National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota
The primary focus of the science team at the site is to improve the understanding of the mobilization, attenuation, transport, fate, potential health effects, and remediation of petroleum in the subsurface through collaborative research, peer-reviewed publications, presentations, data, and educational activities.
The objective of the project is to improve the understanding of the mobilization, transport, and fate of crude oil in the
shallow subsurface. The U.S. Geological Survey Toxic Substances Hydrology Program began an interdisciplinary research project in 1983 at the site of a crude-oil spill near Bemidji, Minnesota. Research is conducted by scientists from the U.S. Geological Survey and from several academic institutions. Currently we have four primary research objectives: (1)characterizing the nature, toxicity and prevalence of partial transformation products emanating from the crude oil source, (2) evaluating the secondary impacts [such as arsenic cycling] of biodegradation, (3) understanding the timeframe of natural attenuation of petroleum hydrocarbon source zones, and (4) developing field tools, methods, and data that support evaluations of environmental health effects of natural attenuation of crude oil.
A fact sheet describing results from the Bemidji research site is available.
The spill occurred in 1979 when a pipeline transporting crude oil broke. After cleanup efforts were completed in 1980, about 400,000 liters of oil remained in the unsaturated zone and near the water table. This continues to be a source of contaminants to a shallow outwash aquifer. The oil is moving as a separate fluid phase, as dissolved petroleum constituents in ground water, and as vapors in the unsaturated zone. Native microbes are converting the petroleum derivatives into carbon dioxide, methane, and other biodegradation products.
The publications below are associated with this project.
Cross section area at the Bemidji Crude Oil spill site
Lessons learned decades after an oil spill faded from headlines
Characterization of the partial oxidation products of crude oil contaminating groundwater at the U.S. Geological Survey Bemidji research site in Minnesota by elemental analysis, radiocarbon dating, nuclear magnetic resonance spectroscopy, and Fourier tran
Arsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries
We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH)3 during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 µg/L drinking water standard for ~40
Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi
Natural Attenuation in Source Zone and Groundwater Plume - Bemidji Crude Oil Spill
Molecular-level evidence provided by ultrahigh resolution mass spectrometry for oil-derived doc in groundwater at Bemidji, Minnesota
Reactive transport modeling of geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA
A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Crude oil at the Bemidji Site: 25 years of monitoring, modeling, and understanding
Forensic fingerprinting of oil-spill hydrocarbons in a methanogenic environment-Mandan, ND and Bemidji, MN
Geobacter bemidjiensis sp. nov. and Geobacter psychrophilus sp. nov., two novel Fe(III)-reducing subsurface isolates
Inverse modeling of BTEX dissolution and biodegradation at the Bemidji, MN crude-oil spill site
The primary focus of the science team at the site is to improve the understanding of the mobilization, attenuation, transport, fate, potential health effects, and remediation of petroleum in the subsurface through collaborative research, peer-reviewed publications, presentations, data, and educational activities.
The objective of the project is to improve the understanding of the mobilization, transport, and fate of crude oil in the
shallow subsurface. The U.S. Geological Survey Toxic Substances Hydrology Program began an interdisciplinary research project in 1983 at the site of a crude-oil spill near Bemidji, Minnesota. Research is conducted by scientists from the U.S. Geological Survey and from several academic institutions. Currently we have four primary research objectives: (1)characterizing the nature, toxicity and prevalence of partial transformation products emanating from the crude oil source, (2) evaluating the secondary impacts [such as arsenic cycling] of biodegradation, (3) understanding the timeframe of natural attenuation of petroleum hydrocarbon source zones, and (4) developing field tools, methods, and data that support evaluations of environmental health effects of natural attenuation of crude oil.
A fact sheet describing results from the Bemidji research site is available.
The spill occurred in 1979 when a pipeline transporting crude oil broke. After cleanup efforts were completed in 1980, about 400,000 liters of oil remained in the unsaturated zone and near the water table. This continues to be a source of contaminants to a shallow outwash aquifer. The oil is moving as a separate fluid phase, as dissolved petroleum constituents in ground water, and as vapors in the unsaturated zone. Native microbes are converting the petroleum derivatives into carbon dioxide, methane, and other biodegradation products.
The publications below are associated with this project.
Cross section area at the Bemidji Crude Oil spill site
Lessons learned decades after an oil spill faded from headlines
Characterization of the partial oxidation products of crude oil contaminating groundwater at the U.S. Geological Survey Bemidji research site in Minnesota by elemental analysis, radiocarbon dating, nuclear magnetic resonance spectroscopy, and Fourier tran
Arsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries
We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH)3 during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 µg/L drinking water standard for ~40
Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi