Publications
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Arsenic in New Jersey Coastal Plain streams, sediments, and shallow groundwater: effects from different geologic sources and anthropogenic inputs on biogeochemical and physical mobilization processes
Arsenic (As) concentrations in New Jersey Coastal Plain streams generally exceed the State Surface Water Quality Standard (0.017 micrograms per liter (µg/L)), but concentrations seldom exceed 1 µg/L in filtered stream-water samples, regardless of geologic contributions or anthropogenic inputs. Nevertheless, As concentrations in unfiltered stream water indicate substantial variation because of part
Authors
Julia L. Barringer, Pamela A. Reilly, Dennis D. Eberl, Adam C. Mumford, William Benzel, Zoltan Szabo, Jennifer L. Shourds, Lily Y. Young
Microbial transformations of arsenic: Mobilization from glauconitic sediments to water
In the Inner Coastal Plain of New Jersey, arsenic (As) is released from glauconitic sediment to carbon- and nutrient-rich shallow groundwater. This As-rich groundwater discharges to a major area stream. We hypothesize that microbes play an active role in the mobilization of As from glauconitic subsurface sediments into groundwater in the Inner Coastal Plain of New Jersey. We have examined the pote
Authors
Adam C. Mumford, Julia L. Barringer, William Benzel, Pamela A. Reilly, L.Y. Young
Emerging contaminants at a closed and an operating landfill in Oklahoma
Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leach
Authors
William J. Andrews, Jason R. Masoner, Isabelle M. Cozzarelli
Determination of nonylphenol isomers in landfill leachate and municipal wastewater using steam distillation extraction coupled with comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry
4-Nonylphenols (4-NPs) are known endocrine disruptors and by-products of the microbial degradation of nonylphenol polyethoxylate surfactants. One of the challenges to understanding the toxic effects of nonylphenols is the large number of isomers that may exist in environmental samples. In order to attribute toxic effects to specific compounds, a method is needed for the separation and quantitation
Authors
Caixiang Zhang, Robert P. Eganhouse, James Pontolillo, Isabelle M. Cozzarelli, Yanxin Wang
GeoChip-based analysis of microbial functional gene diversity in a landfill leachate-contaminated aquifer
The functional gene diversity and structure of microbial communities in a shallow landfill leachate-contaminated aquifer were assessed using a comprehensive functional gene array (GeoChip 3.0). Water samples were obtained from eight wells at the same aquifer depth immediately below a municipal landfill or along the predominant downgradient groundwater flowpath. Functional gene richness and diversi
Authors
Zhenmei Lu, Zhili He, Victoria A. Parisi, Sanghoon Kang, Ye Deng, Joy D. Van Nostrand, Jason R. Masoner, Isabelle M. Cozzarelli, Joseph M. Suflita, Jizhong Zhou
Stable-isotope ratios of hydrogen and oxygen in precipitation at Norman, Oklahoma, 1996–2008
Precipitation samples for measurement of stable-isotope ratios of hydrogen (delta2H) and oxygen (delta18O) were collected at the Norman Landfill Research Site in Norman, Oklahoma, from May 1996 to October 2008. Rainfall amounts also were measured at the site (U.S. Geological Survey gaging station 07229053) during the collection period. The delta2H of precipitation samples ranged from -121.9 to +8.
Authors
Jeanne B. Jaeschke, Martha A. Scholl, Isabelle M. Cozzarelli, Jason R. Masoner, Scott Christenson, Haiping Qi
Long-term natural attenuation of crude oil in the subsurface
The time frame for natural attenuation of crude oil contamination in the subsurface has been studied for the last 27 years at a spill site located near Bemidji, Minnesota, USA. Data from thegroundwater contaminant plume show that dissolved benzene concentrations adjacent to the oil decreased by 50% between 1993 and 2007. To assess how this decrease is related to benzeneconcentrations in the crude
Authors
Barbara A. Bekins, Mary Jo Baedecker, Robert P. Eganhouse, William N. Herkelrath
Methane oxidation in a crude oil contaminated aquifer: Delineation of aerobic reactions at the plume fringes
High resolution direct-push profiling over short vertical distances was used to investigate CH4 attenuation in a petroleum contaminated aquifer near Bemidji, Minnesota. The contaminant plume was delineated using dissolved gases, redox sensitive components, major ions, carbon isotope ratios in CH4 and CO2, and the presence of methanotrophic bacteria. Sharp redox gradients were observed near the wat
Authors
R.T. Amos, Barbara A. Bekins, Geoffrey N. Delin, Isabelle M. Cozzarelli, D.W. Blowes, J. D. Kirshtein
Biogeochemical evolution of a landfill leachate plume, Norman, Oklahoma
Leachate from municipal landfills can create groundwater contaminant plumes that may last for decades to centuries. The fate of reactive contaminants in leachate-affected aquifers depends on the sustainability of biogeochemical processes affecting contaminant transport. Temporal variations in the configuration of redox zones downgradient from the Norman Landfill were studied for more than a decade
Authors
Isabelle M. Cozzarelli, John K. Böhlke, Jason R. Masoner, George N. Breit, Michelle M. Lorah, Michele L. Tuttle, Jeanne B. Jaeschke
In situ rates of sulfate reduction in response to geochemical perturbations
Rates of in situ microbial sulfate reduction in response to geochemical perturbations were determined using Native Organism Geochemical Experimentation Enclosures (NOGEEs), a new in situ technique developed to facilitate evaluation of controls on microbial reaction rates. NOGEEs function by first trapping a native microbial community in situ and then subjecting it to geochemical perturbations thro
Authors
T.A. Kneeshaw, J.T. McGuire, Isabelle M. Cozzarelli, E.W. Smith
Loss of volatile hydrocarbons from an LNAPL oil source
The light nonaqueous phase liquid (LNAPL) oil pool in an aquifer that resulted from a pipeline spill near Bemidji, Minnesota, was analyzed for volatile hydrocarbons (VHCs) to determine if the composition of the oil remains constant over time. Oil samples were obtained from wells at five locations in the oil pool in an anaerobic part of the glacial outwash aquifer. Samples covering a 21-year period
Authors
Mary Jo Baedecker, Robert P. Eganhouse, Barbara A. Bekins, Geoffrey N. Delin
Fate and transport of petroleum hydrocarbons in the subsurface near Cass Lake, Minnesota
The U.S. Geological Survey (USGS) investigated the natural attenuation of subsurface petroleum hydrocarbons leaked over an unknown number of years from an oil pipeline under the Enbridge Energy Limited Partnership South Cass Lake Pumping Station, in Cass Lake, Minnesota. Three weeks of field work conducted between May 2007 and July 2008 delineated a dissolved plume of aromatic hydrocarbons and cha
Authors
Dina M. Drennan, Barbara A. Bekins, Ean Warren, Isabelle M. Cozzarelli, Mary Jo Baedecker, William N. Herkelrath, Geoffrey N. Delin, Robert J. Rosenbauer, Pamela L. Campbell