Cross section of a hydrothermal vent chimney from East Diamante Caldera in the Mariana volcanic arc, west Pacific Ocean, collected during a 2010 research cruise. Most of the sample is zinc sulfide.
James Hein
zation
Geologist Emeritus with the USGS Pacific Coastal and Marine Science Center
Science and Products
Global Marine Mineral Resources
The Global Marine Mineral Resources project studies deep ocean minerals that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions. Our research concerns the setting, genesis, and metal enrichment processes of mineral occurrences, the relationship between marine minerals related and deep-sea biota, and the potential geochemical footprint of any seafloor mining. We...
Global ferromanganese crust and abyssal ferromanganese nodule prospective occurrence regions
This data release is a polygon shapefile representing prospective occurrence regions of ferromanganese crusts and abyssal ferromanganese nodules on the seafloor throughout the global oceans. Polygons represent areas where oceanographic criteria, such as low sedimentation rate and moderate primary productivity, overlap with geologic criteria, including regions with appropriate seafloor...
Geochemistry of ferromanganese crusts, nodules, and hydrothermally altered rocks from the Arctic Ocean
Ferromanganese crusts, nodules, and hydrothermally altered rocks were collected via dredge within the Amerasia Basin in the Arctic Ocean during USCGC icebreaker Healy cruises HLY0805, HLY0905, and HLY1202 in 2008, 2009, and 2012 respectively. Dredged samples were donated and sent to USGS for subsampling and major and trace element geochemical analyses. Major and trace element data as...
Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater
This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals. These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for...
Sorbed-water (H2O-) corrected chemistry for ferromanganese crust samples from the western equatorial Pacific Ocean
Ferromanganese crust samples were collected via dredge during four oceanographic research cruises to the western equatorial Pacific Ocean. The location (latitude, longitude, depth) and concentrations of 27 major and trace elements in the most recent growth layers of ferromanganese crusts from 57 dredge sites are presented here, as well as select seawater chemistry at each location. These...
Bathymetry of the Republic of the Marshall Islands and vicinity
The bathymetric map of the Republic of the Marshall Islands and vicinity is bounded by a window of latitude 3 to 17 degrees North, longitude 153 to 175 degrees East. The map was compiled from surveys conducted by the USGS, Korean Ocean Research and Development Institute, and published gridded data. In addition to national jurisdictions, island and atoll coastlines are indicated on the...
Cross section of a hydrothermal vent chimney from East Diamante Caldera in the Mariana volcanic arc, west Pacific Ocean, collected during a 2010 research cruise. Most of the sample is zinc sulfide.
Filter Total Items: 167
Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean
Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so...
Authors
James R. Hein, Kira Mizell, Amy Gartman
Crystal chemistry of thallium in marine ferromanganese deposits
Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO2), the principle manganate mineral in oxic and suboxic environments, and (2) being able to...
Authors
Alain Manceau, Alexandre Simionovici, Nathaniel Findling, Pieter Glatzel, Blanka Detlefs, Anna V Wegorzewski, Kira Mizell, James R. Hein, Andrea Koschinsky
Deep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals
The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest.Polymetallic nodules are essentially two...
Authors
James R. Hein, Kira Mizell
Estimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules
Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for...
Authors
Kira Mizell, James R. Hein, Manda Viola Au, Amy Gartman
Geochemical insights into formation of enigmatic ironstones from Rio Grande rise, South Atlantic Ocean
Rio Grande Rise (RGR) is an intraplate oceanic elevation in the South Atlantic Ocean that formed at a hotspot on the Mid-Atlantic Ridge during the Cretaceous. In spreading center and hotspot environments, ironstones form mainly by biomineralization of reduced Fe from hydrothermal fluids or oxidation of sulfide deposits. However, RGR has been considered aseismic and volcanically inactive...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Kenneth A. Farley, Jonathon Treffkorn, Luigi Jovane
Miocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean
Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87Sr/86Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Luigi Jovane
Changes in seabed mining
Chapter 23 of the First World Ocean Assessment (WOA I) focused on marine mining, and particularly on established extractive industries, which are predominantly confined to near-shore areas, where shallow-water, near-shore aggregate and placer deposits, and somewhat deeper water phosphate deposits are found (United Nations, 2017a). At the time of publication, there were no commercially...
Authors
James R. Hein, Pedro Madureira, Maria João Bebianno, Ana Colaço, Luis M. Pinheiro, Richard Roth, Pradeep K. Singh, Anastasia Strati, Joshua T. Tuhumwire
Ocean floor manganese deposits
Much of the dissolved Mn delivered to the oceans is slowly oxidized and precipitated alongside varying amounts of Fe into Mn and ferromanganese (FeMn) mineral deposits that occur extensively in the deep ocean wherever sediment accumulation is low and substrate is available. FeMn crusts grow as pavements on rock outcrops throughout the global ocean whereas nodules form as individual FeMn...
Authors
Kira Mizell, James R. Hein
Sphalerite oxidation in seawater with covellite: Implications for seafloor massive sulfide deposits and mine waste
Metal sulfide minerals exist in several marine environments and are in thermodynamic disequilibrium with oxygenated seawater from the time of their formation. Oxidation is both ubiquitous and heterogeneous, as observational and experimental evidence demonstrates that sulfide minerals may oxidize completely on decadal timescales (hydrothermal plumes) or incompletely in billions of years...
Authors
Amy Gartman, Samantha P. Whisman, James R. Hein
The effects of phosphatization on the mineral associations and speciation of Pb in ferromanganese crusts
The older layers of thick ferromanganese (FeMn) crusts from the central Pacific Ocean have undergone diagenetic phosphatization, during which carbonate fluorapatite (CFA) filled fractures and pore space and replaced carbonates. The effects of phosphatization on individual trace metal concentrations, speciation, and phase associations in FeMn crusts remain poorly understood yet may be...
Authors
Kira Mizell, James R. Hein, Andrea Koschinsky, Sarah M. Hayes
Changes in sediment source areas to the Amerasia Basin, Arctic Ocean, over the past 5.5 million years based on radiogenic isotopes (Sr, Nd, Pb) of detritus from ferromanganese crusts
Ferromanganese (FeMn) crusts provide a useful paleoenvironmental archive for studying the poorly understood climatic, oceanographic, and geologic evolution of the Arctic Ocean. This study is based on the identification and temporal reconstruction of sources and inferred transport pathways of terrigenous material in FeMn crusts collected from several sites across the Amerasia Basin...
Authors
Natalia Konstantinova, James R. Hein, Kira Mizell, Georgy Cherkashov, Brian Dreyer, Deborah Hutchinson
Genesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Terrence Blackburn, Luigi Jovane
Science and Products
Global Marine Mineral Resources
The Global Marine Mineral Resources project studies deep ocean minerals that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions. Our research concerns the setting, genesis, and metal enrichment processes of mineral occurrences, the relationship between marine minerals related and deep-sea biota, and the potential geochemical footprint of any seafloor mining. We...
Global ferromanganese crust and abyssal ferromanganese nodule prospective occurrence regions
This data release is a polygon shapefile representing prospective occurrence regions of ferromanganese crusts and abyssal ferromanganese nodules on the seafloor throughout the global oceans. Polygons represent areas where oceanographic criteria, such as low sedimentation rate and moderate primary productivity, overlap with geologic criteria, including regions with appropriate seafloor...
Geochemistry of ferromanganese crusts, nodules, and hydrothermally altered rocks from the Arctic Ocean
Ferromanganese crusts, nodules, and hydrothermally altered rocks were collected via dredge within the Amerasia Basin in the Arctic Ocean during USCGC icebreaker Healy cruises HLY0805, HLY0905, and HLY1202 in 2008, 2009, and 2012 respectively. Dredged samples were donated and sent to USGS for subsampling and major and trace element geochemical analyses. Major and trace element data as...
Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater
This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals. These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for...
Sorbed-water (H2O-) corrected chemistry for ferromanganese crust samples from the western equatorial Pacific Ocean
Ferromanganese crust samples were collected via dredge during four oceanographic research cruises to the western equatorial Pacific Ocean. The location (latitude, longitude, depth) and concentrations of 27 major and trace elements in the most recent growth layers of ferromanganese crusts from 57 dredge sites are presented here, as well as select seawater chemistry at each location. These...
Bathymetry of the Republic of the Marshall Islands and vicinity
The bathymetric map of the Republic of the Marshall Islands and vicinity is bounded by a window of latitude 3 to 17 degrees North, longitude 153 to 175 degrees East. The map was compiled from surveys conducted by the USGS, Korean Ocean Research and Development Institute, and published gridded data. In addition to national jurisdictions, island and atoll coastlines are indicated on the...
Zinc-sulfide chimney
Cross section of a hydrothermal vent chimney from East Diamante Caldera in the Mariana volcanic arc, west Pacific Ocean, collected during a 2010 research cruise. Most of the sample is zinc sulfide.
Cross section of a hydrothermal vent chimney from East Diamante Caldera in the Mariana volcanic arc, west Pacific Ocean, collected during a 2010 research cruise. Most of the sample is zinc sulfide.
Filter Total Items: 167
Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean
Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so...
Authors
James R. Hein, Kira Mizell, Amy Gartman
Crystal chemistry of thallium in marine ferromanganese deposits
Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO2), the principle manganate mineral in oxic and suboxic environments, and (2) being able to...
Authors
Alain Manceau, Alexandre Simionovici, Nathaniel Findling, Pieter Glatzel, Blanka Detlefs, Anna V Wegorzewski, Kira Mizell, James R. Hein, Andrea Koschinsky
Deep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals
The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest.Polymetallic nodules are essentially two...
Authors
James R. Hein, Kira Mizell
Estimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules
Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for...
Authors
Kira Mizell, James R. Hein, Manda Viola Au, Amy Gartman
Geochemical insights into formation of enigmatic ironstones from Rio Grande rise, South Atlantic Ocean
Rio Grande Rise (RGR) is an intraplate oceanic elevation in the South Atlantic Ocean that formed at a hotspot on the Mid-Atlantic Ridge during the Cretaceous. In spreading center and hotspot environments, ironstones form mainly by biomineralization of reduced Fe from hydrothermal fluids or oxidation of sulfide deposits. However, RGR has been considered aseismic and volcanically inactive...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Kenneth A. Farley, Jonathon Treffkorn, Luigi Jovane
Miocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean
Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87Sr/86Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Luigi Jovane
Changes in seabed mining
Chapter 23 of the First World Ocean Assessment (WOA I) focused on marine mining, and particularly on established extractive industries, which are predominantly confined to near-shore areas, where shallow-water, near-shore aggregate and placer deposits, and somewhat deeper water phosphate deposits are found (United Nations, 2017a). At the time of publication, there were no commercially...
Authors
James R. Hein, Pedro Madureira, Maria João Bebianno, Ana Colaço, Luis M. Pinheiro, Richard Roth, Pradeep K. Singh, Anastasia Strati, Joshua T. Tuhumwire
Ocean floor manganese deposits
Much of the dissolved Mn delivered to the oceans is slowly oxidized and precipitated alongside varying amounts of Fe into Mn and ferromanganese (FeMn) mineral deposits that occur extensively in the deep ocean wherever sediment accumulation is low and substrate is available. FeMn crusts grow as pavements on rock outcrops throughout the global ocean whereas nodules form as individual FeMn...
Authors
Kira Mizell, James R. Hein
Sphalerite oxidation in seawater with covellite: Implications for seafloor massive sulfide deposits and mine waste
Metal sulfide minerals exist in several marine environments and are in thermodynamic disequilibrium with oxygenated seawater from the time of their formation. Oxidation is both ubiquitous and heterogeneous, as observational and experimental evidence demonstrates that sulfide minerals may oxidize completely on decadal timescales (hydrothermal plumes) or incompletely in billions of years...
Authors
Amy Gartman, Samantha P. Whisman, James R. Hein
The effects of phosphatization on the mineral associations and speciation of Pb in ferromanganese crusts
The older layers of thick ferromanganese (FeMn) crusts from the central Pacific Ocean have undergone diagenetic phosphatization, during which carbonate fluorapatite (CFA) filled fractures and pore space and replaced carbonates. The effects of phosphatization on individual trace metal concentrations, speciation, and phase associations in FeMn crusts remain poorly understood yet may be...
Authors
Kira Mizell, James R. Hein, Andrea Koschinsky, Sarah M. Hayes
Changes in sediment source areas to the Amerasia Basin, Arctic Ocean, over the past 5.5 million years based on radiogenic isotopes (Sr, Nd, Pb) of detritus from ferromanganese crusts
Ferromanganese (FeMn) crusts provide a useful paleoenvironmental archive for studying the poorly understood climatic, oceanographic, and geologic evolution of the Arctic Ocean. This study is based on the identification and temporal reconstruction of sources and inferred transport pathways of terrigenous material in FeMn crusts collected from several sites across the Amerasia Basin...
Authors
Natalia Konstantinova, James R. Hein, Kira Mizell, Georgy Cherkashov, Brian Dreyer, Deborah Hutchinson
Genesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825...
Authors
Mariana Benites, James R. Hein, Kira Mizell, Terrence Blackburn, Luigi Jovane