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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

Using borehole geophysics and cross-borehole flow testing to define hydraulic connections between fracture zones in bedrock aquifers Using borehole geophysics and cross-borehole flow testing to define hydraulic connections between fracture zones in bedrock aquifers

Nearly a decade of intensive geophysical logging at fractured rock hydrology research sites indicates that geophysical logs can be used to identify and characterize fractures intersecting boreholes. However, borehole-to-borehole flow tests indicate that only a few of the apparently open fractures found to intersect boreholes conduct flow under test conditions. This paper presents a...
Authors
Frederick L. Paillet

Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate

EXAFS spectra were collected on both the As and Fe K-edges from samples of two-line ferrihydrite with adsorbed (ADS) and coprecipitated (CPT) arsenate prepared over a range of conditions and arsenate surface coverages. Spectra also were collected for arsenate adsorbed on the surfaces of three FeOOH crystalline polymorphs, α (goethite), β (akaganeite), and γ (lepidocrocite), and as a free...
Authors
G.A. Waychunas, B.A. Rea, C. C. Fuller, J.A. Davis

Automated solid-phase extraction of herbicides from water for gas chromatographic-mass spectrometric analysis Automated solid-phase extraction of herbicides from water for gas chromatographic-mass spectrometric analysis

An automated solid-phase extraction (SPE) method was developed for the pre-concentration of chloroacetanilide and triazine herbicides, and two triazine metabolites from 100-ml water samples. Breakthrough experiments for the C18 SPE cartridge show that the two triazine metabolites are not fully retained and that increasing flow-rate decreases their retention. Standard curve r2 values of 0...
Authors
M. T. Meyer, M. S. Mills, E.M. Thurman

Application of mixed-mode, solid-phase extraction in environmental and clinical chemistry. Combining hydrogen-bonding, cation-exchange and Van der Waals interactions Application of mixed-mode, solid-phase extraction in environmental and clinical chemistry. Combining hydrogen-bonding, cation-exchange and Van der Waals interactions

Silica- and styrene-divinylbenzene-based mixed-mode resins that contain C8, C18 and sulphonated cation-exchange groups were compared for their efficiency in isolation of neutral triazine compounds from water and of the basic drug, benzoylecgonine, from urine. The triazine compounds were isolated by a combination of Van der Waals and hydrogen-bonding interactions, and benzoylecgonine was...
Authors
M. S. Mills, E.M. Thurman, M.J. Pedersen

Manganese minerals and associated fine particulates in the streambed of Pinal Creek, Arizona, U.S.A.: a mining-related acid drainage problem Manganese minerals and associated fine particulates in the streambed of Pinal Creek, Arizona, U.S.A.: a mining-related acid drainage problem

The Pinal creek drainage basin in Arizona is a good example of the principal non-coal source of mining-related acid drainage in the U.S.A., namely copper mining. Infiltration of drainage waters from mining and ore refining has created an acid groundwater plume that has reacted with calcite during passage through the alluvium, thereby becoming less acid. Where O2 is present and the water...
Authors
Carol J. Lind, J.D. Hem

Crude oil in a shallow sand and gravel aquifer-II. Organic geochemistry Crude oil in a shallow sand and gravel aquifer-II. Organic geochemistry

Crude oil spilled from a pipeline break in a remote area of north-central Minnesota has contaminated a shallow glacial outwash aquifer. Part of the oil was sprayed over a large area to the west of the pipeline and part of it accumulated in an oil body that floats at the water table to the east of the point of discharge. Total dissolved organic carbon (TDOC) concentrations in shallow...
Authors
R.P. Eganhouse, M.J. Baedecker, I.M. Cozzarelli, G. R. Aiken, K. A. Thorn, T.F. Dorsey

Organic carbon sources and sinks in San Francisco Bay: variability induced by river flow Organic carbon sources and sinks in San Francisco Bay: variability induced by river flow

Sources and sinks of organic carbon for San Francisco Bay (California, USA) were estimated for 1980. Sources for the southern reach were dominated by phytoplankton and benthic microalgal production. River loading of organic matter was an additional important factor in the northern reach. Tidal marsh export and point sources played a secondary role. Autochthonous production in San...
Authors
Alan D. Jassby, T.M. Powell, James E. Cloern

Hydrogeologic, water-quality, and land-use data for the reconnaissance of herbicides and nitrate in near-surface aquifers of the Midcontinental United States, 1991 Hydrogeologic, water-quality, and land-use data for the reconnaissance of herbicides and nitrate in near-surface aquifers of the Midcontinental United States, 1991

Water samples were collected during the spring and summer of 1991 from 303 wells penetrating near-surface unconsolidated and bedrock aquifers of the midcontinental United States. Samples were analyzed for 11 herbicides, 2 dealkylated atrazine metabolites, and 4 nutrients. Specific conductance, pH, and dissolved-oxygen concentrations of the ground water were measured onsite. Ancillary...
Authors
D.W. Kolpin, M. R. Burkart, E.M. Thurman

Nonpoint source contamination of the Mississippi river and its tributaries by herbicides Nonpoint source contamination of the Mississippi river and its tributaries by herbicides

A study of the Mississippi River and its tributaries during July-August 1991, October-November 1991, and April-May 1992 has indicated that the entire navigable reach of the river is contaminated with a complex mixture of agrochemicals and their transformation products derived from nonpoint sources. Twenty-three compounds were identified, including triazine, chloroacetanilide...
Authors
W. E. Pereira, F. D. Hostettler
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