zation
Geologist Emeritus with the USGS Pacific Coastal and Marine Science Center
Science and Products
Global Marine Mineral Resources
Researching seafloor mineral resources that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions.
Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater
This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals.
These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloor
Sorbed-water (H2O-) corrected chemistry for ferromanganese crust samples from the western equatorial Pacific Ocean
Ferromanganese crust samples were collected via dredge during four oceanographic research cruises to the western equatorial Pacific Ocean. The location (latitude, longitude, depth) and concentrations of 27 major and trace elements in the most recent growth layers of ferromanganese crusts from 57 dredge sites are presented here, as well as select seawater chemistry at each location. These data were
Bathymetry of the Republic of the Marshall Islands and vicinity
The bathymetric map of the Republic of the Marshall Islands and vicinity is bounded by a window of latitude 3 to 17 degrees North, longitude 153 to 175 degrees East. The map was compiled from surveys conducted by the USGS, Korean Ocean Research and Development Institute, and published gridded data. In addition to national jurisdictions, island and atoll coastlines are indicated on the map.
Filter Total Items: 167
Crystal chemistry of thallium in marine ferromanganese deposits
Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO2), the principle manganate mineral in oxic and suboxic environments, and (2) being able to determine the so
Authors
Alain Manceau, Alexandre Simionovici, Nathaniel Findling, Pieter Glatzel, Blanka Detlefs, Anna V Wegorzewski, Kira Mizell, James R. Hein, Andrea Koschinsky
Deep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals
The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest.Polymetallic nodules are essentially two-dimensional min
Authors
James R. Hein, Kira Mizell
Estimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules
Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for ferromangan
Authors
Kira Mizell, James R. Hein, Manda Viola Au, Amy Gartman
Geochemical insights into formation of enigmatic ironstones from Rio Grande rise, South Atlantic Ocean
Rio Grande Rise (RGR) is an intraplate oceanic elevation in the South Atlantic Ocean that formed at a hotspot on the Mid-Atlantic Ridge during the Cretaceous. In spreading center and hotspot environments, ironstones form mainly by biomineralization of reduced Fe from hydrothermal fluids or oxidation of sulfide deposits. However, RGR has been considered aseismic and volcanically inactive for the pa
Authors
Mariana Benites, James R. Hein, Kira Mizell, Kenneth A. Farley, Jonathon Treffkorn, Luigi Jovane
Miocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean
Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87Sr/86Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese crusts, and
Authors
Mariana Benites, James R. Hein, Kira Mizell, Luigi Jovane
Changes in seabed mining
Chapter 23 of the First World Ocean Assessment (WOA I) focused on marine mining, and particularly on established extractive industries, which are predominantly confined to near-shore areas, where shallow-water, near-shore aggregate and placer deposits, and somewhat deeper water phosphate deposits are found (United Nations, 2017a). At the time of publication, there were no commercially developed de
Authors
James R. Hein, Pedro Madureira, Maria João Bebianno, Ana Colaço, Luis M. Pinheiro, Richard Roth, Pradeep K. Singh, Anastasia Strati, Joshua T. Tuhumwire
Ocean floor manganese deposits
Much of the dissolved Mn delivered to the oceans is slowly oxidized and precipitated alongside varying amounts of Fe into Mn and ferromanganese (FeMn) mineral deposits that occur extensively in the deep ocean wherever sediment accumulation is low and substrate is available. FeMn crusts grow as pavements on rock outcrops throughout the global ocean whereas nodules form as individual FeMn-encrusted
Authors
Kira Mizell, James R. Hein
Sphalerite oxidation in seawater with covellite: Implications for seafloor massive sulfide deposits and mine waste
Metal sulfide minerals exist in several marine environments and are in thermodynamic disequilibrium with oxygenated seawater from the time of their formation. Oxidation is both ubiquitous and heterogeneous, as observational and experimental evidence demonstrates that sulfide minerals may oxidize completely on decadal timescales (hydrothermal plumes) or incompletely in billions of years (mineral de
Authors
Amy Gartman, Samantha P. Whisman, James R. Hein
The effects of phosphatization on the mineral associations and speciation of Pb in ferromanganese crusts
The older layers of thick ferromanganese (FeMn) crusts from the central Pacific Ocean have undergone diagenetic phosphatization, during which carbonate fluorapatite (CFA) filled fractures and pore space and replaced carbonates. The effects of phosphatization on individual trace metal concentrations, speciation, and phase associations in FeMn crusts remain poorly understood yet may be important to
Authors
Kira Mizell, James R. Hein, Andrea Koschinsky, Sarah M. Hayes
Changes in sediment source areas to the Amerasia Basin, Arctic Ocean, over the past 5.5 million years based on radiogenic isotopes (Sr, Nd, Pb) of detritus from ferromanganese crusts
Ferromanganese (FeMn) crusts provide a useful paleoenvironmental archive for studying the poorly understood climatic, oceanographic, and geologic evolution of the Arctic Ocean. This study is based on the identification and temporal reconstruction of sources and inferred transport pathways of terrigenous material in FeMn crusts collected from several sites across the Amerasia Basin. Samples from th
Authors
Natalia Konstantinova, James R. Hein, Kira Mizell, Georgy Cherkashov, Brian Dreyer, Deborah Hutchinson
Genesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825 m) Fe–Mn c
Authors
Mariana Benites, James R. Hein, Kira Mizell, Terrence Blackburn, Luigi Jovane
Geographic and oceanographic influences on ferromanganese crust composition along a Pacific Ocean meridional transect, 14N to 14S
The major controls on the variability of ferromanganese (FeMn) crust composition have been generally described over the past 40 years; however, most compilation studies lack quantitative statistics and are limited to a small region of several seamounts or compare FeMn crusts from disparate areas of the global oceans. This study provides the first detailed research to address the geographic and ocea
Authors
Kira Mizell, James R. Hein, Phoebe J. Lam, Anthony A.P. Koppers, Hubert Staudigel
Science and Products
- Science
Global Marine Mineral Resources
Researching seafloor mineral resources that occur within the U.S. Exclusive Economic Zone and areas beyond national jurisdictions. - Data
Measurements of zinc, oxygen, and pH, from sphalerite and ZnS oxidation in seawater
This data release presents the concentration of zinc, oxygen, pH, temperature, and the time point at which measurements were taken for experimental oxidation work regarding zinc and copper sulfide minerals. These data accompany the following publication: Gartman, A., Whisman, S.P., and Hein, J.R., 2020, Interactive oxidation of sphalerite and covellite in seawater: implications for seafloorSorbed-water (H2O-) corrected chemistry for ferromanganese crust samples from the western equatorial Pacific Ocean
Ferromanganese crust samples were collected via dredge during four oceanographic research cruises to the western equatorial Pacific Ocean. The location (latitude, longitude, depth) and concentrations of 27 major and trace elements in the most recent growth layers of ferromanganese crusts from 57 dredge sites are presented here, as well as select seawater chemistry at each location. These data were - Maps
Bathymetry of the Republic of the Marshall Islands and vicinity
The bathymetric map of the Republic of the Marshall Islands and vicinity is bounded by a window of latitude 3 to 17 degrees North, longitude 153 to 175 degrees East. The map was compiled from surveys conducted by the USGS, Korean Ocean Research and Development Institute, and published gridded data. In addition to national jurisdictions, island and atoll coastlines are indicated on the map.
- Multimedia
- Publications
Filter Total Items: 167
Crystal chemistry of thallium in marine ferromanganese deposits
Our understanding of the up to 7 orders of magnitude partitioning of thallium (Tl) between seawater and ferromanganese (FeMn) deposits rests upon two foundations: (1) being able to quantify the Tl(I)/Tl(III) ratio that reflects the extent of the oxidative scavenging of Tl by vernadite (δ-MnO2), the principle manganate mineral in oxic and suboxic environments, and (2) being able to determine the soAuthorsAlain Manceau, Alexandre Simionovici, Nathaniel Findling, Pieter Glatzel, Blanka Detlefs, Anna V Wegorzewski, Kira Mizell, James R. Hein, Andrea KoschinskyDeep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals
The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest.Polymetallic nodules are essentially two-dimensional minAuthorsJames R. Hein, Kira MizellEstimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules
Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for ferromanganAuthorsKira Mizell, James R. Hein, Manda Viola Au, Amy GartmanGeochemical insights into formation of enigmatic ironstones from Rio Grande rise, South Atlantic Ocean
Rio Grande Rise (RGR) is an intraplate oceanic elevation in the South Atlantic Ocean that formed at a hotspot on the Mid-Atlantic Ridge during the Cretaceous. In spreading center and hotspot environments, ironstones form mainly by biomineralization of reduced Fe from hydrothermal fluids or oxidation of sulfide deposits. However, RGR has been considered aseismic and volcanically inactive for the paAuthorsMariana Benites, James R. Hein, Kira Mizell, Kenneth A. Farley, Jonathon Treffkorn, Luigi JovaneMiocene phosphatization of rocks from the summit of Rio Grande Rise, Southwest Atlantic Ocean
Marine phosphorites are an important part of the oceanic phosphorus cycle and are related to the effects of long-term global climate changes. We use petrography, mineralogy, rare earth elements contents, and 87Sr/86Sr-determined carbonate fluorapatite (CFA) and calcite ages to investigate the paragenesis and history of phosphatization of carbonate sediments, limestones, ferromanganese crusts, andAuthorsMariana Benites, James R. Hein, Kira Mizell, Luigi JovaneChanges in seabed mining
Chapter 23 of the First World Ocean Assessment (WOA I) focused on marine mining, and particularly on established extractive industries, which are predominantly confined to near-shore areas, where shallow-water, near-shore aggregate and placer deposits, and somewhat deeper water phosphate deposits are found (United Nations, 2017a). At the time of publication, there were no commercially developed deAuthorsJames R. Hein, Pedro Madureira, Maria João Bebianno, Ana Colaço, Luis M. Pinheiro, Richard Roth, Pradeep K. Singh, Anastasia Strati, Joshua T. TuhumwireOcean floor manganese deposits
Much of the dissolved Mn delivered to the oceans is slowly oxidized and precipitated alongside varying amounts of Fe into Mn and ferromanganese (FeMn) mineral deposits that occur extensively in the deep ocean wherever sediment accumulation is low and substrate is available. FeMn crusts grow as pavements on rock outcrops throughout the global ocean whereas nodules form as individual FeMn-encrustedAuthorsKira Mizell, James R. HeinSphalerite oxidation in seawater with covellite: Implications for seafloor massive sulfide deposits and mine waste
Metal sulfide minerals exist in several marine environments and are in thermodynamic disequilibrium with oxygenated seawater from the time of their formation. Oxidation is both ubiquitous and heterogeneous, as observational and experimental evidence demonstrates that sulfide minerals may oxidize completely on decadal timescales (hydrothermal plumes) or incompletely in billions of years (mineral deAuthorsAmy Gartman, Samantha P. Whisman, James R. HeinThe effects of phosphatization on the mineral associations and speciation of Pb in ferromanganese crusts
The older layers of thick ferromanganese (FeMn) crusts from the central Pacific Ocean have undergone diagenetic phosphatization, during which carbonate fluorapatite (CFA) filled fractures and pore space and replaced carbonates. The effects of phosphatization on individual trace metal concentrations, speciation, and phase associations in FeMn crusts remain poorly understood yet may be important toAuthorsKira Mizell, James R. Hein, Andrea Koschinsky, Sarah M. HayesChanges in sediment source areas to the Amerasia Basin, Arctic Ocean, over the past 5.5 million years based on radiogenic isotopes (Sr, Nd, Pb) of detritus from ferromanganese crusts
Ferromanganese (FeMn) crusts provide a useful paleoenvironmental archive for studying the poorly understood climatic, oceanographic, and geologic evolution of the Arctic Ocean. This study is based on the identification and temporal reconstruction of sources and inferred transport pathways of terrigenous material in FeMn crusts collected from several sites across the Amerasia Basin. Samples from thAuthorsNatalia Konstantinova, James R. Hein, Kira Mizell, Georgy Cherkashov, Brian Dreyer, Deborah HutchinsonGenesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean
The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825 m) Fe–Mn cAuthorsMariana Benites, James R. Hein, Kira Mizell, Terrence Blackburn, Luigi JovaneGeographic and oceanographic influences on ferromanganese crust composition along a Pacific Ocean meridional transect, 14N to 14S
The major controls on the variability of ferromanganese (FeMn) crust composition have been generally described over the past 40 years; however, most compilation studies lack quantitative statistics and are limited to a small region of several seamounts or compare FeMn crusts from disparate areas of the global oceans. This study provides the first detailed research to address the geographic and oceaAuthorsKira Mizell, James R. Hein, Phoebe J. Lam, Anthony A.P. Koppers, Hubert Staudigel - News