Publications

History matching of large hydrologic models is challenging due to data sparsity and non-unique process combinations (and associated parameters) that can produce similar model predictions. We develop an ensemble-based history matching (and uncertainty quantification) approach using an iterative ensemble smoother (iES) method for three cutouts of the National Hydrologic Model (NHM) and...

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent...

Regulatory agencies in humid temperate environments rely on timely evaluations of streamflow depletion and drawdown to protect aquatic ecosystems and existing water users. Numerical models offer detailed insights, but their complexity and time demands often preclude their practical use in rapid decision-making. We present pycap-dss, an open-source Python package that implements a suite...

Modeling plays a vital role in understanding and managing complex environmental systems, but its credibility and quality depend heavily on a comprehensive set of defensible model activities and practices, especially when the system of interest is plagued with uncertainties and conflicting stakeholder perspectives. This paper proposes a catalogue of Do's and Don'ts to guide modelers in...

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed...

The FluOil tool was developed to help with planning and early response for oil spills in rivers where subsurface oil-sediment interactions result in the formation of oil-particle aggregates (OPA). The turbulence and variable velocity associated with water flowing within a natural stream channel creates the conditions needed for an oil slick to break up into small droplets and mix in the...

Mercury (Hg) methylation is a microbially mediated process that converts inorganic Hg into bioaccumulative, neurotoxic methylmercury (MeHg). The metabolic activity of methylating organisms is highly dependent on biogeochemical conditions, which subsequently influences MeHg production. However, our understanding of the ecophysiology of methylators in natural ecosystems is still limited...

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO3– + NO2–-N) export across the UMRB at high spatial resolution (12-digit...

Urban runoff containing high amounts of nutrients like phosphorus (P) is a well-established driver of surface water eutrophication. In residential areas, a primary source of nutrients is derived from leaf litter. P contained in leaves is leached and transported by stormwater from source to stream. The majority of P leached from leaf litter is in the dissolved phase, which can be...

The U.S. Geological Survey is developing nationally consistent water-use modeling approaches to replace previous methods relying on locally specific reported and estimated data. These national assessments require datasets that incorporate water withdrawal variability across the United States and over long periods. However, source data often have unclear definitions, missing or varied...

Community concerns about water availability vary depending on local economic, regulatory, environmental, and ecological considerations. In water-rich basins, water quality is often the focus of community concerns. As such, understanding community priorities in the context of water quality is crucial for informing scientists working in water-rich basins. In this work, we compiled over 6...

When sampling for waterborne microbes, researchers may need to diverge from recommended sample volumes due to logistical constraints, novel targets, or challenging matrices, with little guidance about the potential impact on results. In field studies, we measured bacteria, viruses, and protozoa (15 quantitative polymerase chain reaction assays) in paired large- and small-volume samples...