Groundwater is an important source of drinking water in the United States. In order to assess the status and long-term sustainability of this important resource, I use environmental tracers, geochemical modeling, and statistical methods to understand the age structure, geochemical processes, and trends affecting water-quality in aquifers.
Science and Products
Groundwater Age
The age of groundwater is key in predicting which contaminants it might contain. There are many tracers and techniques that allow us to estimate the age—or mix of ages—of the groundwater we depend on as a drinking water supply.
Data for Distribution of Groundwater Age in Aquifers Used for Public Supply in the Continental United States, 2004 - 2017 (Version 1.1: June 2022)
This data release documents seven tables that contain environmental tracer data and lumped parameter model (LPM) results that are used for assessing the distribution of groundwater age in 21 Principal Aquifers of the continental United States. Groundwater samples were collected from 1,279 sites and analyzed for environmental tracers: tritium, tritiogenic helium-3, sulfur hexafluoride, carbon-14, a
Data for assessing the penetration depth post-1950s water in the Central Valley aquifer system, California (July 2022)
This dataset provides groundwater ages estimates that were used in an assessment of the penetration depth of modern groundwater in the Central Valley aquifer system (CVAL). Groundwater ages were estimated by calibration of environmental tracers (tritium, tritiogenic helium-3, chlorofluorocarbons, sulfur hexafluoride, carbon-14 and radiogenic helium-4) to lumped parameter models (LPMs) for samples
Data for Time Scales of Arsenic Variability and the Role of High-Frequency Monitoring at Three Water-Supply Wells in New Hampshire, USA
This data release consists of data (in four tables) for assessing the time scales of arsenic variability in three production wells in New Hampshire; tables that describe the data fields in the data tables are also included in the data release. High-frequency (every 5 to 15 minutes) and bi-monthly water-quality monitoring of a bedrock-aquifer domestic well (425651070573701), a bedrock-aquifer publi
Data for Assessing the Lead Solubility Potential of Untreated Groundwater of the United States
Groundwater chemistry data used for assessing the lead (Pb) solubility potential of untreated groundwater of the United States were compiled from the USGS National Water Information System (NWIS) database for groundwater sites sampled between January 1, 2000 and January 1, 2016. Two datasets were compiled: one dataset having 13,324 groundwater sites was used to assess Pb occurrence in untreated gr
Geochemical Correction of Carbon-14 in Dissolved Inorganic Carbon used for Groundwater Age Dating in the Glacial Aquifer System, Conterminous United States
Data provided here describe geochemical correction of carbon-14 in dissolved inorganic carbon (DIC) for groundwater age dating. Datasets include major ion chemistry of groundwater samples, model parameter inputs, and final corrected carbon-14 in DIC. Geochemical correction was completed in two phases: determination of reactive phase mole transfers through an inverse geochemical model (PHREEQC; Par
Data for Radium Mobility and the Age of Groundwater in Public-drinking-water Supplies from the Cambrian-Ordovician Aquifer System, North-Central USA
High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers ( 3H, 3Hetrit, SF6 , 14C and 4Herad) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (1 Myr) in the most downgradien
Well characteristics, water quality and age-date tracer data for wells along two regional flow paths in the Memphis aquifer, southwest Tennessee
In 2013, water-quality and age-date tracer samples were collected at wells located along two flow paths in the Memphis aquifer, southwest Tennessee, as part of the National Water Quality Assessment (NAWQA) Project of the National Water-Quality Program to better understand the vulnerability of the aquifer to contamination.. Each flow path began in the aquifer outcrop area (shallow well depths) and
Filter Total Items: 53
Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California
The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA. Tracers
Quality of groundwater used for public supply in the continental United States: A comprehensive assessment
The presence of contaminants in a source water can constrain its suitability for drinking. The quality of groundwater used for public supply was assessed in 25 principal aquifers (PAs) that account for 84% of groundwater pumped for public supply in the U.S. (89.6 million people on a proportional basis). Each PA was sampled across its lateral extent using an equal-area grid, typically with 60 wells
Over a third of groundwater in USA public-supply aquifers is Anthropocene-age and susceptible to surface contamination
The distribution of groundwater age is useful for evaluating the susceptibility and sustainability of groundwater resources. Here, we compute the aquifer-scale cumulative distribution function to characterize the age distribution for 21 Principal Aquifers that account for ~80% of public-supply pumping in the United States. The aquifer-scale cumulative distribution function for each Principal Aquif
Effects of imported recharge on fluoride trends in groundwater used for public supply in California
Fluoride is a naturally occurring element in groundwater that supports bone and dental health at low concentrations but can cause health problems at elevated concentrations in drinking water. This study investigates spatial and temporal trends for fluoride concentrations in untreated groundwater from over 20,000 public supply wells in California. The presence of a significant temporal trend in flu
Critical aquifer overdraft accelerates degradation of groundwater quality in California’s Central Valley during drought
Drought-induced pumpage has precipitated dramatic groundwater-level declines in California’s Central Valley over the past 30 years, but the impacts of aquifer overdraft on water quality are poorly understood. This study coupled over 160,000 measurements of nitrate from ∼6,000 public-supply wells with a 30-year reconstruction of groundwater levels throughout the Central Valley to evaluate dynamic r
A multi-tracer and well-bore flow profile approach to determine occurrence, movement, and sources of perchlorate in groundwater
The purpose of this study is to determine the occurrence, movement and sources of perchlorate in groundwater using a comprehensive set of environmental tracers coupled with discreet borehole data. Potential sources of perchlorate to groundwater at the study site have been attributed to waste disposal and industrial activities as well as to past agricultural operations. Perchlorate concentrations i
Groundwater residence time estimates obscured by anthropogenic carbonate
Groundwater is an important source of drinking and irrigation water. Dating groundwater informs its vulnerability to contamination and aids in calibrating flow models. Here, we report measurements of multiple age tracers (14C, 3H, 39Ar, and 85Kr) and parameters relevant to dissolved inorganic carbon (DIC) from 17 wells in California’s San Joaquin Valley (SJV), an agricultural region that is heavil
Groundwater development leads to decreasing arsenic concentrations in the San Joaquin Valley, California
In the San Joaquin Valley (SJV), California, about 10% of drinking water wells since 2010 had arsenic concentrations above the US maximum contaminant level of 10 μg/L. High concentrations of arsenic are often associated with high pH (greater than 7.8) or reduced geochemical conditions. Although most wells have low arsenic (
DGMETA (version 1)—Dissolved gas modeling and environmental tracer analysis computer program
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis) is a Microsoft Excel-based computer program that is used for modeling air-water equilibrium conditions from measurements of dissolved gases and for computing concentrations of environmental tracers that rely on air-water equilibrium model results. DGMETA can solve for the temperature, salinity, excess air, fractionation of gases, or
Geochemistry and age of groundwater in the Williston Basin, USA: Assessing potential effects of shale-oil production on groundwater quality
Thirty water wells were sampled in 2018 to understand the geochemistry and age of groundwater in the Williston Basin and assess potential effects of shale-oil production from the Three Forks-Bakken petroleum system (TBPS) on groundwater quality. Two geochemical groups are identified using hierarchical cluster analysis. Group 1 represents the younger (median 4He = 21.49 × 10−8 cm3 STP/g), less chem
Identifying areas of degrading and improving groundwater-quality conditions in the State of California, USA, 1974-2014
Areas of improving and degrading groundwater-quality conditions in the State of California were assessed using spatial weighting of a new metric for scoring wells based on constituent concentrations and the direction and magnitude of a trend slope (Sen). Individual well scores were aggregated across 2135 equal-area grid cells covering the entire groundwater resource used for public supply in the s
Evaluation of soil zone processes and a novel radiocarbon correction approach for groundwater with mixed sources
Estimates of groundwater age based on 14C is often limited by the uncertainty in geochemical processes that alter the 14C concentration measured in water and the composition (δ13C and 14C) of carbon sources needed to appropriately parametrize 14C adjustment models. Estimated ages for samples that contain a mixture of young and old groundwater will be particularly sensitive to model parametrization
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis)
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis) is a Microsoft Excel-based computer program that is used for modeling air-water equilibrium conditions from measurements of dissolved gases and for computing concentrations of environmental tracers that rely on air-water equilibrium model results.
Groundwater Age Mixtures & Contaminant Trends Tool (GAMACTT)
Use this Groundwater Age Mixtures and Contaminant Trends Tool (GAMACTT) to explore the effects of basic aquifer properties and well configurations on groundwater age mixtures in groundwater discharge and on contaminant trends from varying nonpoint-source contaminant input scenarios.
TracerLPM
An Excel® Workbook for Interpreting Groundwater Age Distributions from Environmental Tracer Data
Science and Products
- Science
Groundwater Age
The age of groundwater is key in predicting which contaminants it might contain. There are many tracers and techniques that allow us to estimate the age—or mix of ages—of the groundwater we depend on as a drinking water supply. - Data
Data for Distribution of Groundwater Age in Aquifers Used for Public Supply in the Continental United States, 2004 - 2017 (Version 1.1: June 2022)
This data release documents seven tables that contain environmental tracer data and lumped parameter model (LPM) results that are used for assessing the distribution of groundwater age in 21 Principal Aquifers of the continental United States. Groundwater samples were collected from 1,279 sites and analyzed for environmental tracers: tritium, tritiogenic helium-3, sulfur hexafluoride, carbon-14, aData for assessing the penetration depth post-1950s water in the Central Valley aquifer system, California (July 2022)
This dataset provides groundwater ages estimates that were used in an assessment of the penetration depth of modern groundwater in the Central Valley aquifer system (CVAL). Groundwater ages were estimated by calibration of environmental tracers (tritium, tritiogenic helium-3, chlorofluorocarbons, sulfur hexafluoride, carbon-14 and radiogenic helium-4) to lumped parameter models (LPMs) for samplesData for Time Scales of Arsenic Variability and the Role of High-Frequency Monitoring at Three Water-Supply Wells in New Hampshire, USA
This data release consists of data (in four tables) for assessing the time scales of arsenic variability in three production wells in New Hampshire; tables that describe the data fields in the data tables are also included in the data release. High-frequency (every 5 to 15 minutes) and bi-monthly water-quality monitoring of a bedrock-aquifer domestic well (425651070573701), a bedrock-aquifer publiData for Assessing the Lead Solubility Potential of Untreated Groundwater of the United States
Groundwater chemistry data used for assessing the lead (Pb) solubility potential of untreated groundwater of the United States were compiled from the USGS National Water Information System (NWIS) database for groundwater sites sampled between January 1, 2000 and January 1, 2016. Two datasets were compiled: one dataset having 13,324 groundwater sites was used to assess Pb occurrence in untreated grGeochemical Correction of Carbon-14 in Dissolved Inorganic Carbon used for Groundwater Age Dating in the Glacial Aquifer System, Conterminous United States
Data provided here describe geochemical correction of carbon-14 in dissolved inorganic carbon (DIC) for groundwater age dating. Datasets include major ion chemistry of groundwater samples, model parameter inputs, and final corrected carbon-14 in DIC. Geochemical correction was completed in two phases: determination of reactive phase mole transfers through an inverse geochemical model (PHREEQC; ParData for Radium Mobility and the Age of Groundwater in Public-drinking-water Supplies from the Cambrian-Ordovician Aquifer System, North-Central USA
High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers ( 3H, 3Hetrit, SF6 , 14C and 4Herad) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (1 Myr) in the most downgradienWell characteristics, water quality and age-date tracer data for wells along two regional flow paths in the Memphis aquifer, southwest Tennessee
In 2013, water-quality and age-date tracer samples were collected at wells located along two flow paths in the Memphis aquifer, southwest Tennessee, as part of the National Water Quality Assessment (NAWQA) Project of the National Water-Quality Program to better understand the vulnerability of the aquifer to contamination.. Each flow path began in the aquifer outcrop area (shallow well depths) and - Multimedia
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Filter Total Items: 53
Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California
The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA. TracersQuality of groundwater used for public supply in the continental United States: A comprehensive assessment
The presence of contaminants in a source water can constrain its suitability for drinking. The quality of groundwater used for public supply was assessed in 25 principal aquifers (PAs) that account for 84% of groundwater pumped for public supply in the U.S. (89.6 million people on a proportional basis). Each PA was sampled across its lateral extent using an equal-area grid, typically with 60 wells
Over a third of groundwater in USA public-supply aquifers is Anthropocene-age and susceptible to surface contamination
The distribution of groundwater age is useful for evaluating the susceptibility and sustainability of groundwater resources. Here, we compute the aquifer-scale cumulative distribution function to characterize the age distribution for 21 Principal Aquifers that account for ~80% of public-supply pumping in the United States. The aquifer-scale cumulative distribution function for each Principal AquifEffects of imported recharge on fluoride trends in groundwater used for public supply in California
Fluoride is a naturally occurring element in groundwater that supports bone and dental health at low concentrations but can cause health problems at elevated concentrations in drinking water. This study investigates spatial and temporal trends for fluoride concentrations in untreated groundwater from over 20,000 public supply wells in California. The presence of a significant temporal trend in fluCritical aquifer overdraft accelerates degradation of groundwater quality in California’s Central Valley during drought
Drought-induced pumpage has precipitated dramatic groundwater-level declines in California’s Central Valley over the past 30 years, but the impacts of aquifer overdraft on water quality are poorly understood. This study coupled over 160,000 measurements of nitrate from ∼6,000 public-supply wells with a 30-year reconstruction of groundwater levels throughout the Central Valley to evaluate dynamic rA multi-tracer and well-bore flow profile approach to determine occurrence, movement, and sources of perchlorate in groundwater
The purpose of this study is to determine the occurrence, movement and sources of perchlorate in groundwater using a comprehensive set of environmental tracers coupled with discreet borehole data. Potential sources of perchlorate to groundwater at the study site have been attributed to waste disposal and industrial activities as well as to past agricultural operations. Perchlorate concentrations iGroundwater residence time estimates obscured by anthropogenic carbonate
Groundwater is an important source of drinking and irrigation water. Dating groundwater informs its vulnerability to contamination and aids in calibrating flow models. Here, we report measurements of multiple age tracers (14C, 3H, 39Ar, and 85Kr) and parameters relevant to dissolved inorganic carbon (DIC) from 17 wells in California’s San Joaquin Valley (SJV), an agricultural region that is heavilGroundwater development leads to decreasing arsenic concentrations in the San Joaquin Valley, California
In the San Joaquin Valley (SJV), California, about 10% of drinking water wells since 2010 had arsenic concentrations above the US maximum contaminant level of 10 μg/L. High concentrations of arsenic are often associated with high pH (greater than 7.8) or reduced geochemical conditions. Although most wells have low arsenic (DGMETA (version 1)—Dissolved gas modeling and environmental tracer analysis computer program
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis) is a Microsoft Excel-based computer program that is used for modeling air-water equilibrium conditions from measurements of dissolved gases and for computing concentrations of environmental tracers that rely on air-water equilibrium model results. DGMETA can solve for the temperature, salinity, excess air, fractionation of gases, orGeochemistry and age of groundwater in the Williston Basin, USA: Assessing potential effects of shale-oil production on groundwater quality
Thirty water wells were sampled in 2018 to understand the geochemistry and age of groundwater in the Williston Basin and assess potential effects of shale-oil production from the Three Forks-Bakken petroleum system (TBPS) on groundwater quality. Two geochemical groups are identified using hierarchical cluster analysis. Group 1 represents the younger (median 4He = 21.49 × 10−8 cm3 STP/g), less chemIdentifying areas of degrading and improving groundwater-quality conditions in the State of California, USA, 1974-2014
Areas of improving and degrading groundwater-quality conditions in the State of California were assessed using spatial weighting of a new metric for scoring wells based on constituent concentrations and the direction and magnitude of a trend slope (Sen). Individual well scores were aggregated across 2135 equal-area grid cells covering the entire groundwater resource used for public supply in the sEvaluation of soil zone processes and a novel radiocarbon correction approach for groundwater with mixed sources
Estimates of groundwater age based on 14C is often limited by the uncertainty in geochemical processes that alter the 14C concentration measured in water and the composition (δ13C and 14C) of carbon sources needed to appropriately parametrize 14C adjustment models. Estimated ages for samples that contain a mixture of young and old groundwater will be particularly sensitive to model parametrization - Software
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis)
DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis) is a Microsoft Excel-based computer program that is used for modeling air-water equilibrium conditions from measurements of dissolved gases and for computing concentrations of environmental tracers that rely on air-water equilibrium model results.
Groundwater Age Mixtures & Contaminant Trends Tool (GAMACTT)
Use this Groundwater Age Mixtures and Contaminant Trends Tool (GAMACTT) to explore the effects of basic aquifer properties and well configurations on groundwater age mixtures in groundwater discharge and on contaminant trends from varying nonpoint-source contaminant input scenarios.
TracerLPM
An Excel® Workbook for Interpreting Groundwater Age Distributions from Environmental Tracer Data
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