Publications

The unsaturated zone (UZ) extends across the Earth’s terrestrial surface and is central to many problems related to land and water resource management. Flow of water through the UZ is typically thought to be slow and diffusive, such that it could attenuate fluxes and dampen variability between atmospheric inputs and underlying aquifer systems. This would reduce water resource...

This paper summarizes the changes in permeability at three boreholes located above an abutment pillar at a longwall coal mine in southwestern Pennsylvania. The motivation of this study was to better characterize the potential interaction between shale gas wells and the mine environment, through measurement of permeability changes in the coal mine overburden caused by mining-induced...

Recent production of light sweet oil has prompted reevaluation of Devonian petroleum systems in the central Appalachian Basin. Upper Devonian Ohio Shale (lower Huron Member) and Middle Devonian Marcellus Shale organic-rich source rocks from eastern Ohio and nearby areas were examined using organic petrography and geochemical analysis of solvent extracts to test ideas related to organic...

As part of a study to determine the origin of oil and gas in the Berea Sandstone in northeastern Kentucky and southeastern Ohio, 158 samples of organic-rich shale from the Upper Devonian Olentangy and Ohio Shales and the Lower Mississippian Sunbury Shale, collectively referred to as the “black shale,” were collected and analyzed from 12 cores. The samples were analyzed for total organic...

Shallow production of sweet high-gravity oil from the Upper Devonian Berea Sandstone in northeastern Kentucky has caused the region to become the leading oil producer in the state. Potential nearby source rocks, namely, the overlying Mississippian Sunbury Shale and underlying Ohio Shale, are immature for commercial oil generation according to vitrinite reflectance and programmed...

Geological carbon sequestration (GCS) is necessary to help meet emissions reduction goals, but groundwater contamination may occur if CO2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of southwest Utah, water with moderate salinity and high CO2 concentrations is leaking...

This study examines the use of organic petrology techniques to quantify the amount of coal and carbonaceous combustion by-products (i.e., coke, coal tar/pitch, cenospheres) in sediments taken from the Kinnickinnic River adjacent to the former site of the Milwaukee Solvay Coke and Gas Company. These materials are of concern as contaminants like polycyclic aromatic hydrocarbons (PAHs) are...

Since 2011, the Devonian Berea Sandstone in northeastern Kentucky has produced oil where thermal maturity studies indicate that likely source rocks, namely, the Devonian Ohio Shale and Mississippian Sunbury Shale, are thermally immature. Downdip, where source rocks are mature for oil, the Berea Sandstone and Ohio Shale primarily produce gas. To investigate this thermal maturity...

The Arctic Alaska petroleum province is geologically and geochemically complex. Mixed hydrocarbon charge from multiple source rocks and/or levels of thermal maturity is common within an individual oil pool. Biomarker and chemometric statistical analyses were used to correlate twenty-nine oils to five oil families derived from: (1) Triassic Shublik Formation (calcareous organofacies), (2)...

Atomic chlorine (Cl•) affects air quality and atmospheric oxidizing capacity. Nitryl chloride (ClNO2) – a common Cl• source–forms when chloride-containing aerosols react with dinitrogen pentoxide (N2O5). A recent study showed that saline lakebed (playa) dust is an inland source of particulate chloride (Cl–) that generates high ClNO2. However, the underlying physiochemical factors...

A Gram-stain-negative, strictly anaerobic, non-motile, rod-shaped bacterium, designated SFB93T, was isolated from the intertidal sediments of South San Francisco Bay, located near Palo Alto, CA, USA. SFB93T was capable of acetylenotrophic and diazotrophic growth, grew at 22–37 °C, pH 6.3–8.5 and in the presence of 10–45 g l−1 NaCl. Phylogenetic analyses based on 16S rRNA gene sequencing...

Exsolution and re-dissolution of CO2 gas within heterogeneous porous media are investigated using experimental data and mathematical modeling. In a set of bench-scale experiments, water saturated with CO2 under a given pressure is injected into a 2-D water-saturated porous media system, causing CO2 gas to exsolve and migrate upwards. A layer of fine sand mimicking a heterogeneity within...