Emily Woodward is a Physical Scientist with the Pennsylvania Water Science Center. Her research focuses on the fate and transport of organic contaminants in surface water and soil.
Current Projects
- PFAS monitoring in Pennsylvania surface waters
- PFAS enrichment in natural foams on surface waters within the Delaware River Basin
- Pesticide concentrations and mass in runoff from lettuce fields planted with treated seeds (California)
Professional Experience
2021-Present – Physical Scientist, Pennsylvania Water Science Center
2019-2021 – Physical Scientist, California Water Science Center
2018-2019 – Project Scientist, University of California, Davis
2017-2018 – Lecturer, Geology Department, California State University, Sacramento
2016-2018 – Postdoctoral Soil Scientist, California Water Science Center
Education and Certifications
Ph.D., Soil Science and Biogeochemistry, Pennsylvania State University, 2016
M.S., Soil Science, Pennsylvania State University, 2012
B.A., Geology and Environmental Science, University of Akron, 2010
Science and Products
Costs and Benefits of Nitrapyrin
Pesticide Fate Research Group (PFRG)
New Study Measures Crop Bactericide, Nitrapyrin, in Iowa Streams
Evaluation of ELISA for the Analysis of Imidacloprid in Plasma, Liver, and Fecal Matter
Insecticide and fungicide concentrations in irrigation runoff and soils from a lettuce field in the Salinas Valley, California, 2019 and 2020
Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US
Herbicide safeners and associated stream flow for water samples collected across Iowa and Illinois (2016-2017).
Per- and polyfluorinated alkyl substances (PFAS) in Pennsylvania surface waters: A statewide assessment, associated sources, and land-use relations
Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive guided extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
Comparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California
Evaluation of ELISA for the analysis of imidacloprid in biological matrices: Cross-reactivities, matrix interferences, and comparison to LC-MS/MS
Widespread use of the nitrification inhibitor nitrapyrin: Assessing benefits and costs to agriculture, ecosystems, and environmental health
Pesticide mixtures in the Sacramento–San Joaquin Delta, 2016–17: Results from year 2 of the Delta Regional Monitoring Program
Fate and transport of nitrapyrin in agroecosystems: Occurrence in agricultural soils, subsurface drains, and receiving streams in the Midwestern US
Occurrence of dichloroacetamide herbicide safeners and co-applied herbicides in midwestern U.S. streams
Nitrapyrin in streams: The first study documenting off-field transport of a nitrogen stabilizer compound
Non-USGS Publications**
**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.
Science and Products
- Science
Costs and Benefits of Nitrapyrin
In December 2020, our research group (as part of the Food Integrated Science Team) published a review of nitrapyrin costs and benefits in the journal Environmental Science & Technology.Pesticide Fate Research Group (PFRG)
Pesticides are applied in agricultural and urban areas to control weeds, insects, fungus, and other pests. Applied pesticides and their degradates can be transported off-site through a variety of mechanisms; these pesticides can then be found in non-target areas. Pesticide transport can occur through the atmosphere, in the aqueous phase (surface and groundwater) and associated with soil/sediment...New Study Measures Crop Bactericide, Nitrapyrin, in Iowa Streams
First-ever reconnaissance study documents the off-field transport of nitrapyrin — a nitrification inhibitor applied with fertilizers as a bactericide to kill natural soil bacteria for the purpose of increasing crop yields — to adjacent streams. This study is the first step in understanding the transport, occurrence, and potential effects of nitrapyrin or similar compounds on nitrogen processing in... - Data
Evaluation of ELISA for the Analysis of Imidacloprid in Plasma, Liver, and Fecal Matter
Neonicotinoids have become the most widely used insecticides in world with rapid growth in applications as seed coatings. Nontarget organisms are exposed to concentrated levels of pesticidal active ingredients through ingestion of treated seeds. To better understand pesticide fate, analytical methods are necessary to rapidly screen and accurately quantitate contaminants in environmental and biologInsecticide and fungicide concentrations in irrigation runoff and soils from a lettuce field in the Salinas Valley, California, 2019 and 2020
Irrigation runoff and soil samples were collected from a lettuce field located at the USDA-ARS Spence Research farm in the Salinas Valley, California to measure neonicotinoid insecticides (clothianidin and imidacloprid) and a fungicide (azoxystrobin) applied via coated seed and drench treatments. The field trial was designed to evaluate four treatments with replication: 1) control, untreated seed,Nitrapyrin, 6-CPA, and herbicide concentrations in agricultural soils, subsurface drains, and corresponding streams in the Midwestern US
Nitrapyrin is a nitrification inhibitor that is co-applied with N-fertilizer in agroecosystems. Over the course of one year (March 2016 to June 2017), 192 water samples from seven streams across Iowa and Illinois were analyzed for nitrapyrin, its degradate 6-chloropicolinic acid (6-CPA), and three widely used herbicides acetochlor, atrazine, and metolachlor. Additional environmental samples were cHerbicide safeners and associated stream flow for water samples collected across Iowa and Illinois (2016-2017).
Four dichloroacetamide herbicide safeners (AD-67, benoxacor, dichlormid, and furilazole) and two co-applied herbicides (acetochlor and metolachlor) were measured in water samples from 7 streams across Iowa and Illinois. Iowa water samples were collected from March 2016 to June 2017, and Illinois water samples were collected from September 2016 to June 2017. The compounds studied are applied to cor - Multimedia
- Publications
Per- and polyfluorinated alkyl substances (PFAS) in Pennsylvania surface waters: A statewide assessment, associated sources, and land-use relations
The objectives of this study are to identify per- and polyfluoroalkyl substances (PFAS) in Pennsylvania surface waters, corresponding associations with potential sources of PFAS contamination (PSOC) and other parameters, and compare raw surface water concentrations to human and ecological benchmarks. Surface water samples from 161 streams were collected in September 2019 and were analyzed for 33 tAuthorsSara Breitmeyer, Amy Williams, Joseph W. Duris, Lee W. Eicholtz, Dustin R. Shull, Timothy A. Wertz, Emily WoodwardMultiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive guided extraction with analysis by gas and liquid chromatography tandem mass spectroscopy
The development of sample processing techniques that recover a broad suite of pesticides from solid matrices, while mitigating coextracted matrix interferences, and reducing processing time is beneficial for high throughput analyses. The objective of this study was to evaluate the effectiveness of an automated extraction system for pesticide analyses in solid environmental samples. An Energized DiAuthorsGabrielle Pecora Black, Emily Woodward, Corey Sanders, Michael S. Gross, Michelle HladikComparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California
Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to planting). In California, multiple crops, including lettuce, can be grown using neonicotinoid treated seeds or receive a direct neonicotinoid soil application (drenching) at planting. Using research plots, this study compared pesticiAuthorsEmily Woodward, Michelle Hladik, Anson Main, Michael Cahn, James Orlando, Jennifer TeerlinkEvaluation of ELISA for the analysis of imidacloprid in biological matrices: Cross-reactivities, matrix interferences, and comparison to LC-MS/MS
Imidacloprid is among the most used pesticides worldwide and there are toxicity concerns for nontarget organisms. Accurate and sensitive methods are necessary to quantitate imidacloprid concentrations in biological matrices to better understand their fate and effects. Here we evaluated an enzyme-linked immunosorbent assay (ELISA) kit for the analysis of imidacloprid in biological samples. FollowinAuthorsMichael S. Gross, Emily Woodward, Michelle HladikWidespread use of the nitrification inhibitor nitrapyrin: Assessing benefits and costs to agriculture, ecosystems, and environmental health
Agricultural production and associated applications of nitrogen (N) fertilizers have increased dramatically in the last century, and current projections to 2050 show that demands will continue to increase as the human population grows. Applied in both organic and inorganic fertilizer forms, N is an essential nutrient in crop productivity. Increased fertilizer applications, however, create the poteAuthorsEmily Woodward, Thea Margaret Edwards, Carrie E Givens, Dana W. Kolpin, Michelle HladikPesticide mixtures in the Sacramento–San Joaquin Delta, 2016–17: Results from year 2 of the Delta Regional Monitoring Program
The Delta Regional Monitoring Program was developed by the Central Valley Regional Water Quality Control Board in response to the decline of pelagic fish species in the Sacramento–San Joaquin Delta that was observed in the early 2000s. The U.S. Geological Survey, in cooperation with the Delta Regional Monitoring Program, has been responsible for collecting and analyzing surface-water samples for aAuthorsMatthew De Parsia, Emily E. Woodward, James L. Orlando, Michelle L. HladikFate and transport of nitrapyrin in agroecosystems: Occurrence in agricultural soils, subsurface drains, and receiving streams in the Midwestern US
Nitrapyrin is a nitrification inhibitor that is co-applied with nitrogen fertilizer in agroecosystems. There is limited information on the fate of nitrapyrin after it is applied to agricultural soils. Over the course of one year (March 2016 to June 2017), 192 water samples from seven streams across Iowa and Illinois were analyzed for nitrapyrin, its metabolite 6‑chloropicolinic acid (6‑CPA), and tAuthorsEmily Woodward, Dana W. Kolpin, Wei Zheng, Nancy L Holm, Shannon M. Meppelink, Paul J. Terrio, Michelle HladikOccurrence of dichloroacetamide herbicide safeners and co-applied herbicides in midwestern U.S. streams
Dichloroacetamide safeners (e.g., AD-67, benoxacor, dichlormid, and furilazole) are co-applied with chloroacetanilide herbicides to protect crops from herbicide toxicity. While such safeners have been used since the early 1970s, there are minimal data about safener usage, occurrence in streams, or potential ecological effects. This study focused on one of these research gaps, occurrence in streamsAuthorsEmily Woodward, Michelle Hladik, Dana W. KolpinNitrapyrin in streams: The first study documenting off-field transport of a nitrogen stabilizer compound
Nitrapyrin is a bactericide that is co-applied with fertilizer to prevent nitrification and enhance corn yields. While there have been studies of the environmental fate of nitrapyrin, there is no documentation of its off-field transport to streams. In 2016, 59 water samples from 11 streams across Iowa were analyzed for nitrapyrin and its degradate, 6-chloropicolinic acid (6-CPA), along with threeAuthorsEmily Woodward, Michelle Hladik, Dana W. KolpinNon-USGS Publications**
Woodward, E., Raij-Hoffman, I., Scow, K., and Tautges, N., 2022, Alfalfa reduces winter nitrate leaching relative to organic and conventional annual vegetable systems: Resin bag field measurements and modeling with HYDRUS-1D. Journal of Soil and Water Conservation. 77 (5): 450-465.Franklin, A.M., Williams, C.F., Andrews, D.M., Woodward, E.E., and Watson, J.E. 2016. Uptake of three antibiotics and an antiepileptic drug by wheat crops spray irrigated with wastewater treatment plant effluent. J. Environ. Qual. 45 (2) 546-554.Woodward, E.E., Andrews, D.M., Williams, C.F., and Watson, J.E. 2014. Vadose zone transport of natural and synthetic estrogen hormones at Penn State's "Living Filter" wastewater irrigation site. J. Environ. Qual. 43 (6) 1933-1941.Woodward, E.E., and Sasowsky, I.D. 2009. A spreadsheet program (ScallopEx) to calculate paleovelocities from cave wall scallops. Acta Carsologica 38 (2-3).**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.
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