Sediment cores let us look back in time at the contaminant history of a watershed. Learn about what lake and reservoir sediment cores tell us about trends in metals, organochlorine pesticides, polycyclic aromatic hydrocarbons, and other sediment-related contaminants.
Water-quality trends can provide an assessment of the effectiveness of regulatory actions aimed at improving water quality, a warning of water-quality degradation, and an improved understanding of how human activities affect water quality.
Sediment cores—long tubes of mud—are collected from a lake or reservoir and sliced into thin intervals. Each slice represents an interval of time. By analyzing the sediments in each slice for the contaminants of interest, changes in the occurrence of contaminants and their use in the watershed can be reconstructed. The approximate date corresponding to deposition of the sediment in each slice is determined by analysis of radionuclides (cesium-137 and lead-210).
USGS studies of reconstructed trends in metals and hydrophobic organic contaminants have shed light on the effectiveness of restrictions on the use of leaded gasoline, DDT, and PCBs, and the effectiveness of the Clean Air Act in reducing concentrations of some heavy metals. The studies also have identified some contaminants, like polycyclic aromatic hydrocarbons (PAHs), whose concentrations are increasing in urban areas, spurring efforts to identify the source or sources of these upward trends.
Find out more about coal-tar-based sealcoat, a potent source of PAHs to lake and streambed sediment, and related environmental health issues.
NATIONAL SUMMARIES
- Increased mercury fallout near major U.S. cities (Environ. Pollution, 2012)
- Coal-tar sealcoat largest PAH source to U.S. lakes (Sci. Total Env., 2010)
- PAH in coal tar sealcoat a national problem (Env. Sci. & Tech., 2009)
- National-scale trends in organics (Env. Sci. & Tech., 2005)
- National-scale trends in metals (Env. Tox. & Chem., 2006) associated Data Report
- Methods and age dating of cores (USGS SIR 2004-5184)
- Urban trends in PAHs (Env. Sci. & Tech., 2000)
- Rates of decrease in DDT and PCBs (Env. Sci. & Tech., 1998)
- Trends in organochlorine compounds (Env. Sci. & Tech., 1997)
TOPICAL FINDINGS
- Evaluating mercury and 210Pb atmospheric fallout and focusing to lakes (Env. Sci. & Tech., 2009)
- Effects of Hurricanes Katrina and Rita on Lake Pontchartrain sediments (Env. Sci. & Tech., 2006)
- Parking lot sealcoat: an urban source of PAHs (Env. Sci. & Tech., 2005) associated fact sheet, data report
- Chemical response to urbanization, New England, USA (Chalmers et al. 2007)
- Contaminant trends in the Mississippi River Basin (Van Metre and Horowitz 2013)
- Reservoir cores versus stream suspended sediments (Env. Sci. & Tech., 2004)
- Monitoring suspended sediment chemistry (Arch. Env. Contam. & Tox., 2003)
- Metal diagenesis in reservoir cores (J. Paleolimnology, 2000)
LOCAL RESULTS
- PAHs decline after ban on coal-tar sealcoat, Austin, TX (Env. Sci. Technol., 2014)
- Chemical response of particle-associated contaminants in aquatic sediments to urbanization in New England (Contam. Hydro., 2007)
- Lead and zinc in greater Atlanta, Georgia (Env. Sci. & Tech., 2000)
- Trends in White Rock Lake, Texas (J. Paleolimnology, 1997)
Read about additional science related to sediment-associated contaminants and water-quality trends by following the links to web pages below.
Learn more about water quality trends as recorded in sediment cores at the publications below.
Trends in hydrophobic organic contaminants in urban and reference lake sediments across the United States, 1970-2001
Major and trace elements in 35 lake and reservoir sediment cores from across the United States, 1994-2001
Parking lot sealcoat: a major source of polycyclic aromatic hydrocarbons (PAHs) in urban and suburban environments
Trends in metals in urban and reference lake sediments across the United States, 1970 to 2001
Effects of hurricanes Katrina and Rita on the chemistry of bottom sediments in Lake Pontchartrain, Louisiana, USA
Collection, analysis, and age-dating of sediment cores from 56 U.S. lakes and reservoirs sampled by the U.S. Geological Survey, 1992-2001
Trends in hydrophobic organic contaminants in urban and reference lake sediments across the United States, 1970-2001
Parking lot sealcoat: An unrecognized source of urban polycyclic aromatic hydrocarbons
Occurrence, trends, and sources in particle-associated contaminants in selected streams and lakes in Fort Worth, Texas
A chronicle of organochlorine contamination in Clear Creek, Galveston and Harris Counties, Texas, 1960-2002, as recorded in sediment cores
Tire-wear particles as a source of zinc to the environment
Contaminant trends in reservoir sediment cores as records of influent stream quality
Trends in chemical concentration in sediment cores from three lakes in New Jersey and one lake on Long Island, New York
- Overview
Sediment cores let us look back in time at the contaminant history of a watershed. Learn about what lake and reservoir sediment cores tell us about trends in metals, organochlorine pesticides, polycyclic aromatic hydrocarbons, and other sediment-related contaminants.
A hydrologic technician collects a core of lake sediment from Lake Lanier, Georgia. By examining changes in contaminant concentrations from the top of the core (most recent sediment) to the bottom (oldest sediment), contaminant histories can be reconstructed. Water-quality trends can provide an assessment of the effectiveness of regulatory actions aimed at improving water quality, a warning of water-quality degradation, and an improved understanding of how human activities affect water quality.
Sediment cores—long tubes of mud—are collected from a lake or reservoir and sliced into thin intervals. Each slice represents an interval of time. By analyzing the sediments in each slice for the contaminants of interest, changes in the occurrence of contaminants and their use in the watershed can be reconstructed. The approximate date corresponding to deposition of the sediment in each slice is determined by analysis of radionuclides (cesium-137 and lead-210).
USGS studies of reconstructed trends in metals and hydrophobic organic contaminants have shed light on the effectiveness of restrictions on the use of leaded gasoline, DDT, and PCBs, and the effectiveness of the Clean Air Act in reducing concentrations of some heavy metals. The studies also have identified some contaminants, like polycyclic aromatic hydrocarbons (PAHs), whose concentrations are increasing in urban areas, spurring efforts to identify the source or sources of these upward trends.
Find out more about coal-tar-based sealcoat, a potent source of PAHs to lake and streambed sediment, and related environmental health issues.
Preparing to cut open a sediment core to release the overlying lake water. NATIONAL SUMMARIES
- Increased mercury fallout near major U.S. cities (Environ. Pollution, 2012)
- Coal-tar sealcoat largest PAH source to U.S. lakes (Sci. Total Env., 2010)
- PAH in coal tar sealcoat a national problem (Env. Sci. & Tech., 2009)
- National-scale trends in organics (Env. Sci. & Tech., 2005)
- National-scale trends in metals (Env. Tox. & Chem., 2006) associated Data Report
- Methods and age dating of cores (USGS SIR 2004-5184)
- Urban trends in PAHs (Env. Sci. & Tech., 2000)
- Rates of decrease in DDT and PCBs (Env. Sci. & Tech., 1998)
- Trends in organochlorine compounds (Env. Sci. & Tech., 1997)
TOPICAL FINDINGS
Lake sediment core sample. A sediment core can represent from a few to many decades of sediment, depending on the sedimentation rate of the lake or reservoir. - Evaluating mercury and 210Pb atmospheric fallout and focusing to lakes (Env. Sci. & Tech., 2009)
- Effects of Hurricanes Katrina and Rita on Lake Pontchartrain sediments (Env. Sci. & Tech., 2006)
- Parking lot sealcoat: an urban source of PAHs (Env. Sci. & Tech., 2005) associated fact sheet, data report
- Chemical response to urbanization, New England, USA (Chalmers et al. 2007)
- Contaminant trends in the Mississippi River Basin (Van Metre and Horowitz 2013)
- Reservoir cores versus stream suspended sediments (Env. Sci. & Tech., 2004)
- Monitoring suspended sediment chemistry (Arch. Env. Contam. & Tox., 2003)
- Metal diagenesis in reservoir cores (J. Paleolimnology, 2000)
LOCAL RESULTS
- PAHs decline after ban on coal-tar sealcoat, Austin, TX (Env. Sci. Technol., 2014)
- Chemical response of particle-associated contaminants in aquatic sediments to urbanization in New England (Contam. Hydro., 2007)
- Lead and zinc in greater Atlanta, Georgia (Env. Sci. & Tech., 2000)
- Trends in White Rock Lake, Texas (J. Paleolimnology, 1997)
Sediment cores are sliced into intervals for chemical analysis. Each slice of sediment represents a "slice" of time. - Science
Read about additional science related to sediment-associated contaminants and water-quality trends by following the links to web pages below.
- Publications
Learn more about water quality trends as recorded in sediment cores at the publications below.
Trends in hydrophobic organic contaminants in urban and reference lake sediments across the United States, 1970-2001
A shift in national policy toward stronger environmental protection began in the United States in about 1970. Conversely, urban land use, population, energy consumption, and vehicle use have increased greatly since then. To assess the effects of these changes on water quality, the U.S. Geological Survey used sediment cores to reconstruct water-quality histories for38 urban and reference lakes acroAuthorsP. C. Van Metre, B.J. MahlerFilter Total Items: 42Major and trace elements in 35 lake and reservoir sediment cores from across the United States, 1994-2001
This report presents data on major and trace element concentrations in sediment cores collected from 35 lakes and reservoirs during 1994-2001. The lakes and reservoirs are located in or near 18 major urban areas across the United States and provide a geographically diverse coverage of urban land use for the country as well as some reference settings. Vertical intervals of the cores were analyzed fAuthorsPeter C. Van Metre, Barbara Mahler, Jennifer T. Wilson, Edward CallenderParking lot sealcoat: a major source of polycyclic aromatic hydrocarbons (PAHs) in urban and suburban environments
Collaborative studies by the City of Austin and the U. S. Geological Survey (USGS) have identified coal-tar based sealcoat—the black, shiny emulsion painted or sprayed on asphalt pavement such as parking lots—as a major and previously unrecognized source of polycyclic aromatic hydrocarbon (PAH) contamination. Several PAHs are suspected human carcinogens and are toxic to aquatic life. Studies in AuAuthorsPeter C. Van Metre, Barbara Mahler, Mateo Scoggins, Pixie A. HamiltonTrends in metals in urban and reference lake sediments across the United States, 1970 to 2001
Trends in metals concentrations in sediment cores from 35 reservoirs and lakes in urban and reference settings were analyzed to determine the effects of three decades of legislation, regulation, and changing demographics and industrial practices in the United States on concentrations of metals in the environment. Decreasing trends outnumber increasing trends for all seven metals analyzed (Cd, Cr,AuthorsB.J. Mahler, P. C. Van Metre, E. CallenderEffects of hurricanes Katrina and Rita on the chemistry of bottom sediments in Lake Pontchartrain, Louisiana, USA
The effects of Hurricanes Katrina and Rita and the subsequent unwatering of New Orleans, Louisiana, on the sediment chemistry of Lake Pontchartrain were evaluated by chemical analysis of samples of street mud and suspended and bottom sediments. The highest concentrations of urban-related elements and compounds (e.g., Pb, Zn, polycyclic aromatic hydrocarbons, and chlordane) in bottom sediments exceAuthorsP. C. Van Metre, A. J. Horowitz, B.J. Mahler, W.T. Foreman, C. C. Fuller, M.R. Burkhardt, K. A. Elrick, E. T. Furlong, S. C. Skrobialowski, J.J. Smith, J.T. Wilson, S.D. ZauggCollection, analysis, and age-dating of sediment cores from 56 U.S. lakes and reservoirs sampled by the U.S. Geological Survey, 1992-2001
The U.S. Geological Survey Reconstructed Trends National Synthesis study collected sediment cores from 56 lakes and reservoirs between 1992 and 2001 across the United States. Most of the sampling was conducted as part of the National Water-Quality Assessment (NAWQA) Program. The primary objective of the study was to determine trends in particle-associated contaminants in response to urbanization;AuthorsPeter Van Metre, Jennifer T. Wilson, Christopher C. Fuller, Edward Callender, Barbara MahlerTrends in hydrophobic organic contaminants in urban and reference lake sediments across the United States, 1970-2001
A shift in national policy toward stronger environmental protection began in the United States in about 1970. Conversely, urban land use, population, energy consumption, and vehicle use have increased greatly since then. To assess the effects of these changes on water quality, the U.S. Geological Survey used sediment cores to reconstruct water-quality histories for38 urban and reference lakes acroAuthorsP. C. Van Metre, B.J. MahlerParking lot sealcoat: An unrecognized source of urban polycyclic aromatic hydrocarbons
Polycyclic aromatic hydrocarbons (PAHs) are a ubiquitous contaminant in urban environments. Although numerous sources of PAHs to urban runoff have been identified, their relative importance remains uncertain. We show that a previously unidentified source of urban PAHs, parking lot sealcoat, may dominate loading of PAHs to urban water bodies in the United States. Particles in runoff from parking loAuthorsB.J. Mahler, P. C. Van Metre, T. J. Bashara, J.T. Wilson, D. A. JohnsOccurrence, trends, and sources in particle-associated contaminants in selected streams and lakes in Fort Worth, Texas
Several lakes and stream segments in Fort Worth, Texas, have fish consumption bans because of elevated levels of chlordane, dieldrin, DDE, and polychlorinated biphenyls (PCBs). This study was undertaken to evaluate current loading, trends, and sources in these long-banned contaminants and other particle-associated contaminants commonly found in urban areas. Sampling included suspended sediments atAuthorsPeter C. Van Metre, Jennifer T. Wilson, Glenn R. Harwell, Marcus O. Gary, Franklin T. Heitmuller, Barbara MahlerA chronicle of organochlorine contamination in Clear Creek, Galveston and Harris Counties, Texas, 1960-2002, as recorded in sediment cores
Clear Creek flows through the Texas Coastal Plain from its headwaters southeast of Houston, Texas, to Clear Lake, which empties into Galveston Bay. Segments of Clear Creek were on the State of Texas 303(d) list for 1998, 1999, and 2000 as a result of a fish consumption advisory issued by the Texas Department of Health. One of the contaminants for which the fish consumption advisory was issued is tAuthorsBarbara Mahler, Peter Van MetreTire-wear particles as a source of zinc to the environment
Tire-tread material has a zinc (Zn) content of about 1 wt %. The quantity of tread material lost to road surfaces by abrasion has not been well characterized. Two approaches were used to assess the magnitude of this nonpoint source of Zn in the U.S. for the period 1936−1999. In the first approach, tread-wear rates from the automotive engineering literature were used in conjunction with vehicle disAuthorsT.B. Councell, K.U. Duckenfield, E. R. Landa, E. CallenderContaminant trends in reservoir sediment cores as records of influent stream quality
When reconstructing water-quality histories from lake and reservoir cores, it is sometimes assumed that the chemical signatures in the cores reflect historical water quality in the influent streams. To investigate this assumption, concentrations of metals, PAHs, and organochlorine compounds in sediment cores were compared to those associated with an influent-stream suspended sediment for three resAuthorsP. C. Van Metre, B.J. MahlerTrends in chemical concentration in sediment cores from three lakes in New Jersey and one lake on Long Island, New York
Sediment cores were extracted from three lakes in northeastern New Jersey and one lake on western Long Island, New York, as part of the U.S. Geological Survey National Water-Quality Assessment Program. Sediment layers were dated by use of cesium-137 (137Cs), copper, lead, or dichlorodiphenyl-trichloroethane (DDT) profiles. Sediment layers were analyzed for seven selected trace elements, includingAuthorsGary R. Long, Edward C. Callender, Mark A. Ayers, Peter C. Van Metre