The primary focus of the science team at the site is to improve the understanding of the mobilization, attenuation, transport, fate, potential health effects, and remediation of petroleum in the subsurface through collaborative research, peer-reviewed publications, presentations, data, and educational activities.
The objective of the project is to improve the understanding of the mobilization, transport, and fate of crude oil in the
shallow subsurface. The U.S. Geological Survey Toxic Substances Hydrology Program began an interdisciplinary research project in 1983 at the site of a crude-oil spill near Bemidji, Minnesota. Research is conducted by scientists from the U.S. Geological Survey and from several academic institutions. Currently we have four primary research objectives: (1)characterizing the nature, toxicity and prevalence of partial transformation products emanating from the crude oil source, (2) evaluating the secondary impacts [such as arsenic cycling] of biodegradation, (3) understanding the timeframe of natural attenuation of petroleum hydrocarbon source zones, and (4) developing field tools, methods, and data that support evaluations of environmental health effects of natural attenuation of crude oil.
A fact sheet describing results from the Bemidji research site is available.
The spill occurred in 1979 when a pipeline transporting crude oil broke. After cleanup efforts were completed in 1980, about 400,000 liters of oil remained in the unsaturated zone and near the water table. This continues to be a source of contaminants to a shallow outwash aquifer. The oil is moving as a separate fluid phase, as dissolved petroleum constituents in ground water, and as vapors in the unsaturated zone. Native microbes are converting the petroleum derivatives into carbon dioxide, methane, and other biodegradation products.
The publications below are associated with this project.
Cross section area at the Bemidji Crude Oil spill site
Lessons learned decades after an oil spill faded from headlines
Characterization of the partial oxidation products of crude oil contaminating groundwater at the U.S. Geological Survey Bemidji research site in Minnesota by elemental analysis, radiocarbon dating, nuclear magnetic resonance spectroscopy, and Fourier tran
Arsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries
We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH)3 during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 µg/L drinking water standard for ~40
Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi
Natural Attenuation in Source Zone and Groundwater Plume - Bemidji Crude Oil Spill
Molecular-level evidence provided by ultrahigh resolution mass spectrometry for oil-derived doc in groundwater at Bemidji, Minnesota
Reactive transport modeling of geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA
A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Crude oil at the Bemidji Site: 25 years of monitoring, modeling, and understanding
Forensic fingerprinting of oil-spill hydrocarbons in a methanogenic environment-Mandan, ND and Bemidji, MN
Geobacter bemidjiensis sp. nov. and Geobacter psychrophilus sp. nov., two novel Fe(III)-reducing subsurface isolates
Inverse modeling of BTEX dissolution and biodegradation at the Bemidji, MN crude-oil spill site
- Overview
The primary focus of the science team at the site is to improve the understanding of the mobilization, attenuation, transport, fate, potential health effects, and remediation of petroleum in the subsurface through collaborative research, peer-reviewed publications, presentations, data, and educational activities.
Four USGS scientists sampling pore water from a canoe in un-named lake approximately 340 meters downgradient of the Bemidji, Minnesota crude oil spill site. The objective of the project is to improve the understanding of the mobilization, transport, and fate of crude oil in the
shallow subsurface. The U.S. Geological Survey Toxic Substances Hydrology Program began an interdisciplinary research project in 1983 at the site of a crude-oil spill near Bemidji, Minnesota. Research is conducted by scientists from the U.S. Geological Survey and from several academic institutions. Currently we have four primary research objectives: (1)characterizing the nature, toxicity and prevalence of partial transformation products emanating from the crude oil source, (2) evaluating the secondary impacts [such as arsenic cycling] of biodegradation, (3) understanding the timeframe of natural attenuation of petroleum hydrocarbon source zones, and (4) developing field tools, methods, and data that support evaluations of environmental health effects of natural attenuation of crude oil.
A fact sheet describing results from the Bemidji research site is available.
The spill occurred in 1979 when a pipeline transporting crude oil broke. After cleanup efforts were completed in 1980, about 400,000 liters of oil remained in the unsaturated zone and near the water table. This continues to be a source of contaminants to a shallow outwash aquifer. The oil is moving as a separate fluid phase, as dissolved petroleum constituents in ground water, and as vapors in the unsaturated zone. Native microbes are converting the petroleum derivatives into carbon dioxide, methane, and other biodegradation products.
- Publications
The publications below are associated with this project.
Cross section area at the Bemidji Crude Oil spill siteLessons learned decades after an oil spill faded from headlinesFilter Total Items: 29Characterization of the partial oxidation products of crude oil contaminating groundwater at the U.S. Geological Survey Bemidji research site in Minnesota by elemental analysis, radiocarbon dating, nuclear magnetic resonance spectroscopy, and Fourier tran
In oil spill research, a topic of increasing attention during the last decade has been the environmental impact of the partial oxidation products that result from transformation of the petroleum in freshwater, marine, and terrestrial ecosystems. This report describes the isolation and characterization of the partial oxidation products from crude oil contaminating groundwater at the long-term U.S.AuthorsKevin A. Thorn, Ananna Islam, Sunghwan KimArsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries
We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH)3 during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 µg/L drinking water standard for ~40
AuthorsBrady A. Ziegler, G.-H. Crystal Ng, Isabelle M. Cozzarelli, Aubrey J. Dunshee, Madeline E. SchreiberEffects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This additional remedi
AuthorsGeoffrey N. Delin, William N. Herkelrath, Jared J. TrostNatural Attenuation in Source Zone and Groundwater Plume - Bemidji Crude Oil Spill
A long-term study of a 40-year-old crude oil spill provides insights about petroleum hydrocarbon natural attenuation processes and rates. In the source zone, fermentation coupled to methanogenesis is the dominant natural source zone depletion (NSZD) process, and most of the carbon mass exits the surface as CO2 efflux. Monitored natural attenuation (MNA) of the groundwater plume shows that benzeneAuthorsBarbara A. BekinsMolecular-level evidence provided by ultrahigh resolution mass spectrometry for oil-derived doc in groundwater at Bemidji, Minnesota
Dissolved organic matter samples extracted from ground water at the USGS Bemidji oil spill site in Minnesota were investigated by ultrahigh resolution mass spectrometry. Principle component analysis (PCA) of the elemental composition assignments of the samples showed that the score plots for the contaminated sites were well separated from those for the uncontaminated sites. Additionally, spectra oAuthorsAnanna Islam, Arif Ahmed, Manhoi Hur, Kevin A. Thorn, Sunghwan KimReactive transport modeling of geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Anaerobic biodegradation of organic amendments and contaminants in aquifers can trigger secondary water quality impacts that impair groundwater resources. Reactive transport models help elucidate how diverse geochemical reactions control the spatiotemporal evolution of these impacts. Using extensive monitoring data from a crude oil spill site near Bemidji, Minnesota (USA), we implemented a comprehAuthorsGene-Hua Crystal Ng, Barbara A. Bekins, Isabelle M. Cozzarelli, Mary Jo Baedecker, Philip C. Bennett, Richard T. Amos, William N. HerkelrathEffects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA
A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, MN. In 1998, the pipeline company installed a dual-pump recovery system designed to remove crude oil remaining in the subsurface at the site. The remediation from 1999 to 2003 resulted in removal of about 115,000 L of crude oil, representing between 36% and 41% of the volume of oil (280,000 to 316,000 L) estimated to be presentAuthorsGeoffrey N. Delin, William N. HerkelrathA mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN
Secondary water quality impacts can result from a broad range of coupled reactions triggered by primary groundwater contaminants. Data from a crude-oil spill research site near Bemidji, MN provide an ideal test case for investigating the complex interactions controlling secondary impacts, including depleted dissolved oxygen and elevated organic carbon, inorganic carbon, CH4, Mn, Fe, and other dissAuthorsGene-Hua Crystal Ng, Barbara A. Bekins, Isabelle M. Cozzarelli, Mary Jo Baedecker, Philip C. Bennett, Richard T. AmosCrude oil at the Bemidji Site: 25 years of monitoring, modeling, and understanding
The fate of hydrocarbons in the subsurface near Bemidji, Minnesota, has been investigated by a multidisciplinary group of scientists for over a quarter century. Research at Bemidji has involved extensive investigations of multiphase flow and transport, volatilization, dissolution, geochemical interactions, microbial populations, and biodegradation with the goal of providing an improved understandiAuthorsHedeff I. Essaid, Barbara A. Bekins, William N. Herkelrath, Geoffrey N. DelinForensic fingerprinting of oil-spill hydrocarbons in a methanogenic environment-Mandan, ND and Bemidji, MN
In recent decades forensic fingerprinting of oil-spill hydrocarbons has emerged as an important tool for correlating oils and for evaluating their source and character. Two long-term hydrocarbon spills, an off-road diesel spill (Mandan, ND) and a crude oil spill (Bemidji, MN) experiencing methanogenic biodegradation were previously shown to be undergoing an unexpected progression of homologous n-aAuthorsFrances D. Hostettler, Y. Wang, Y. Huang, W. Cao, Barbara A. Bekins, Colleen E. Rostad, C. F. Kulpa, Andrew E. LaursenGeobacter bemidjiensis sp. nov. and Geobacter psychrophilus sp. nov., two novel Fe(III)-reducing subsurface isolates
Fe(III)-reducing isolates were recovered from two aquifers in which Fe(III) reduction is known to be important. Strain BemT was enriched from subsurface sediments collected in Bemidji, MN, USA, near a site where Fe(III) reduction is important in aromatic hydrocarbon degradation. Strains P11, P35T and P39 were isolated from the groundwater of an aquifer in Plymouth, MA, USA, in which Fe(III) reductAuthorsKelly P. Nevin, Dawn E. Holmes, Trevor L. Woodard, Erich S. Hinlein, David W. Ostendorf, Derek R. LovelyInverse modeling of BTEX dissolution and biodegradation at the Bemidji, MN crude-oil spill site
The U.S. Geological Survey (USGS) solute transport and biodegradation code BIOMOC was used in conjunction with the USGS universal inverse modeling code UCODE to quantify field-scale hydrocarbon dissolution and biodegradation at the USGS Toxic Substances Hydrology Program crude-oil spill research site located near Bemidji, MN. This inverse modeling effort used the extensive historical data compiledAuthorsH.I. Essaid, I.M. Cozzarelli, R.P. Eganhouse, W.N. Herkelrath, B.A. Bekins, G. N. Delin