crusts are characterized by a two- to four-layered stratigraphy. The chemical composition of the Arctic crusts differs significantly from hydrogenetic crusts from elsewhere of global ocean by high mean Fe/Mn ratioAuthorsNatalia Konstantinova, James R. Hein, Amy Gartman, Kira Mizell, Pedro Barrulas, Georgy Cherkashov, Pavel Mikhailik, Alexander KhanchukFormation and occurrence of ferromanganese crusts: Earth’s storehouse for critical metals
Marine ferromanganese oxide crusts (Fe–Mn crusts) are potentially important metal resources formed on the seafloor by precipitation of dissolved and colloidal components from ambient seawater onto rocky surfaces. The unique properties and slow growth rates of the crusts promote adsorption of numerous elements from seawater: some, such as Te and Co, reach concentrations rarely encountered elsewhereAuthorsPaul A. Lusty, James R. Hein, Pierre JossoMineralization at oceanic transform faults and fracture zones
Mineral formation in the modern oceans can take place over millions of years as a result precipitation from ambient ocean water, or orders of magnitude more rapidly from hydrothermal activity related to magmatic and tectonic processes. Here, we review associations between transform faults and related fracture zones and marine minerals. We define marine transform faults as strike-slip or oblique faAuthorsAmy Gartman, James R. HeinBoiling-induced formation of colloidal gold in black smoker hydrothermal fluids
Gold colloids occur in black smoker fluids from the Niua South hydrothermal vent field, Lau Basin (South Pacific Ocean), confirming the long-standing hypothesis that gold may undergo colloidal transport in hydrothermal fluids. Six black smoker vents, varying in temperature from 250 °C to 325 °C, were sampled; the 325 °C vent was boiling at the time of sampling and the 250 °C fluids were diffuselyAuthorsAmy Gartman, Mark Hannington, John W. Jamieson, Ben Peterkin, Dieter Garbe-Schönberg, Alyssa J Findlay, Sebastian Fuchs, Tom KwasnitschkaArctic deep-water ferromanganese-oxide deposits reflect the unique characteristics of the Arctic Ocean
Little is known about marine mineral deposits in the Arctic Ocean, an ocean dominated by continental shelf and basins semi-closed to deep-water circulation. Here, we present data for ferromanganese crusts and nodules collected from the Amerasia Arctic Ocean in 2008, 2009, and 2012 (HLY0805, HLY0905, HLY1202). We determined mineral and chemical compositions of the crusts and nodules and the onset oAuthorsJames R. Hein, Natalia Konstantinova, Mariah Mikesell, Kira Mizell, Jessica N. Fitzsimmons, Phoebe Lam, Laramie T. Jensen, Yang Xiang, Amy Gartman, Georgy Cherkashov, Deborah Hutchinson, Claire P. Till - News
Below are news stories associated with this project.
Filter Total Items: 18