U.S. Geological Survey (USGS) scientists have discovered that rainwater recharging the water table above petroleum contamination plumes affects how plumes grow and the rate that petroleum products (in this case crude oil) degrade and weather in ground water. The amount of recharge affects the migration of oil in the subsurface, how chemicals dissolve from the oil into ground water, and the transport of nutrients and other dissolved constituents that control the natural attenuation of contaminants to the water table. USGS scientists working at the Bemidji Crude Oil Spill Research Site have developed a method for estimating ground-water recharge amounts. The method quantifies the soil moisture balance by continuous monitoring of soil moisture content.
Applying the new method at the site, the scientists found that the estimated recharge rate under depressions on the land surface is about double the rate in areas where the land surface is just a few feet higher in elevation. They have documented that the variation in recharge results in highly variable rates of crude oil degradation in the subsurface oil body. Faster oil degradation rates occur under areas where there is increased recharge because there is a corresponding increase in the transport of the nutrients and other dissolved chemicals the microbes need for metabolism and growth. The extreme variation in degradation rates calls into question a widely used method for dating the timing of an oil spill that's based on an assumption of relatively consistent degradation throughout a contamination site. The new method and the information on variable degradation rates can be used by remediation professionals to more accurately document the degradation of petroleum contaminant plumes for sites where monitored natural attenuation is the cleanup remedy of choice.
References
Bekins, B.A., Hostettler, F.D., Herkelrath, W.N., Delin, G.N., Warren, E., and Essaid, H.I., 2005, Progression of methanogenic degradation of crude oil in the subsurface: Environmental Geosciences, v. 12, no. 2, p. 139-152.
Delin, G.N., and Herkelrath, W.N., 2005, Use of soil moisture probes to estimate ground water recharge at an oil spill site, Journal of the American Water Resources Association, v. 41, no. 6, p. 1259-1277.
Below are other science projects associated with this project.
Cyclical Mobilization and Attenuation of Naturally Occurring Arsenic in an Underground Petroleum Plume
U.S. Geological Survey Identifies Crude-Oil Metabolites in Subsurface Plumes
Remote Sensing Provides a National View of Cyanobacteria Blooms
Ethanol-Containing Fuel Spills Enhanced Natural Trace Element Release from Sediments in an Experimental Setting
Below are publications associated with this project.
Progression of methanogenic degradation of crude oil in the subsurface
Use of soil moisture probes to estimate ground water recharge at an oil spill site
Ground water contamination by crude oil near Bemidji, Minnesota
- Overview
U.S. Geological Survey (USGS) scientists have discovered that rainwater recharging the water table above petroleum contamination plumes affects how plumes grow and the rate that petroleum products (in this case crude oil) degrade and weather in ground water. The amount of recharge affects the migration of oil in the subsurface, how chemicals dissolve from the oil into ground water, and the transport of nutrients and other dissolved constituents that control the natural attenuation of contaminants to the water table. USGS scientists working at the Bemidji Crude Oil Spill Research Site have developed a method for estimating ground-water recharge amounts. The method quantifies the soil moisture balance by continuous monitoring of soil moisture content.
Trench with unsaturated-zone instruments installed in trench wall Applying the new method at the site, the scientists found that the estimated recharge rate under depressions on the land surface is about double the rate in areas where the land surface is just a few feet higher in elevation. They have documented that the variation in recharge results in highly variable rates of crude oil degradation in the subsurface oil body. Faster oil degradation rates occur under areas where there is increased recharge because there is a corresponding increase in the transport of the nutrients and other dissolved chemicals the microbes need for metabolism and growth. The extreme variation in degradation rates calls into question a widely used method for dating the timing of an oil spill that's based on an assumption of relatively consistent degradation throughout a contamination site. The new method and the information on variable degradation rates can be used by remediation professionals to more accurately document the degradation of petroleum contaminant plumes for sites where monitored natural attenuation is the cleanup remedy of choice.
References
USGS scientists inoculating microbial growth media to determine the number and type of microorganisms carrying out biodegradation in the contaminated aquifer. Bekins, B.A., Hostettler, F.D., Herkelrath, W.N., Delin, G.N., Warren, E., and Essaid, H.I., 2005, Progression of methanogenic degradation of crude oil in the subsurface: Environmental Geosciences, v. 12, no. 2, p. 139-152.
Delin, G.N., and Herkelrath, W.N., 2005, Use of soil moisture probes to estimate ground water recharge at an oil spill site, Journal of the American Water Resources Association, v. 41, no. 6, p. 1259-1277.
- Science
Below are other science projects associated with this project.
Cyclical Mobilization and Attenuation of Naturally Occurring Arsenic in an Underground Petroleum Plume
Scientists found that naturally occurring arsenic in aquifer sediments was mobilized into groundwater and attenuated through reattachment to sediments within an underground petroleum plume. Understanding these patterns identifies anthropogenic factors that affect arsenic presence and magnitude in groundwater.U.S. Geological Survey Identifies Crude-Oil Metabolites in Subsurface Plumes
U.S. Geological Survey (USGS) scientists studying two subsurface crude-oil spill sites in Minnesota measured concentrations of oil breakdown products (metabolites) at greater concentrations than parent compound concentrations.Remote Sensing Provides a National View of Cyanobacteria Blooms
Four Federal agencies, including the U.S. Geological Survey (USGS), are collaborating to transform satellite data into information managers can use to protect ecological and human health from freshwater contaminated by harmful algal blooms.Ethanol-Containing Fuel Spills Enhanced Natural Trace Element Release from Sediments in an Experimental Setting
Experimental field research simulating hydrocarbon spills by researchers from the U.S. Geological Survey (USGS), Virginia Tech, and the University of St. Thomas showed that mixed ethanol and petroleum-based fuels increased the rate by which arsenic and other natural trace elements are released from aquifer sediments to groundwater when compared to petroleum-based fuels alone. - Publications
Below are publications associated with this project.
Progression of methanogenic degradation of crude oil in the subsurface
Our results show that subsurface crude-oil degradation rates at a long-term research site were strongly influenced by small-scale variations in hydrologic conditions. The site is a shallow glacial outwash aquifer located near Bemidji in northern Minnesota that became contaminated when oil spilled from a broken pipeline in August 1979. In the study area, separate-phase oil forms a subsurface oil boAuthorsB.A. Bekins, F. D. Hostettler, W.N. Herkelrath, G. N. Delin, E. Warren, H.I. EssaidUse of soil moisture probes to estimate ground water recharge at an oil spill site
Soil moisture data collected using an automated data logging system were used to estimate ground water recharge at a crude oil spill research site near Bemidji, Minnesota. Three different soil moisture probes were tested in the laboratory as well as the field conditions of limited power supply and extreme weather typical of northern Minnesota: a self‐contained reflectometer probe, and two time domAuthorsG. N. Delin, W.N. HerkelrathGround water contamination by crude oil near Bemidji, Minnesota
Ground-water contamination by crude oil, and other petroleum-based liquids, is a widespread problem. An average of 83 crude-oil spills occurred per year during 1994-96 in the United States, each spilling about 50,000 barrels of crude oil (U.S. Office of Pipeline Safety, electronic commun., 1997). An understanding of the fate of organic contaminants (such as oil and gasoline) in the subsurface is nAuthorsG. N. Delin, H.I. Essaid, I.M. Cozzarelli, M.H. Lahvis, B.A. Bekins