Carl is a Research Soil Scientist with the USGS Colorado Water Science Center.
My research examines the geochemical interactions between water, rock, and soil in both natural and human-managed systems. I specialize in using isotopes and geochemical tracers to answer questions of both basic and applied research. Areas of focus in my recent work include:
- Using tritium to trace the ages of surface waters and water availability in the Upper Colorado River Basin as part of the USGS Next Generation Water Observing System (NGWOS)
- Salinity in surface waters and soils of the semiarid western U.S.
- Contaminants of concern like PFAS and selenium
- Water and soil effects from uranium mining
Professional Experience
2016-present Research Soil Scientist, USGS Colorado Water Science Center
2010-2016 Research Soil Scientist, USGS Crustal Geophysics and Geochemistry Science Center
2008-2010 Mendenhall Fellow, USGS Crustal Geophysics and Geochemistry Science Center
2006-2008 Post-doctoral researcher, University of California, Santa Barbara
Education and Certifications
Ph.D. University of Colorado, Boulder, Colorado, Ecology and Biogeochemistry
B.S. Virginia Tech, Blacksburg, Virginia, Biology
Science and Products
Technique Used to Distinguish Natural Background from Human-Caused Enrichment of Trace Elements in Soils
Soil Disturbance Can Increase Stream Salinity in Semiarid Watersheds
Stable hydrogen and oxygen isotopic compositions of precipitation samples from selected Colorado and Utah National Atmospheric Deposition Program (NADP) sites
Geochemical and fallout radionuclide data for sediment source fingerprinting studies of the Loutsenhizer Arroyo and Sunflower Drain watersheds in western Colorado
Geochemical data from batch experiments to test mobility of trace elements downgradient from breccia-pipe uranium deposits
GIS and Data Tables for Focus Areas for Potential Domestic Nonfuel Sources of Rare Earth Elements
Surface Materials Data from Breccia-Pipe Uranium Mine and Reference Sites, Arizona, USA
Laboratory data from testing parameters of EPA Method 3060A on Soils Contaminated with Chromium Ore Processing Residue 2013-2016
Assessment of salinity retention or mobilization by sediment-retention ponds near Delta, Colorado, 2019
Source contributions to suspended sediment and particulate selenium export from the Loutsenhizer Arroyo and Sunflower Drain watersheds in Colorado
Examination of dissolved uranium concentrations in regional shallow groundwater relative to Operable Unit 8 of the Denver Radium Superfund Site
Characterization of and temporal changes in groundwater quality of the Upper Black Squirrel Creek Basin, El Paso County, Colorado, 2018–20
Laboratory simulation of groundwater along uranium-mining-affected flow paths near the Grand Canyon, Arizona, USA
Water–rock interaction and the concentrations of major, trace, and rare earth elements in hydrocarbon-associated produced waters of the United States
Nontuberculous mycobacterial disease and molybdenum in Colorado watersheds
Salt flushing, salt storage, and controls on selenium: A 31-year mass-balance analysis of an irrigated, semiarid valley
Effects of John Martin Reservoir on water quality and quantity: Assessment by chemical, isotopic, and mass-balance methods
Comment on “Particle fluxes in groundwater change subsurface rock chemistry over geologic time”
Improved enrichment factor calculations through principal component analysis: Examples from soils near breccia pipe uranium mines, Arizona, USA
Dual-phase mass balance modeling of small mineral particle losses from sedimentary rock-derived soils
Science and Products
- Science
Technique Used to Distinguish Natural Background from Human-Caused Enrichment of Trace Elements in Soils
Human activities can enrich toxic trace elements like uranium and arsenic in the environment, but these elements also are from natural sources and occur at background levels. Scientists utilized a technique that identifies the background and the elemental fingerprint of human-caused enrichment and tested the new technique on data collected near uranium mines in Arizona.Soil Disturbance Can Increase Stream Salinity in Semiarid Watersheds
Soil disturbance from construction of roads, pipelines, and well pads on naturally salt-rich soils was determined to be a potential factor resulting in increased salinity in a southern Wyoming stream. Construction can expose salt-rich soils in the subsurface to increased contact with rain and snow, thus mobilizing salts through runoff or water percolating into soils. - Data
Stable hydrogen and oxygen isotopic compositions of precipitation samples from selected Colorado and Utah National Atmospheric Deposition Program (NADP) sites
The stable hydrogen (delta 2H) and oxygen (delta 18O) isotopic compositions of more than 4,300 weekly composite samples of precipitation from thirteen National Atmospheric Deposition Program (NADP) sites (CO02, CO08, CO09, CO10, CO21, CO89, CO91, CO92, CO93, CO96, CO97, CO98, and UT09) in Colorado and Utah were analyzed on archived samples obtained from NADP over various time periods between JanuaGeochemical and fallout radionuclide data for sediment source fingerprinting studies of the Loutsenhizer Arroyo and Sunflower Drain watersheds in western Colorado
This data release includes geochemical and fallout radionuclide data for suspended sediments and potential sediment source types for the Loutsenhizer Arroyo and Sunflower Drain watersheds in western Colorado. Suspended sediments were collected by passive samplers deployed in the stream channel of the watershed outlets during four study periods between August 2018 and August 2019. Potential sedimenGeochemical data from batch experiments to test mobility of trace elements downgradient from breccia-pipe uranium deposits
This data release includes solid and aqueous chemical data related to a set of sequential laboratory batch experiments conducted to test and simulate the mobility of trace elements as natural waters contact ore from breccia pipe uranium (BPU) deposits located in northern Arizona. The experiments made use of aquifer-related, sedimentary rocks collected specifically for this study and archival ore mGIS and Data Tables for Focus Areas for Potential Domestic Nonfuel Sources of Rare Earth Elements
In response to Executive Order 13817 of December 20, 2017, the U.S. Geological Survey (USGS) coordinated with the Bureau of Land Management (BLM) to identify 35 nonfuel minerals or mineral materials considered critical to the economic and national security of the United States (U.S.). Acquiring information on possible domestic sources of these critical minerals is the basis of the USGS Earth MappiSurface Materials Data from Breccia-Pipe Uranium Mine and Reference Sites, Arizona, USA
This data release includes elemental analysis of soil samples collected at breccia-pipe uranium mines, at one undeveloped breccia-pipe uranium deposit, and at a reference site in northern Arizona. Samples were collected near the Arizona 1, Canyon, Kanab North, and Pinenut uranium mines, over the EZ2 breccia-pipe uranium deposit, and at the Little Robinson Tank reference site. Samples were collectLaboratory data from testing parameters of EPA Method 3060A on Soils Contaminated with Chromium Ore Processing Residue 2013-2016
It has been shown that EPA Method 3060A does not adequately extract Cr(VI) from solids containing chromium ore processing residue (COPR). We systematically tested modifications to prescribed parameters of EPA 3060A towards improving extraction efficiency of Cr(VI) from NIST SRM 2701, a standard COPR-contaminated soil from New Jersey (NJ). The alkaline extraction fluid leached Al, Si, and B from th - Multimedia
- Publications
Filter Total Items: 23
Assessment of salinity retention or mobilization by sediment-retention ponds near Delta, Colorado, 2019
Salinity control efforts in the Colorado River Basin have focused on mobilization of salts from irrigated land, but nonirrigated rangelands are also a source of salinity. In particular, lands where soils have formed from the Late Cretaceous Mancos Shale under arid and semiarid climates contain considerable quantities of salt, mainly in the subsurface. Hundreds of thousands of contour furrows and cAuthorsRodney J. Richards, Carleton R. Bern, Victoria MorenoSource contributions to suspended sediment and particulate selenium export from the Loutsenhizer Arroyo and Sunflower Drain watersheds in Colorado
Selenium in aquatic ecosystems of the lower Gunnison River Basin in Colorado is affecting the recovery of populations of endangered, native fish species. Dietary exposure is the primary pathway for bioaccumulation of selenium in fish, and particulate selenium can be consumed directly by fish or by the invertebrates on which fish feed. Although selenium can be incorporated into particulate matter vAuthorsCarleton R. Bern, Cory A. Williams, Christopher G. SmithExamination of dissolved uranium concentrations in regional shallow groundwater relative to Operable Unit 8 of the Denver Radium Superfund Site
A radium industry existed between about 1914 and 1920 in Denver, Colorado, with operations located along the South Platte River. Sites associated with that industry were contaminated with radium and uranium processing residues and were incorporated into clean-up efforts as Operating Units (OUs) of the Denver Radium Superfund Site. Concentrations of uranium exceeding the U.S. Environmental ProtectiAuthorsCarleton R. BernCharacterization of and temporal changes in groundwater quality of the Upper Black Squirrel Creek Basin, El Paso County, Colorado, 2018–20
In 2018–20, the U.S. Geological Survey, in cooperation with Upper Black Squirrel Creek Ground Water Management District, sampled 48 wells for Phase III of a multiphase plan investigating groundwater quality in the alluvial aquifer of the Upper Black Squirrel Creek Basin (UBSB), El Paso County, Colorado. Results for samples collected from October to December each year were used to assess spatial anAuthorsZachary D. Kisfalusi, Nancy J. Bauch, Carleton R. BernLaboratory simulation of groundwater along uranium-mining-affected flow paths near the Grand Canyon, Arizona, USA
Mining of volumetrically small, but relatively enriched (average 0.6% U3O8) breccia pipe uranium (BPU) deposits near the Grand Canyon, Arizona, USA has the potential to affect groundwater and springs in the area. Such deposits also contain base metal sulfides that can oxidize to generate acid mine drainage and release trace metals. In this study, sequential batch experiments were conducted to simuAuthorsCarleton R. Bern, Kate M. Campbell, Katherine Walton-Day, Bradley S. Van GosenWater–rock interaction and the concentrations of major, trace, and rare earth elements in hydrocarbon-associated produced waters of the United States
Studies of co-produced waters from hydrocarbon extraction across multiple energy-producing basins have generally focused on major ions or a few select tracers, and studies that examine trace elements and involve laboratory experiments have generally been basin specific. Here, new perspective is sought through a broad analysis of concentration data for 26 elements from three hydrocarbon well typesAuthorsCarleton R. Bern, Justin E. Birdwell, Aaron M. JubbNontuberculous mycobacterial disease and molybdenum in Colorado watersheds
Nontuberculous mycobacteria (NTM) are environmental bacteria that may cause chronic lung disease. Environmental factors that favor NTM growth likely increase the risk of NTM exposure within specific environments. We aimed to identify water-quality constituents (Al, As, Cd, Ca, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Zn, and pH) associated with NTM disease across Colorado watersheds. We conducted aAuthorsEttie M Lipner, Joshua French, Carleton R. Bern, Katherine Walton-Day, David Knox, Michael Strong, D. Rebecca Prevots, James L CrooksSalt flushing, salt storage, and controls on selenium: A 31-year mass-balance analysis of an irrigated, semiarid valley
Salinity, selenium, and uranium pose water‐quality challenges for the Arkansas River in southeastern Colorado and other rivers that support irrigation in semiarid regions. This study used 31 years of continuous discharge and specific conductance (SC) monitoring data to assess interannual patterns in water quality using mass balance on a 120‐km reach of river. Discrete sampling data were used to liAuthorsCarleton R. Bern, Michael J. Holmberg, Zachary D. KisfalusiEffects of John Martin Reservoir on water quality and quantity: Assessment by chemical, isotopic, and mass-balance methods
Water quality and quantity can be influenced by transit through and storage in reservoirs. Assessing such effects can be challenging, however, because of mixing and residence times, and inter-annual net storage and release from both the reservoir itself and surrounding porosity. Here, different methodologies were used to assess the effect of John Martin Reservoir (JMR), located on the Arkansas RivAuthorsCarleton R. Bern, Michael J. Holmberg, Zachary D. KisfalusiComment on “Particle fluxes in groundwater change subsurface rock chemistry over geologic time”
Over the last decade, studies at the Shale Hills Critical Zone Observatory (Shale Hills) have greatly expanded knowledge of weathering in previously understudied, shale-mantled terrains, as well as Earth's Critical Zone as a whole. Among the many discoveries made was the importance of redistribution and losses of micron-sized particles during development of shale-derived soils. A geochemical fingeAuthorsCarleton R. Bern, Tiffany YesavageImproved enrichment factor calculations through principal component analysis: Examples from soils near breccia pipe uranium mines, Arizona, USA
The enrichment factor (EF) is a widely used metric for determining how much the presence of an element in a sampling media has increased relative to average natural abundance because of human activity. Calculation of an EF requires the selection of both a background composition and a reference element, choices that can strongly influence the result of the calculation. Here, it is shown how carefulAuthorsCarleton R. Bern, Katherine Walton-Day, David L. NaftzDual-phase mass balance modeling of small mineral particle losses from sedimentary rock-derived soils
Losses of small mineral particles can be a significant physical process that affects the elemental composition of soils derived from sedimentary rocks. Shales, in particular, contain abundant clay-sized minerals that can be mobilized by simple disaggregation, and solutional weathering is limited because the parent rock is composed primarily of recalcitrant minerals previously subjected to continenAuthorsCarleton R. Bern, Tiffany Yesavage