Publications

Watershed land cover affects in-stream water quality and sediment nutrient dynamics. The presence of natural land cover in the riparian zone can reduce the negative effects of agricultural land use on water quality; however, literature evaluating the effects of natural riparian land cover on stream sediment nutrient dynamics is scarce. The objective of this study was to assess if stream...

A comparison of the presence of additives in airport deicers commonly used in the United States and in airport runoff was conducted with data collected before and after changes in deicer formulations. Three isomers of benzotriazoles (BTs)—4-methyl-1H-benzotriazole (4-MeBT), 5-methyl-1H-benzotriazole (5-MeBT), and 1H-benzotriazole (1H-BT)—are corrosion inhibitors added to some...

This report provides the necessary documentation of the numerical models developed for the Central Sands Lake study in central Wisconsin and will be included as a technical appendix in the report to the Wisconsin State Legislature by the Wisconsin Department of Natural Resources (WDNR) in response to 2017 Wisconsin Act 10. This legislation directed WDNR to determine whether existing and...

The Mississippi embayment encompasses about 100,000 square miles and covers parts of eight States. In 2016, the U.S. Geological Survey began updating previous work for a part of the embayment known as the Mississippi Alluvial Plain to support informed water use and agricultural policy in the region. Groundwater, water use, economic, and other related models are being combined with field...

In 2015–16, a comparison study of stream sediment collection techniques was done for a U.S. Geological Survey streamgage on the Nemadji River near South Superior, Wisconsin (U.S. Geological Survey station number 04024430) to provide an adjustment factor for comparing suspended-sediment rating curves for two historical periods 1973–86 and 2006–16. During 1973–1986, the U.S. Geological...

Waterborne contaminants were monitored in 69 tributaries of the Laurentian Great Lakes in 2010 and 2014 using semipermeable membrane devices (SPMDs) and polar organic chemical integrative samplers (POCIS). A risk-based screening approach was used to prioritize chemicals and chemical mixtures, identify sites at greatest risk for biological impacts, and identify potential hazards to...

Algal and cyanobacterial blooms can foul water systems, inhibit recreation, and produce cyanotoxins, which can be toxic to humans, domestic animals, and wildlife. Blooms that recur yearly present a special challenge, in that chronic effects of most cyanotoxins are unknown. To better understand cyanotoxin timing, possible environmental triggers, and inter-relations among taxa and toxins...

Freshwater Harmful Algal Blooms (HABs) pose serious risks throughout the world to drinking water, recreation, and ecosystem health. The Great Lakes, which contain nearly 20% of the world’s available surface freshwater, have been experiencing an increase in HABs since the 1990s. Knowledge gaps relating to HABs remain even after extensive and ongoing research efforts. These knowledge gaps...

Toxicity of methylmercury (MeHg) to wildlife and humans results from its binding to cysteine residues of proteins, forming MeHg-cysteinate (MeHgCys) complexes that hinder biological functions. MeHgCys complexes can be detoxified in vivo, yet how this occurs is unknown. We report that MeHgCys complexes are transformed into selenocysteinate (Hg(Sec)4) complexes in multiple animals from two...

Despite limitations in reproducing complex bedload sediment transport processes in rivers, formulas have been preferred over collection and analysis of field data due to the high cost and time-consuming nature of bedload discharge measurements. However, the performance of such formulas depends on the hydraulic and sedimentological conditions they attempt to describe. The availability of...

Realistic environmental models used for decision making typically require a highly parameterized approach. Calibration of such models is computationally intensive because widely used parameter estimation approaches require individual forward runs for each parameter adjusted. These runs construct a parameter-to-observation sensitivity, or Jacobian, matrix used to develop candidate...

The robust application of stable mercury (Hg) isotopes for mercury source apportionment and risk assessment necessitates the understanding of mass-dependent fractionation (MDF) due to internal transformations within organisms. Here, we used high energy-resolution XANES spectroscopy and isotope ratios of total mercury (δ202THg) and methylmercury (δ202MeHg) to elucidate the chemical...