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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 686

Exploring the potential value of satellite remote sensing to monitor chlorophyll-a for U.S. lakes and reservoirs Exploring the potential value of satellite remote sensing to monitor chlorophyll-a for U.S. lakes and reservoirs

Assessment of chlorophyll-a, an algal pigment, typically measured by field and laboratory in situ analyses, is used to estimate algal abundance and trophic status in lakes and reservoirs. In situ-based monitoring programs can be expensive, may not be spatially, and temporally comprehensive and results may not be available in the timeframe needed to make some management decisions, but can...
Authors
Michael Papenfus, Blake Schaeffer, Amina Pollard, Keith Loftin

Metabarcoding assays for the detection of freshwater mussels (Unionida) with environmental DNA Metabarcoding assays for the detection of freshwater mussels (Unionida) with environmental DNA

Freshwater mussels of the order Unionida are a widely distributed taxon that are important in maintaining freshwater ecosystems and are also highly imperiled throughout the world. Monitoring of mussel populations with environmental DNA (eDNA) is an attractive alternative to traditional methods because it is noninvasive and requires less labor and taxonomic knowledge from field personnel...
Authors
Katy Klymus, Catherine Richter, Nathan Thompson, Jo Hinck, Jess Jones

Terrestrial ecological risk analysis via dietary exposure at uranium mine sites in the Grand Canyon watershed (Arizona, USA) Terrestrial ecological risk analysis via dietary exposure at uranium mine sites in the Grand Canyon watershed (Arizona, USA)

The U.S. Department of the Interior recently included uranium (U) on a list of mineral commodities that are considered critical to economic and national security. The uses of U for commercial and residential energy production, defense applications, medical device technologies, and energy generation for space vehicles and satellites are known, but the environmental impacts of uranium...
Authors
Jo Hinck, Danielle Cleveland, Bradley Sample

Retrospective analysis of estrogenic endocrine disruption and land-use influences in the Chesapeake Bay watershed Retrospective analysis of estrogenic endocrine disruption and land-use influences in the Chesapeake Bay watershed

The Chesapeake Bay is the largest estuary in the United States and its watershed includes river drainages in six states and the District of Columbia. Sportfishing is of major economic interest, however, the rivers within the watershed provide numerous other ecological, recreational, cultural and economic benefits, as well as serving as a drinking water source for millions of people...
Authors
Vicki S. Blazer, Stephanie Gordon, Daniel Jones, Luke R. Iwanowicz, Heather Walsh, Adam Sperry, Kelly L. Smalling

Development and testing of species-specific quantitative PCR assays for environmental DNA applications Development and testing of species-specific quantitative PCR assays for environmental DNA applications

New, non-invasive methods for detecting and monitoring species presence are being developed to aid in fisheries and wildlife conservation management. The use of environmental DNA (eDNA) samples for detecting macrobiota is one such group of methods that is rapidly becoming popular and being implemented in national management programs. Here we focus on the development of species-specific...
Authors
Katy Klymus, Dannise Ruiz-Ramos, Nathan Thompson, Catherine Richter

Assessing uranium and select trace elements associated with breccia pipe uranium deposits in the Colorado River and main tributaries in Grand Canyon, USA Assessing uranium and select trace elements associated with breccia pipe uranium deposits in the Colorado River and main tributaries in Grand Canyon, USA

Assessing chemical loading from streams in remote, difficult-to-access watersheds is challenging. The Grand Canyon area in northern Arizona, an international tourist destination and sacred place for many Native Americans, is characterized by broad plateaus divided by canyons as much as two-thousand meters deep and hosts some of the highest-grade uranium deposits in the U.S. From 2015...
Authors
Fred Tillman, Jessica Anderson, Joel A. Unema, Thomas Chapin

Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota Effects of a crude-oil recovery remediation system operated 1999–2003 on groundwater plumes and unsaturated-zone vapor concentrations at a crude-oil spill site near Bemidji, Minnesota

A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, Minnesota. More than 70 percent of the 1.7 million liters of spilled crude oil was removed shortly thereafter. In response to a requirement by the State regulatory agency to remove the remaining crude to a sheen in all wells, in 1998, the pipeline company installed a dual-pump recovery system at the site. This...
Authors
Geoffrey Delin, William Herkelrath, Jared Trost

Transport and speciation of uranium in groundwater-surface water systems impacted by legacy milling operations Transport and speciation of uranium in groundwater-surface water systems impacted by legacy milling operations

Growing worldwide concern over uranium contamination of groundwater resources has placed an emphasis on understanding uranium transport dynamics and potential toxicity in groundwater-surface water systems. In this study, we utilized novel in-situ sampling methods to establish the location and magnitude of contaminated groundwater entry into a receiving surface water environment, and to...
Authors
Patrick Byrne, Christopher Fuller, David Naftz, Robert Runkel, Niklas Lehto, William L Dam

Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore

Widespread application of neonicotinoids has led to their proliferation in waters. Despite low neonicotinoid hydrophobicity, our prior studies implicated granular activated carbon (GAC) in neonicotinoid removal. Based on known receptor binding characteristics, we hypothesized that the insecticidal pharmacophore influences neonicotinoid sorption. Our objectives were to illuminate drivers...
Authors
Danielle Webb, Matthew Nagorzanski, Megan Powers, David Cwiertny, Michelle Hladik, Gregory LeFevre

Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters

Releases of oil and gas (OG) wastewaters can have complex effects on stream-water quality and downstream organisms, due to sediment-water interactions and groundwater/surface water exchange. Previously, elevated concentrations of sodium (Na), chloride (Cl), barium (Ba), strontium (Sr), and lithium (Li), and trace hydrocarbons were determined to be key markers of OG wastewater releases...
Authors
Isabelle Cozzarelli, Douglas Kent, Martin Briggs, Mark Engle, Adam Benthem, Katherine Skalak, Adam Mumford, Jeanne Jaeschke, Aida Farag, John W. Lane, Denise M. Akob

Groundwater discharges as a source of phytoestrogens and other agriculturally derived contaminants to streams Groundwater discharges as a source of phytoestrogens and other agriculturally derived contaminants to streams

Groundwater discharge zones in streams are important habitats for aquatic organisms. The use of discharge zones for thermal refuge and spawning by fish and other biota renders them susceptible to potential focused discharge of groundwater contamination. Currently, there is a paucity of information about discharge zones as a potential exposure pathway of chemicals to stream ecosystems...
Authors
Tyler Thompson, Martin A. Briggs, Patrick Phillips, Vicki S. Blazer, Kelly L. Smalling, Dana W. Kolpin, Tyler Wagner

Effects of early life stage exposure of largemouth bass to atrazine or a model estrogen (17α-ethinylestradiol) Effects of early life stage exposure of largemouth bass to atrazine or a model estrogen (17α-ethinylestradiol)

Endocrine disrupting contaminants are of continuing concern for potentially contributing to reproductive dysfunction in largemouth and smallmouth bass in the Chesapeake Bay watershed (CBW) and elsewhere. Exposures to atrazine (ATR) have been hypothesized to have estrogenic effects on vertebrate endocrine systems. The incidence of intersex in male smallmouth bass from some regions of CBW...
Authors
Jessica Leet, Catherine Richter, Robert Cornman, Jason P. Berninger, Ramji K. Bhandari, Diane K. Nicks, James L. Zajicek, Vicki S. Blazer, Donald Tillitt
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