Brian Bergamaschi (Former Employee)

Shifts in land use, population, and climate have altered hydrologic systems in the United States in ways that affect water quality and ecosystem function. Water diversions, detention in reservoirs, increased channelization, and changes in rainfall and snowmelt are major causes, but there are also more subtle causes such as changes in soil temperature, atmospheric deposition, and shifting

Willow Slough, a seasonally irrigated agricultural watershed in the Sacramento River valley, California, was sampled synoptically in order to investigate the extent to which dissolved organic carbon (DOC) concentrations and compositions from throughout the catchment are represented at the mouth. DOC concentrations ranged from 1.8 to 13.9 mg L−1, with the lowest values in headwater 1st...

The influence of groundwater on surface-water quality in the San Joaquin River, California, was examined for a 59-mile reach from the confluence with Salt Slough to Vernalis. The primary objective of this study was to quantify the rate of groundwater discharged to the lower San Joaquin River and the contribution of nitrate and dissolved organic carbon concentrations to the river...

We investigated the role of land use/land cover and agriculture practices on stream dissolved organic carbon (DOC) dynamics in the Willow Slough watershed (WSW) from 2006 to 2008. The 415 km2watershed in the northern Central Valley, California is covered by 31% of native vegetation and the remaining 69% of agricultural fields (primarily alfalfa, tomatoes, and rice). Stream discharge and...

The recent commercial availability of in situ optical sensors, together with new techniques for data collection and analysis, provides the opportunity to monitor a wide range of water-quality constituents on time scales in which environmental conditions actually change. Of particular interest is the application of ultraviolet (UV) photometers for in situ determination of nitrate...

This study characterized the amount and quality of organic matter in the Clackamas River, Oregon, to gain an understanding of sources that contribute to the formation of chlorinated and brominated disinfection by-products (DBPs), focusing on regulated DBPs in treated drinking water from two direct-filtration treatment plants that together serve approximately 100,000 customers. The...

We used high-resolution in situ measurements of turbidity and fluorescent dissolved organic matter (FDOM) to quantitatively estimate the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, a tidal wetland. Turbidity and FDOM—representative of particle-associated and filter-passing Hg, respectively—together predicted 94 % of the...

This assessment was conducted to fulfill the requirements of section 712 of the Energy Independence and Security Act (EISA) of 2007 and to improve understanding of carbon and greenhouse gas (GHG) fluxes in ecosystems of the Western United States. The assessment examined carbon storage, carbon fluxes, and other GHG fluxes (methane and nitrous oxide) in all major terrestrial ecosystems...

Dissolved organic matter (DOM) significantly decreased accumulation of methylmercury (MeHg) by the diatom Cyclotella meneghiniana in laboratory experiments. Live diatom cells accumulated two to four times more MeHg than dead cells, indicating that accumulation may be partially an energy-requiring process. Methylmercury enrichment in diatoms relative to ambient water was measured by a...

Field-deployable sensors designed to continuously measure the fluorescence of colored dissolved organic matter (FDOM) in situ are of growing interest. However, the ability to make FDOM measurements that are comparable across sites and over time requires a clear understanding of how instrument characteristics and environmental conditions affect the measurements. In particular, the effects...

Advanced in situ optical water-quality sensors and new techniques for data analysis hold enormous promise for furthering scientific understanding of aquatic systems. These sensors measure important biogeochemical parameters for long deployments, enabling the capture of data at time scales over which they vary most meaningfully. The high-frequency, real-time water-quality data they...

The flux of dissolved organic carbon (DOC) from mangrove swamps accounts for 10% of the global terrestrial flux of DOC to coastal oceans. Recent findings of high concentrations of mercury (Hg) and methylmercury (MeHg) in mangroves, in conjunction with the common co-occurrence of DOC and Hg species, have raised concerns that mercury fluxes may also be large. We used a novel approach to...