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Publications

Below are publications from the Mercury lab.

Filter Total Items: 180

Mercury and methylmercury in aquatic sediment across western North America

Large-scale assessments are valuable in identifying primary factors controlling total mercury (THg) and monomethyl mercury (MeHg) concentrations, and distribution in aquatic ecosystems. Bed sediment THg and MeHg concentrations were compiled for > 16,000 samples collected from aquatic habitats throughout the West between 1965 and 2013. The influence of aquatic feature type (canals, estuaries, lakes
Authors
Jacob Fleck, Mark C. Marvin-DiPasquale, Collin A. Eagles-Smith, Joshua T. Ackerman, Michelle A. Lutz, Michael T. Tate, Charles N. Alpers, Britt D. Hall, David P. Krabbenhoft, Chris S. Eckley

Sex differences in contaminant concentrations of fish: a synthesis

Comparison of whole-fish polychlorinated biphenyl (PCB) and total mercury (Hg) concentrations in mature males with those in mature females may provide insights into sex differences in behavior, metabolism, and other physiological processes. In eight species of fish, we observed that males exceeded females in whole-fish PCB concentration by 17 to 43%. Based on results from hypothesis testing, we
Authors
Charles P. Madenjian, Richard R. Rediske, David P. Krabbenhoft, Martin A. Stapanian, Sergei M. Chernyak, James P. O'Keefe

Mercury cycling in the Hells Canyon Complex of the Snake River, Idaho and Oregon

Introduction The Hells Canyon Complex (HCC) is a hydroelectric project built and operated by the Idaho Power Company (IPC) that consists of three dams on the Snake River along the Oregon and Idaho border (fig. 1). The dams have resulted in the creation of Brownlee, Oxbow, and Hells Canyon Reservoirs, which have a combined storage capacity of more than 1.5 million acre-feet and span about 90 miles
Authors
Gregory M. Clark, Jesse Naymik, David P. Krabbenhoft, Collin A. Eagles-Smith, George R. Aiken, Mark C. Marvin-DiPasquale, Reed C. Harris, Ralph Myers

Climate change effects on North American inland fish populations and assemblages

Climate is a critical driver of many fish populations, assemblages, and aquatic communities. However, direct observational studies of climate change impacts on North American inland fishes are rare. In this synthesis, we (1) summarize climate trends that may influence North American inland fish populations and assemblages, (2) compile 31 peer-reviewed studies of documented climate change effects o
Authors
Abigail J. Lynch, Bonnie Myers, Cindy Chu, Lisa A. Eby, Jeffrey A. Falke, Ryan P. Kovach, Trevor J. Krabbenhoft, Thomas J. Kwak, John Lyons, Craig P. Paukert, James E. Whitney

Mercury accumulation and the mercury-PCB-sex interaction in summer flounder

Patterns in the relative differences in contaminant concentrations between the sexes of mature fish may reveal important behavioral and physiological differences between the sexes. We determined whole-fish total mercury (Hg) concentrations in 23 female summer flounder (Paralichthys dentatus) and 27 male summer flounder from New Jersey coastal waters. To estimate the change in Hg concentration due
Authors
Charles P. Madenjian, Olaf P. Jensen, David P. Krabbenhoft, John F. DeWild, Jacob M. Ogorek, Anthony R. Vastano

Mercury accumulation, and the mercury-PCB-sex interaction, in lake whitefish (Coregonus clupeaformis)

We determined whole-fish Hg concentrations of 26 female and 34 male adult lake whitefish (Coregonus clupeaformis) from northern Lake Huron captured during November 2010. Subsampling from these 60 fish, Hg concentration was also determined in both the somatic tissue and ovaries (n=5), while methylmercury (MeHg) concentration was determined in whole fish (n=18). Bioenergetics modeling was used to as
Authors
Charles P. Madenjian, Mark P. Ebener, David P. Krabbenhoft

Mercury transformation and release differs with depth and time in a contaminated riparian soil during simulated flooding

Riparian soils are an important environment in the transport of mercury in rivers and wetlands, but the biogeochemical factors controlling mercury dynamics under transient redox conditions in these soils are not well understood. Mercury release and transformations in the Oa and underlying A horizons of a contaminated riparian soil were characterized in microcosms and an intact soil core under satu
Authors
Brett Poulin, George R. Aiken, Kathryn L. Nagy, Alain Manceau, David P. Krabbenhoft, Joseph N. Ryan

Surface-air mercury fluxes across Western North America: A synthesis of spatial trends and controlling variables

Mercury (Hg) emission and deposition can occur to and from soils, and are an important component of the global atmospheric Hg budget. This paper focuses on synthesizing existing surface-air Hg flux data collected throughout the Western North American region and is part of a series of geographically focused Hg synthesis projects. A database of existing Hg flux data collected using the dynamic flux
Authors
Chris S. Eckley, Michael T. Tate, Che-Jen Lin, Mae S. Gustin, Stephen Dent, Collin A. Eagles-Smith, Michelle A. Lutz, Kimberly Wickland, Bronwen Wang, John E. Gray, Grant Edwards, David P. Krabbenhoft, David B. Smith

The effect of natural organic matter on mercury methylation by Desulfobulbus propionicus 1pr3

Methylation of tracer and ambient mercury (200Hg and 202Hg, respectively) equilibrated with four different natural organic matter (NOM) isolates was investigated in vivo using the Hg-methylating sulfate-reducing bacterium Desulfobulbus propionicus 1pr3. Desulfobulbus cultures grown fermentatively with environmentally representative concentrations of dissolved NOM isolates, Hg[II], and HS− were ass
Authors
John W. Moreau, Caitlin M. Gionfriddo, David P. Krabbenhoft, Jacob M. Ogorek, John F. DeWild, George R. Aiken, Eric E. Roden

Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (<1% y−1). These decrease
Authors
Yanxu Zhang, Daniel J. Jacob, Hannah M. Horowitz, Long Chen, Helen M. Amos, David P. Krabbenhoft, Franz Slemr, Vincent L. St. Louis, Elsie M. Sunderland

Use of stable isotope signatures to determine mercury sources in the Great Lakes

Sources of mercury (Hg) in Great Lakes sediments were assessed with stable Hg isotope ratios using multicollector inductively coupled plasma mass spectrometry. An isotopic mixing model based on mass-dependent (MDF) and mass-independent fractionation (MIF) (δ202Hg and Δ199Hg) identified three primary Hg sources for sediments: atmospheric, industrial, and watershed-derived. Results indicate atmosphe
Authors
Ryan F. Lepak, Runsheng Yin, David P. Krabbenhoft, Jacob M. Ogorek, John F. DeWild, Thomas M. Holsen, James P. Hurley

Mercury, monomethyl mercury, and dissolved organic carbon concentrations in surface water entering and exiting constructed wetlands treated with metal-based coagulants, Twitchell Island, California

Coagulation with metal-based salts is a practice commonly employed by drinking-water utilities to decrease particle and dissolved organic carbon concentrations in water. In addition to decreasing dissolved organic carbon concentrations, the effectiveness of iron- and aluminum-based coagulants for decreasing dissolved concentrations both of inorganic and monomethyl mercury in water was demonstrated
Authors
Elizabeth B. Stumpner, Tamara E.C. Kraus, Jacob A. Fleck, Angela M. Hansen, Sandra M. Bachand, William R. Horwath, John F. DeWild, David P. Krabbenhoft, Philip A.M. Bachand