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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4096

13C and 15N NMR identification of product compound classes from aqueous and solid phase photodegradation of 2,4,6-trinitrotoluene 13C and 15N NMR identification of product compound classes from aqueous and solid phase photodegradation of 2,4,6-trinitrotoluene

Abstract Photolysis is one of the main transformation pathways for 2,4,6-trinitrotoluene (TNT) released into the environment. Upon exposure to sunlight, TNT is known to undergo both oxidation and reduction reactions with release of nitrite, nitrate, and ammonium ions, followed by condensation reactions of the oxidation and reduction products. In this study, compound classes of...
Authors
Kevin A. Thorn

Competitive interactions among H, CU, and Zn ion moderate aqueous uptake of Cu and Zn by an aquatic insect Competitive interactions among H, CU, and Zn ion moderate aqueous uptake of Cu and Zn by an aquatic insect

The absorption of aqueous copper (Cu) and zinc (Zn) by aquatic insects, a group widely used to assess water quality, is unresolved. This study examined interactions among Cu, Zn, and protons that potentially moderate Cu and Zn uptake by the acid-tolerant stonefly Zapada sp. Saturation uptake kinetics was imposed to identify competitive mechanisms. Decreasing pH reduced the maximum...
Authors
Daniel J. Cain, Marie Noele Croteau, Christopher C. Fuller

Spatial fingerprinting of biogenic and anthropogenic volatile organic compounds in an arid unsaturated zone Spatial fingerprinting of biogenic and anthropogenic volatile organic compounds in an arid unsaturated zone

Subsurface volatile organic compounds (VOCs) can pose risks to human and environmental health and mediate biological processes. VOCs have both anthropogenic and biogenic origins, but the relative importance of these sources has not been explored in subsurface environments. This study synthesizes 17 years of VOC data from the Amargosa Desert Research Site (ADRS) with the goal of improving
Authors
Christopher Green, Wentai Luo, Christopher H. Conaway, Karl B. Haase, Ronald J. Baker, Brian J. Andraski

Influence of dissolved organic carbon on the acute toxicity of copper and zinc to White Sturgeon (Acipenser transmontanus) and a Cladoceran (Ceriodaphnia dubia) Influence of dissolved organic carbon on the acute toxicity of copper and zinc to White Sturgeon (Acipenser transmontanus) and a Cladoceran (Ceriodaphnia dubia)

We conducted acute lethality tests with white sturgeon (Acipenser transmontanus) and Ceriodaphnia dubia exposed to copper and zinc at dissolved organic carbon concentrations ranging from 0.5 to 5.5 mg/L. Dissolved organic carbon had minimal effects on zinc toxicity but did have a protective effect on acute copper toxicity, which was equal to that predicted by the copper biotic ligand...
Authors
Chris D. Ivey, John M. Besser, Jeffery A. Steevens, Michael Walther, Vanessa Melton

De facto water reuse: Bioassay suite approach delivers depth and breadth in endocrine active compound detection De facto water reuse: Bioassay suite approach delivers depth and breadth in endocrine active compound detection

Although endocrine disrupting compounds (EDCs) have been detected in wastewater and surface waters worldwide using a variety of in vitro effects-based screening tools, e.g. bioassays, few have examined potential attenuation of environmental contaminants by both natural (sorption, degradation, etc) and anthropogenic (water treatment practices) processes. This study used several bioassays...
Authors
Elizabeth K Medlock Kakaley, Brett R. Blackwell, Mary C. Cardon, Justin M. Conley, Nicola Evans, David J. Feifarek, Edward Furlong, Susan T. Glassmeyer, L. Earl Gray, Phillip C. Hartig, Dana W. Kolpin, Marc A. Mills, Laura Rosenblum, Daniel L. Villeneuve, Vickie S. Wilson

Geophysical mapping of plume discharge to surface water at a crude oil spill site: Inversion versus machine learning Geophysical mapping of plume discharge to surface water at a crude oil spill site: Inversion versus machine learning

The interpretation of geophysical survey results to answer hydrologic, engineering, and geologic questions is critical to diverse problems for management of water, energy, and mineral resources. Although geophysical images provide valuable qualitative insight into subsurface architecture and conditions, translating geophysical images into quantitative information (e.g., saturation...
Authors
Neil Terry, Frederick D. Day-Lewis, John W. Lane, Jared J. Trost, Barbara A. Bekins

Examining the extraction efficiency of petroleum-derived dissolved organic matter in contaminated groundwater plumes Examining the extraction efficiency of petroleum-derived dissolved organic matter in contaminated groundwater plumes

The extraction efficiency of petroleum-derived dissolved organic matter (DOM) was examined for groundwater samples from an aquifer contaminated with crude oil. Four different types of extraction were used to determine which method is best suited for the analysis of potentially toxic petroleum-derived DOM. The four types were a liquid-liquid extraction (LLE) with dichloromethane (EPA...
Authors
Phoebe Zito, Rana Ghannam, Barbara A. Bekins, David C. Podgorski

De facto reuse and disinfection by-products in drinking water systems in the Shenandoah River watershed De facto reuse and disinfection by-products in drinking water systems in the Shenandoah River watershed

De facto reuse is increasingly being studied among the variety of stressors that are relevant to drinking water systems that obtain their source water from surface waters. De facto reuse may influence the levels and types of precursors relevant to formation of disinfection by-products (DBPs) in surface water systems. DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) have...
Authors
Richard J Weisman, Larry B. Barber, Jennifer Rapp, Celso M Ferreira

Lithostratigraphic, geophysical, and hydrogeologic observations from a boring drilled to bedrock in glacial sediments near Nantucket Sound in East Falmouth, Massachusetts Lithostratigraphic, geophysical, and hydrogeologic observations from a boring drilled to bedrock in glacial sediments near Nantucket Sound in East Falmouth, Massachusetts

In spring 2016, a 310-foot-deep boring (named MA–FSW 750) was drilled by the U.S. Geological Survey near Nantucket Sound in East Falmouth, Massachusetts, to investigate the hydrogeology of the southern coast of western Cape Cod. Few borings that are drilled to bedrock exist in the area, and the study area was selected to fill a gap between comprehensive geologic datasets inland to the...
Authors
Robert B. Hull, Carole D. Johnson, Byron D. Stone, Denis R. LeBlanc, Timothy D. McCobb, Stephanie N. Phillips, Katherine L. Pappas, John W. Lane

Toward sustainable environmental quality: Priority research questions for North America Toward sustainable environmental quality: Priority research questions for North America

Anticipating, identifying, and prioritizing strategic needs represent essential activities by research organizations. Decided benefits emerge when these pursuits engage globally important environment and health goals, including the United Nations Sustainable Development Goals. To this end, horizon scanning efforts can facilitate identification of specific research needs to address grand...
Authors
Anne Fairbrother, Derek C.G. Muir, Keith R. Solomon, Gerald T. Ankley, Murray A. Rudd, Alistair B. A. Boxall, William J. Adams, Jennifer N. Apell, Kevin L. Armbrust, Bonnie J. Blalock, Sarah R. Bowman, Linda M. Campbell, George P. Cobb, Kristin A. Connors, David A. Dreier, Marlene S. Evans, Carol J. Henry, Robert A. Hoke, Magali Houde, Stephen J. Klaine, Rebecca D. Klaper, Sigrun A. Kullik, Roman P. Lanno, Charles Meyer, Mary Ann Ottinger, Elias Oziolor, Elijah J. Petersen, Helen C. Poynton, Pamela J. Rice, Gabriela Rodriguez-Fuentes, Alan Samel, Joseph R. Shaw, Jeffery A. Steevens, Tim A. Verslycke, Doris E. Vidal-Dorsch, Scott M. Weir, Peter Wilson, Bryan W. Brooks

Effects of microcystin-LR on juvenile Lost River suckers (Deltistes luxatus) during feeding trials, Upper Klamath Lake, Oregon, 2014−16 Effects of microcystin-LR on juvenile Lost River suckers (Deltistes luxatus) during feeding trials, Upper Klamath Lake, Oregon, 2014−16

Executive Summary Historically, populations of Lost River suckers (Deltistes luxatus) of the Upper Klamath Basin were so numerous that they were commercially harvested; however, declining numbers throughout the 20th century led to the listing of the species under the United States Endangered Species Act in 1988. Habitat destruction, poor water quality, competition with (and predation by)...
Authors
Barbara A. Martin, Kathy R. Echols, Diane G. Elliott, Kevin Feltz, Carla M. Conway, Summer M. Burdick

Water-quality, bed-sediment, and biological data (October 2016 through September 2017) and statistical summaries of data for streams in the Clark Fork Basin, Montana Water-quality, bed-sediment, and biological data (October 2016 through September 2017) and statistical summaries of data for streams in the Clark Fork Basin, Montana

Water, bed sediment, and biota were sampled in selected streams from Butte to near Missoula, Montana, as part of a monitoring program in the Clark Fork Basin of western Montana. The sampling program was led by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the Clark Fork Basin and emphasize trace elements...
Authors
Tom Cleasby, Michelle I. Hornberger, Terry L. Heinert, Matthew A. Turner
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