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Publications

Below are publications from the Mercury lab.

Filter Total Items: 180

Biogeochemical and physical processes controlling mercury methylation and bioaccumulation in Lake Powell, Glen Canyon National Recreation Area, Utah and Arizona, 2014 and 2015

Mercury monitoring results from about 300 Morone saxatilis (striped bass) muscle tissue samples collected by the State of Utah from Lake Powell resulted in a Utah/Arizona fish consumption advisory issued in 2012 for approximately the lower 100 kilometers of the reservoir. Chemical, physical, and biological data were collected during two synoptic sampling cruises on Lake Powell during May/June 2014
Authors
David L. Naftz, Mark Marvin-DiPasquale, David P. Krabbenhoft, George Aiken, Eric S. Boyd, Christopher H. Conaway, Jacob M. Ogorek, Gregory M. Anderson

Coagulant and sorbent efficacy in removing mercury from surface waters in the Cache Creek watershed, California

Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. E
Authors
Erica R. De Parsia, Jacob A. Fleck, David P. Krabbenhoft, Kim Hoang, David Roth, Paul Randall

Rapid pre-concentration of mercury in solids and water for isotopic analysis

The precise quantification of mercury (Hg) stable isotope compositions in low concentration or dilute samples poses analytical challenges due to Hg mass limitations. Common Hg pre-concentration procedures require extended processing times, making rapid Hg stable isotope measurements challenging. Here we present a modified pre-concentration method that combines commonly used Hg reduction and gold t
Authors
Sarah E. Janssen, Ryan F. Lepak, Michael T. Tate, Jacob M. Ogorek, John F. DeWild, Christopher L. Babiarz, James P. Hurley, David P. Krabbenhoft

Mercury isotopes reveal an ontogenetic shift in habitat use by walleye in lower Green Bay of Lake Michigan

In general, fish residing in rivers differ from fish residing in lakes in their mercury (Hg) isotope ratios. Specifically, fish residing in lakes typically show enriched values for the isotope ratios of δ202Hg (mass-dependent fractionation of isotope 202Hg) and Δ199Hg (mass-independent fractionation of isotope 199Hg) compared with fish residing in rivers, because photochemical effects acting on Hg
Authors
Charles P. Madenjian, Sarah E. Janssen, Ryan F. Lepak, Jacob M. Ogorek, Tylor J. Rosera, John F. DeWild, David P. Krabbenhoft, Stewart F. Cogswell, Mark E. Holey

Ratio of mercury concentration to PCB concentration varies with sex of white sucker (Catostomus commersonii)

The whole-fish total mercury (Hg) concentrations were determined in 25 mature female and 26 mature male white suckers (Catostomus commersonii) caught during their spawning run in the Kewaunee River, a tributary to Lake Michigan. The age of each fish was estimated using thin-sectioned otoliths, and total length (TL) and weight were determined for each fish. When adjusted for the effect of age, male
Authors
Charles P. Madenjian, Andrew L. Stevens, Martin A. Stapanian, David P. Krabbenhoft, John F. DeWild, Jacob M. Ogorek, William H. Edwards, Lynn M. Ogilvie, Peter B. McIntyre

Mercury methylation and bioaccumulation in Sinclair Inlet, Kitsap County, Washington

The U.S. Geological Survey evaluated the transformation of mercury to bioavailable methylmercury in Sinclair Inlet, Kitsap County, Washington, and assessed the effect of the transformation processes on the mercury burden in marine organisms and sediment. In August 2008, samples of sediment, water, and biota from six sites in Sinclair Inlet and three bays representative of Puget Sound embayments we
Authors
A.J. Paulson, M.C. Marvin-DiPasquale, P.W. Moran, J.F. DeWild, A.R. Stewart, J. Toft, J.L. Agee, E. Kakouros, Le H. Kieu, B. Carter, R.W. Sheibley, J. Cordell, David P. Krabbenhoft

Factors affecting mercury stable isotopic distribution in piscivorous fish of the Laurentian Great Lakes

Identifying the sources of methylmercury (MeHg) and tracing the transformations of mercury (Hg) in the aquatic food web are important components of effective strategies for managing current and legacy Hg sources. In our previous work, we measured stable isotopes of Hg (δ202Hg, Δ199Hg, and Δ200Hg) in the Laurentian Great Lakes and estimated source contributions of Hg to bottom sediment. Here, we id
Authors
Ryan F. Lepak, Sarah E. Janssen, Runsheng Yin, Jacob M. Ogorek, David P. Krabbenhoft, John F. DeWild, Michael T. Tate, Thomas M. Holsen, James P. Hurley

Permafrost stores a globally significant amount of mercury

Changing climate in northern regions is causing permafrost to thaw with major implications for the global mercury (Hg) cycle. We estimated Hg in permafrost regions based on in situ measurements of sediment total mercury (STHg), soil organic carbon (SOC), and the Hg to carbon ratio (RHgC) combined with maps of soil carbon. We measured a median STHg of 43 ± 30 ng Hg g soil−1 and a median RHgC of 1.6
Authors
Paul F. Schuster, Kevin Schaefer, George R. Aiken, Ronald C. Antweiler, John F. DeWild, Joshua D. Gryziec, Alessio Gusmeroli, Gustaf Hugelius, Elchin E. Jafarov, David P. Krabbenhoft, Lin Liu, Nicole M. Herman-Mercer, Cuicui Mu, David A. Roth, Tim Schaefer, Robert G. Striegl, Kimberly P. Wickland, Tingjun Zhang

Stream mercury export in response to contemporary timber harvesting methods (Pacific Coastal Mountains, Oregon, USA)

Land-use activities can alter hydrological and biogeochemical processes that can affect the fate, transformation, and transport of mercury (Hg). Previous studies in boreal forests have shown that forestry operations can have profound, but variable effects on Hg export and methylmercury (MeHg) formation. The Pacific Northwest is an important timber producing region that receives large atmospheric
Authors
Chris S. Eckley, Collin A. Eagles-Smith, Michael T. Tate, Brandon M Kowalski, Robert Danehy, Sherri L Johnson, David P. Krabbenhoft

Atmospheric deposition to forests in the eastern USA

Atmospheric mercury (Hg) deposition to forests is important because half of the land cover in the eastern USA is forest. Mercury was measured in autumn litterfall and weekly precipitation samples at a total of 27 National Atmospheric Deposition Program (NADP) monitoring sites in deciduous and mixed deciduous-coniferous forests in 16 states in the eastern USA during 2007–2014. These simultaneous, u
Authors
Martin R. Risch, John F. DeWild, David A. Gay, Leiming Zhang, Elizabeth W. Boyer, David P. Krabbenhoft

Spatial dependence of reduced sulfur in Everglades dissolved organic matter controlled by sulfate enrichment

Sulfate inputs to the Florida Everglades stimulate sulfidic conditions in freshwater wetland sediments that affect ecological and biogeochemical processes. An unexplored implication of sulfate enrichment is alteration of the content and speciation of sulfur in dissolved organic matter (DOM), which influences the reactivity of DOM with trace metals. Here, we describe the vertical and lateral spatia
Authors
Brett A. Poulin, Joseph N. Ryan, Kathryn L. Nagy, Aron Stubbins, Thorsten Dittmar, William H. Orem, David P. Krabbenhoft, George R. Aiken

Mobilization of mercury and arsenic from a carbonate-hosted ore deposit, central Idaho, U.S.A.

The Cinnabar and Fern mine sites in central Idaho are primary source areas for elevated mercury and arsenic entering the South Fork of the Salmon River, which provides critical spawning habitat for bull trout and Chinook salmon. Mercury mineralization is hosted by carbonate rocks, which generate waters dominated by Ca2+ and HCO3 - at pH 7 to 9. A synoptic sampling was conducted on headwater tribut
Authors
JoAnn M. Holloway, Michael Pribil, R. Blaine McCleskey, Alexandra B. Etheridge, David P. Krabbenhoft, George R. Aiken