Jacob A Fleck
Jacob A Fleck - California Water Science Center
Science and Products
Remote Sensing of Mercury Pollution in South San Francisco Bay
San Francisco Bay has a long history of being subject to natural resources exploitation and pollution. Ongoing flux of contaminants into the bay, legacy pollution from the Gold Rush era and structural modifications still influence the natural ecosystem today. This project aims to map multiple forms (i.e. species) of mercury -- one of the major contaminants in the bay -- to help inform restoration...
High Resolution Temporal and Spatial Mapping of Mercury and Methylmercury in Surface Waters of the Sacramento – San Joaquin Delta
Mercury (Hg) is a contaminant of significant concern in the San Francisco Bay-Delta estuary and watershed (Bay-Delta). The formation, fate, and transport of methylmercury (MeHg), a particularly toxic organic form of Hg that readily bioaccumulates in wildlife, has been studied extensively throughout the system. However, there is widespread recognition of the need for more comprehensive monitoring...
Assessment of environmental impacts of mercury treatability test using suction dredging, South Yuba River
The goals of the BLM suction dredging treatability study are to (1) assess the effectiveness of suction dredging in removing mercury from the environment and (2) assess potential impacts of suction dredging with regard to discharging mercury-contaminated suspended sediment to the aquatic environment.
Mercury and Dissolved Organic Matter in Delta Wetlands
Between 1860 and 1914, hydraulic mining activities sent more than 800,000,000 cubic yards of mercury-laden sediment into the Delta altering the landscape, water flows, and contributing to the leveeing and reclamation of the Delta's marshes. Transport of mercury from historic mining areas continues today. The sedimentary supply of mercury to the Delta and in Delta sediments (cinnabar, metacinnabar...
A Non-Point Source Of Contaminants To The Estuarine Food Web: Mobilized Particles From The Intertidal Zone
The San Francisco Bay and Sacramento-San Joaquin Delta (Bay-Delta) region is a highly urbanized and contaminated estuary with a valuable commercial and recreational fishery (Nichlos et al., 1986; SFEI, 2004). Many fish and birds in the San Francisco Estuary exhibit high levels of contaminants (metals and organic pollutants), which have been shown to affect their behavior and reproductive success...
Methylmercury cycling and export from agricultural and natural wetlands in the Yolo Bypass
The purpose of the work conducted by the USGS California Water Science Center is to help guide Yolo Wildlife Area management practices by identifying the relationships between management effects on dissolved organic matter properties and the resulting role of dissolved organic matter in mercury methylation and biotic uptake measured by the cooperating USGS scientists. The information gathered will...
Investigation of Linkages Between Management Practices Used in Sacramento-San Joaquin Delta Rice Production and Loads of Dissolved Organic Matter and Disinfection Byproduct Precursors
The primary objective of this study is to expand our current understanding of how to manage rice production in the Sacramento-San Joaquin Delta in a manner that minimizes loads of water quality contaminants to Delta waters.
Evaluating coagulation techniques to reduce the transport of Hg from mine-affected and active geothermal Hg-source watersheds
Our objective is to determine the effectiveness of coagulation and adsorption techniques in removing mercury from contaminated surface waters of the Cache Creek watershed.
Assessment of methyl mercury (MeHg) release from sediment formed in wetland treatment cells designed to remove mercury from surface waters using in situ coagulation
Our objective is to determine the relative propensity of sediment material formed under two different in situ coagulation treatments (iron sulfate, polyaluminum chloride) to release MeHg into surface waters under environmentally relevant conditions that may affect flocculant stability and MeHg production rates.
Monitoring Mercury and Methylmercury in Water, Sediment and Biota in Combie Reservoir Before and After Dredging and Mercury Removal
Dredging to maintain water storage capacity by the Nevada Irrigation District (NID) occurred at Lake Combie reservoir, one of several reservoirs along the Bear River, California over the past 40 years on an as-needed basis to maintain water storage capacity. Maintenance dredging operations were halted by the Central Valley Regional Water Quality Control Board (CVRWQCB) in 2002 because of elevated...
Mercury cycling, bioaccumulation, and risk across western North America: a landscape scale synthesis linking long-term datasets
Mercury (Hg) is a serious environmental problem that is impacting ecological and human health on a global scale. However, local and regional processes are largely responsible for producing methylmercury, which drives ecological risk. This is particularly true in western North America where the combination of diverse landscapes, habitat types, climates, and Hg sources may disproportionally impact t
Filter Total Items: 20
2022 Organic Matter Research Lab Sacramento, California Vectorized Fluorescence Data
The U.S. Geological Survey (USGS) California Water Science Center (CAWSC) Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic
2022 Organic Matter Research Lab Sacramento, California Full Spectra Absorbance Data
The U.S. Geological Survey (USGS) California Water Science Center (CAWSC) Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic
Laboratory optical measurements in support of assessing PFAS enrichment in natural foams on surface waters within the Delaware River Basin
One phenomenon that has been shown to concentrate and release per- and polyfluoroalkyl substances (PFAS) in surface water is the formation of natural foams. For surface water foams to form, surface active compounds or surfactants must be present in the water along with a source of gas bubbles. Some examples of surface-active compounds include humic and fulvic acids, colloidal particles, and lipids
Longitudinal assessment of per- and polyfluoroalkyl substances and co-occurring inorganic and organic contaminants in Neshaminy Creek, Pennsylvania, November 2021
Per- and polyfluoroalkyl substances (PFAS) and co-occurring inorganic and organic contaminants are widely distributed in the environment and understanding their surface water sources is critical for water resource management. In November 2021, 13 sites were sampled along a stream reach in the Neshaminy Creek basin in southeastern Pennsylvania utilizing a time of travel sampling approach. The reach
Laboratory Optical Measurements From Discrete Surface Water Samples Collected During Water Quality Mapping Campaigns on the Illinois Waterway and Chicago Area Waterway Systems
Fluorescence and absorbance spectra were measured in discrete surface water samples collected during three sampling campaigns (Nov 2022, Mar/Apr 2023, Jul 2023) on the Illinois Waterway (IWW) and Chicago Area Waterway System (CAWS), which are the primary drainage of the Illinois River Basin (IRB). Water sampling was conducted concurrently with a boat-based water quality mapping effort using the Fa
Stability testing results for stock solutions to standardize calibration of field fluorescence sensors
Optical sensors measuring fluorescence of dissolved organic matter (fDOM) are increasingly used in water quality studies because they provide proxy measurements for a variety of contaminants and constituents of concern including metals and wastewater effluent. Similarly, sensors measuring fluorescence of chlorophyll (fChl) and phycocyanin (fPC) have gained popularity to measure phytoplankton conce
Optical measurements for surface water samples collected within the Neshaminy Creek basin during November 2021
Here we report optical data collected as part of a collaborative study between USGS Pennsylvania Water Science Center, Pennsylvania Department of Environmental Protection and Water Mission Area Proxies Project. The optical measurements reported here were collected to aide in the characterization of water sources and mixtures and establish proxies (surrogates) for per- and poly-fluorinated alkyl su
Aqueous and solid phases partitioning of elemental constituents associated with Marcellus Shale Energy and Environment Laboratory (MSEEL) gas well produced wastewater, Morgantown, WV, 2016 - 2019
The Marcellus Shale Energy and Environment Laboratory (MSEEL) site is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The
Laboratory fluorescence and total dissolved nitrogen measurements for surface water samples collected from the Rio Grande during a 24-hr time period near Albuquerque, New Mexico
Here, we present data supporting temporal variability and sources of PFAS in the Rio Grande through an arid urban area using high-frequency sampling and novel samplers. Data are compiled into two tables: 1) full fluorescence spectra in vectorized format, and 2) summary file of concentrations of total dissolved nitrogen and commonly extracted field-based sensor arrays. Data are reported from two si
Fluorescence sensor measurements in sediment suspensions to evaluate turbidity corrections
The use of field-deployable fluorescence sensors to better understand dissolved organic matter concentrations and composition has grown immensely in recent years. Applications of these sensors to critical monitoring efforts have also grown to encompass post-fire monitoring, wastewater tracking, and use as a proxy for various contaminants. Despite the growth, it is well known that these sensors are
Comparisons from an Aqualog Fluorometer Standardized to Quinine Sulfate Equivalents (QSE) with Excitation (ex) and Emissions (em) Equivalent to Fluorescence of Dissolved Organic Matter (fDOM) Sensors from Multiple Manufacturers
Here, we present the results supporting Table 2 in Field Techniques for Fluorescence Measurements Targeting Dissolved Organic Matter, Hydrocarbons, and Wastewater in Environmental Waters: Principles and Guidelines for Instrument Selection, Operation and Maintenance, Quality Assurance, and Data Reporting. Table 2 shows comparisons from an Aqualog 800 benchtop fluorometer standardized to quinine sul
2021 Organic Matter Research Lab Vectorized Fluorescence Data
The USGS CAWSC Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic matter (DOM) composition, and can also serve as proxies for
Filter Total Items: 37
Temporal variability and sources of PFAS in the Rio Grande, New Mexico through an arid urban area using multiple tracers and high-frequency sampling
Per- and polyfluoroalkyl substances (PFAS) are ubiquitous in the environment but sources are not well defined for temporal and spatial aspects within an urban environment, and especially for an arid urban environment subject to seasonal short term high-intensity precipitation events. A focused diel sampling was conducted in the summer of 2021 to assess the temporal and spatial variability of PFAS
Authors
Kimberly R. Beisner, Rebecca E. Travis, David Alvarez, Larry B. Barber, Jacob Fleck, Jeramy Roland Jasmann
Influence of irrigation water and soil on annual mercury dynamics in Sacramento Valley rice fields
Methylmercury (MeHg) is a human and environmental toxin produced in flooded soils. Little is known about MeHg in rice (Oryza Sativa L.) fields in Sacramento Valley, California. The objectives of this study were to quantify mercury fractions in irrigation water and within rice fields and to determine their mercury pools in surface water, soil, and grain. Soil, grain, and surface water (dissolved an
Authors
Luke A. Salvato, Mark C. Marvin-DiPasquale, Jacob Fleck, Stephen A. McCord, Bruce A. Linquist
Field techniques for fluorescence measurements targeting dissolved organic matter, hydrocarbons, and wastewater in environmental waters: Principles and guidelines for instrument selection, operation and maintenance, quality assurance, and data reporting
The use of field deployable fluorescence sensors by the U.S. Geological Survey has become increasingly common for a wide variety of surface water and groundwater investigations. This report addresses field deployable fluorometers that measure the fluorescence response of various substances in water exposed to incident light generated by the sensor. An introduction to the basic principles of field
Authors
Amanda Booth, Jacob Fleck, Brian A. Pellerin, Angela Hansen, Alexandra Etheridge, Guy M. Foster, Jennifer L. Graham, Brian A. Bergamaschi, Kurt D. Carpenter, Bryan D. Downing, Stewart A. Rounds, JohnFranco Saraceno
Wetland management strategy to reduce mercury export in water and bioaccumulation in fish
Wetland environments provide numerous ecosystem services but also facilitate methylmercury (MeHg) production and bioaccumulation. We developed a wetland‐management technique to reduce MeHg concentrations in wetland fish and water. We physically modified seasonal wetlands by constructing open‐ and deep‐water treatment cells at the downstream end of seasonal wetlands to promote naturally occurring M
Authors
Joshua T. Ackerman, Jacob Fleck, Collin A. Eagles-Smith, Mark C. Marvin-DiPasquale, Lisamarie Windham-Myers, Mark P. Herzog, Harry L. McQuillen
Coagulant and sorbent efficacy in removing mercury from surface waters in the Cache Creek watershed, California
Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. E
Authors
Erica R. De Parsia, Jacob A. Fleck, David P. Krabbenhoft, Kim Hoang, David Roth, Paul Randall
Geochemical data for water, streambed sediment, and fish tissue from the Sierra Nevada Mercury Impairment Project, 2011–12
This report presents geochemical data for surface water, streambed sediment, and fish tissue samples collected during low-flow conditions in 20 to 24 Sierra Nevada streams during 2011 and 2012. The dataset is part of a larger study designed to assess the factors that control mercury concentrations in fish tissue and to develop a model that predicts mercury concentration in the tissue of selected f
Authors
Elizabeth B. Stumpner, Charles N. Alpers, Mark C. Marvin-DiPasquale, Jennifer L. Agee, Evangelos Kakouros, Michelle R. Arias, Le H. Kieu, David A. Roth, Darrell G. Slotton, Jacob A. Fleck
Procedures for using the Horiba Scientific Aqualog® fluorometer to measure absorbance and fluorescence from dissolved organic matter
Advances in spectroscopic techniques have led to an increase in the use of optical measurements (absorbance and fluorescence) to assess dissolved organic matter composition and infer sources and processing. Although optical measurements are easy to make, they can be affected by many variables rendering them less comparable, including by inconsistencies in sample collection (for example, filter por
Authors
Angela M. Hansen, Jacob Fleck, Tamara E. C. Kraus, Bryan D. Downing, Travis von Dessonneck, Brian A. Bergamaschi
Methylmercury dynamics in Upper Sacramento Valley rice fields with low background soil mercury levels
Few studies have considered how methylmercury (MeHg, a toxic form of Hg produced in anaerobic soils) production in rice (Oryza sativa L.) fields can affect water quality, and little is known about MeHg dynamics in rice fields. Surface water MeHg and total Hg (THg) imports, exports, and storage were studied in two commercial rice fields in the Sacramento Valley, California, where soil THg was low (
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Mark C. Marvin-DiPasquale, Jacob Fleck, Kenneth W. Tate, Bruce A. Linquist
Mercury on a landscape scale—Balancing regional export with wildlife health
The Cosumnes River watershed requires a 57–64 percent reduction in loads to meet the new Delta methylmercury (MeHg) total maximum daily load allocation, established by the Central Valley Regional Water Quality Control Board. Because there are no large point sources of MeHg in the watershed, the focus of MeHg load reductions will fall upon non-point sources, particularly the expansive wetlands cons
Authors
Mark C. Marvin-DiPasquale, Lisamarie Windham-Myers, Jacob A. Fleck, Joshua T. Ackerman, Collin A. Eagles-Smith, Harry McQuillen
Alternate wetting and drying decreases methylmercury in flooded rice (Oryza sativa) systems
In flooded soils, including those found in rice (Oryza sativa L.) fields, microbes convert inorganic Hg to more toxic methylmercury (MeHg). Methylmercury is accumulated in rice grain, potentially affecting health. Methylmercury in rice field surface water can bioaccumulate in wildlife. We evaluated how introducing aerobic periods into an otherwise continuously flooded rice growing season affects M
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Mark C. Marvin-DiPasquale, Jacob Fleck, Bruce A. Linquist
The contribution of rice agriculture to methylmercury in surface waters: A review of data from the Sacramento Valley, California
Methylmercury (MeHg) is a bioaccumulative pollutant produced in and exported from flooded soils, including those used for rice (Oriza sativa L.) production. Using unfiltered aqueous MeHg data from MeHg monitoring programs in the Sacramento River watershed from 1996 to 2007, we assessed the MeHg contribution from rice systems to the Sacramento River. Using a mixed-effects regression analysis, we co
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Jacob Fleck, Kenneth W. Tate, Stephen A. McCord, Bruce A. Linquist
Mercury and methylmercury in aquatic sediment across western North America
Large-scale assessments are valuable in identifying primary factors controlling total mercury (THg) and monomethyl mercury (MeHg) concentrations, and distribution in aquatic ecosystems. Bed sediment THg and MeHg concentrations were compiled for > 16,000 samples collected from aquatic habitats throughout the West between 1965 and 2013. The influence of aquatic feature type (canals, estuaries, lakes
Authors
Jacob Fleck, Mark C. Marvin-DiPasquale, Collin A. Eagles-Smith, Joshua T. Ackerman, Michelle A. Lutz, Michael T. Tate, Charles N. Alpers, Britt D. Hall, David P. Krabbenhoft, Chris S. Eckley
By
Ecosystems Mission Area, Water Resources Mission Area, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Forest and Rangeland Ecosystem Science Center, John Wesley Powell Center for Analysis and Synthesis, Upper Midwest Water Science Center, Mercury Research Laboratory
Science and Products
Remote Sensing of Mercury Pollution in South San Francisco Bay
San Francisco Bay has a long history of being subject to natural resources exploitation and pollution. Ongoing flux of contaminants into the bay, legacy pollution from the Gold Rush era and structural modifications still influence the natural ecosystem today. This project aims to map multiple forms (i.e. species) of mercury -- one of the major contaminants in the bay -- to help inform restoration...
High Resolution Temporal and Spatial Mapping of Mercury and Methylmercury in Surface Waters of the Sacramento – San Joaquin Delta
Mercury (Hg) is a contaminant of significant concern in the San Francisco Bay-Delta estuary and watershed (Bay-Delta). The formation, fate, and transport of methylmercury (MeHg), a particularly toxic organic form of Hg that readily bioaccumulates in wildlife, has been studied extensively throughout the system. However, there is widespread recognition of the need for more comprehensive monitoring...
Assessment of environmental impacts of mercury treatability test using suction dredging, South Yuba River
The goals of the BLM suction dredging treatability study are to (1) assess the effectiveness of suction dredging in removing mercury from the environment and (2) assess potential impacts of suction dredging with regard to discharging mercury-contaminated suspended sediment to the aquatic environment.
Mercury and Dissolved Organic Matter in Delta Wetlands
Between 1860 and 1914, hydraulic mining activities sent more than 800,000,000 cubic yards of mercury-laden sediment into the Delta altering the landscape, water flows, and contributing to the leveeing and reclamation of the Delta's marshes. Transport of mercury from historic mining areas continues today. The sedimentary supply of mercury to the Delta and in Delta sediments (cinnabar, metacinnabar...
A Non-Point Source Of Contaminants To The Estuarine Food Web: Mobilized Particles From The Intertidal Zone
The San Francisco Bay and Sacramento-San Joaquin Delta (Bay-Delta) region is a highly urbanized and contaminated estuary with a valuable commercial and recreational fishery (Nichlos et al., 1986; SFEI, 2004). Many fish and birds in the San Francisco Estuary exhibit high levels of contaminants (metals and organic pollutants), which have been shown to affect their behavior and reproductive success...
Methylmercury cycling and export from agricultural and natural wetlands in the Yolo Bypass
The purpose of the work conducted by the USGS California Water Science Center is to help guide Yolo Wildlife Area management practices by identifying the relationships between management effects on dissolved organic matter properties and the resulting role of dissolved organic matter in mercury methylation and biotic uptake measured by the cooperating USGS scientists. The information gathered will...
Investigation of Linkages Between Management Practices Used in Sacramento-San Joaquin Delta Rice Production and Loads of Dissolved Organic Matter and Disinfection Byproduct Precursors
The primary objective of this study is to expand our current understanding of how to manage rice production in the Sacramento-San Joaquin Delta in a manner that minimizes loads of water quality contaminants to Delta waters.
Evaluating coagulation techniques to reduce the transport of Hg from mine-affected and active geothermal Hg-source watersheds
Our objective is to determine the effectiveness of coagulation and adsorption techniques in removing mercury from contaminated surface waters of the Cache Creek watershed.
Assessment of methyl mercury (MeHg) release from sediment formed in wetland treatment cells designed to remove mercury from surface waters using in situ coagulation
Our objective is to determine the relative propensity of sediment material formed under two different in situ coagulation treatments (iron sulfate, polyaluminum chloride) to release MeHg into surface waters under environmentally relevant conditions that may affect flocculant stability and MeHg production rates.
Monitoring Mercury and Methylmercury in Water, Sediment and Biota in Combie Reservoir Before and After Dredging and Mercury Removal
Dredging to maintain water storage capacity by the Nevada Irrigation District (NID) occurred at Lake Combie reservoir, one of several reservoirs along the Bear River, California over the past 40 years on an as-needed basis to maintain water storage capacity. Maintenance dredging operations were halted by the Central Valley Regional Water Quality Control Board (CVRWQCB) in 2002 because of elevated...
Mercury cycling, bioaccumulation, and risk across western North America: a landscape scale synthesis linking long-term datasets
Mercury (Hg) is a serious environmental problem that is impacting ecological and human health on a global scale. However, local and regional processes are largely responsible for producing methylmercury, which drives ecological risk. This is particularly true in western North America where the combination of diverse landscapes, habitat types, climates, and Hg sources may disproportionally impact t
Filter Total Items: 20
2022 Organic Matter Research Lab Sacramento, California Vectorized Fluorescence Data
The U.S. Geological Survey (USGS) California Water Science Center (CAWSC) Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic
2022 Organic Matter Research Lab Sacramento, California Full Spectra Absorbance Data
The U.S. Geological Survey (USGS) California Water Science Center (CAWSC) Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic
Laboratory optical measurements in support of assessing PFAS enrichment in natural foams on surface waters within the Delaware River Basin
One phenomenon that has been shown to concentrate and release per- and polyfluoroalkyl substances (PFAS) in surface water is the formation of natural foams. For surface water foams to form, surface active compounds or surfactants must be present in the water along with a source of gas bubbles. Some examples of surface-active compounds include humic and fulvic acids, colloidal particles, and lipids
Longitudinal assessment of per- and polyfluoroalkyl substances and co-occurring inorganic and organic contaminants in Neshaminy Creek, Pennsylvania, November 2021
Per- and polyfluoroalkyl substances (PFAS) and co-occurring inorganic and organic contaminants are widely distributed in the environment and understanding their surface water sources is critical for water resource management. In November 2021, 13 sites were sampled along a stream reach in the Neshaminy Creek basin in southeastern Pennsylvania utilizing a time of travel sampling approach. The reach
Laboratory Optical Measurements From Discrete Surface Water Samples Collected During Water Quality Mapping Campaigns on the Illinois Waterway and Chicago Area Waterway Systems
Fluorescence and absorbance spectra were measured in discrete surface water samples collected during three sampling campaigns (Nov 2022, Mar/Apr 2023, Jul 2023) on the Illinois Waterway (IWW) and Chicago Area Waterway System (CAWS), which are the primary drainage of the Illinois River Basin (IRB). Water sampling was conducted concurrently with a boat-based water quality mapping effort using the Fa
Stability testing results for stock solutions to standardize calibration of field fluorescence sensors
Optical sensors measuring fluorescence of dissolved organic matter (fDOM) are increasingly used in water quality studies because they provide proxy measurements for a variety of contaminants and constituents of concern including metals and wastewater effluent. Similarly, sensors measuring fluorescence of chlorophyll (fChl) and phycocyanin (fPC) have gained popularity to measure phytoplankton conce
Optical measurements for surface water samples collected within the Neshaminy Creek basin during November 2021
Here we report optical data collected as part of a collaborative study between USGS Pennsylvania Water Science Center, Pennsylvania Department of Environmental Protection and Water Mission Area Proxies Project. The optical measurements reported here were collected to aide in the characterization of water sources and mixtures and establish proxies (surrogates) for per- and poly-fluorinated alkyl su
Aqueous and solid phases partitioning of elemental constituents associated with Marcellus Shale Energy and Environment Laboratory (MSEEL) gas well produced wastewater, Morgantown, WV, 2016 - 2019
The Marcellus Shale Energy and Environment Laboratory (MSEEL) site is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The
Laboratory fluorescence and total dissolved nitrogen measurements for surface water samples collected from the Rio Grande during a 24-hr time period near Albuquerque, New Mexico
Here, we present data supporting temporal variability and sources of PFAS in the Rio Grande through an arid urban area using high-frequency sampling and novel samplers. Data are compiled into two tables: 1) full fluorescence spectra in vectorized format, and 2) summary file of concentrations of total dissolved nitrogen and commonly extracted field-based sensor arrays. Data are reported from two si
Fluorescence sensor measurements in sediment suspensions to evaluate turbidity corrections
The use of field-deployable fluorescence sensors to better understand dissolved organic matter concentrations and composition has grown immensely in recent years. Applications of these sensors to critical monitoring efforts have also grown to encompass post-fire monitoring, wastewater tracking, and use as a proxy for various contaminants. Despite the growth, it is well known that these sensors are
Comparisons from an Aqualog Fluorometer Standardized to Quinine Sulfate Equivalents (QSE) with Excitation (ex) and Emissions (em) Equivalent to Fluorescence of Dissolved Organic Matter (fDOM) Sensors from Multiple Manufacturers
Here, we present the results supporting Table 2 in Field Techniques for Fluorescence Measurements Targeting Dissolved Organic Matter, Hydrocarbons, and Wastewater in Environmental Waters: Principles and Guidelines for Instrument Selection, Operation and Maintenance, Quality Assurance, and Data Reporting. Table 2 shows comparisons from an Aqualog 800 benchtop fluorometer standardized to quinine sul
2021 Organic Matter Research Lab Vectorized Fluorescence Data
The USGS CAWSC Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic matter (DOM) composition, and can also serve as proxies for
Filter Total Items: 37
Temporal variability and sources of PFAS in the Rio Grande, New Mexico through an arid urban area using multiple tracers and high-frequency sampling
Per- and polyfluoroalkyl substances (PFAS) are ubiquitous in the environment but sources are not well defined for temporal and spatial aspects within an urban environment, and especially for an arid urban environment subject to seasonal short term high-intensity precipitation events. A focused diel sampling was conducted in the summer of 2021 to assess the temporal and spatial variability of PFAS
Authors
Kimberly R. Beisner, Rebecca E. Travis, David Alvarez, Larry B. Barber, Jacob Fleck, Jeramy Roland Jasmann
Influence of irrigation water and soil on annual mercury dynamics in Sacramento Valley rice fields
Methylmercury (MeHg) is a human and environmental toxin produced in flooded soils. Little is known about MeHg in rice (Oryza Sativa L.) fields in Sacramento Valley, California. The objectives of this study were to quantify mercury fractions in irrigation water and within rice fields and to determine their mercury pools in surface water, soil, and grain. Soil, grain, and surface water (dissolved an
Authors
Luke A. Salvato, Mark C. Marvin-DiPasquale, Jacob Fleck, Stephen A. McCord, Bruce A. Linquist
Field techniques for fluorescence measurements targeting dissolved organic matter, hydrocarbons, and wastewater in environmental waters: Principles and guidelines for instrument selection, operation and maintenance, quality assurance, and data reporting
The use of field deployable fluorescence sensors by the U.S. Geological Survey has become increasingly common for a wide variety of surface water and groundwater investigations. This report addresses field deployable fluorometers that measure the fluorescence response of various substances in water exposed to incident light generated by the sensor. An introduction to the basic principles of field
Authors
Amanda Booth, Jacob Fleck, Brian A. Pellerin, Angela Hansen, Alexandra Etheridge, Guy M. Foster, Jennifer L. Graham, Brian A. Bergamaschi, Kurt D. Carpenter, Bryan D. Downing, Stewart A. Rounds, JohnFranco Saraceno
Wetland management strategy to reduce mercury export in water and bioaccumulation in fish
Wetland environments provide numerous ecosystem services but also facilitate methylmercury (MeHg) production and bioaccumulation. We developed a wetland‐management technique to reduce MeHg concentrations in wetland fish and water. We physically modified seasonal wetlands by constructing open‐ and deep‐water treatment cells at the downstream end of seasonal wetlands to promote naturally occurring M
Authors
Joshua T. Ackerman, Jacob Fleck, Collin A. Eagles-Smith, Mark C. Marvin-DiPasquale, Lisamarie Windham-Myers, Mark P. Herzog, Harry L. McQuillen
Coagulant and sorbent efficacy in removing mercury from surface waters in the Cache Creek watershed, California
Cache Creek drains part of northern California’s Coast Ranges and is an important source of mercury (Hg) to the Sacramento–San Joaquin Delta. Cache Creek is contaminated with Hg from several sources, including historical Hg and gold mines, native Hg in the soils, and active mineral springs. In laboratory experiments in a study conducted by the U.S. Geological Survey, in cooperation with the U.S. E
Authors
Erica R. De Parsia, Jacob A. Fleck, David P. Krabbenhoft, Kim Hoang, David Roth, Paul Randall
Geochemical data for water, streambed sediment, and fish tissue from the Sierra Nevada Mercury Impairment Project, 2011–12
This report presents geochemical data for surface water, streambed sediment, and fish tissue samples collected during low-flow conditions in 20 to 24 Sierra Nevada streams during 2011 and 2012. The dataset is part of a larger study designed to assess the factors that control mercury concentrations in fish tissue and to develop a model that predicts mercury concentration in the tissue of selected f
Authors
Elizabeth B. Stumpner, Charles N. Alpers, Mark C. Marvin-DiPasquale, Jennifer L. Agee, Evangelos Kakouros, Michelle R. Arias, Le H. Kieu, David A. Roth, Darrell G. Slotton, Jacob A. Fleck
Procedures for using the Horiba Scientific Aqualog® fluorometer to measure absorbance and fluorescence from dissolved organic matter
Advances in spectroscopic techniques have led to an increase in the use of optical measurements (absorbance and fluorescence) to assess dissolved organic matter composition and infer sources and processing. Although optical measurements are easy to make, they can be affected by many variables rendering them less comparable, including by inconsistencies in sample collection (for example, filter por
Authors
Angela M. Hansen, Jacob Fleck, Tamara E. C. Kraus, Bryan D. Downing, Travis von Dessonneck, Brian A. Bergamaschi
Methylmercury dynamics in Upper Sacramento Valley rice fields with low background soil mercury levels
Few studies have considered how methylmercury (MeHg, a toxic form of Hg produced in anaerobic soils) production in rice (Oryza sativa L.) fields can affect water quality, and little is known about MeHg dynamics in rice fields. Surface water MeHg and total Hg (THg) imports, exports, and storage were studied in two commercial rice fields in the Sacramento Valley, California, where soil THg was low (
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Mark C. Marvin-DiPasquale, Jacob Fleck, Kenneth W. Tate, Bruce A. Linquist
Mercury on a landscape scale—Balancing regional export with wildlife health
The Cosumnes River watershed requires a 57–64 percent reduction in loads to meet the new Delta methylmercury (MeHg) total maximum daily load allocation, established by the Central Valley Regional Water Quality Control Board. Because there are no large point sources of MeHg in the watershed, the focus of MeHg load reductions will fall upon non-point sources, particularly the expansive wetlands cons
Authors
Mark C. Marvin-DiPasquale, Lisamarie Windham-Myers, Jacob A. Fleck, Joshua T. Ackerman, Collin A. Eagles-Smith, Harry McQuillen
Alternate wetting and drying decreases methylmercury in flooded rice (Oryza sativa) systems
In flooded soils, including those found in rice (Oryza sativa L.) fields, microbes convert inorganic Hg to more toxic methylmercury (MeHg). Methylmercury is accumulated in rice grain, potentially affecting health. Methylmercury in rice field surface water can bioaccumulate in wildlife. We evaluated how introducing aerobic periods into an otherwise continuously flooded rice growing season affects M
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Mark C. Marvin-DiPasquale, Jacob Fleck, Bruce A. Linquist
The contribution of rice agriculture to methylmercury in surface waters: A review of data from the Sacramento Valley, California
Methylmercury (MeHg) is a bioaccumulative pollutant produced in and exported from flooded soils, including those used for rice (Oriza sativa L.) production. Using unfiltered aqueous MeHg data from MeHg monitoring programs in the Sacramento River watershed from 1996 to 2007, we assessed the MeHg contribution from rice systems to the Sacramento River. Using a mixed-effects regression analysis, we co
Authors
K. Christy Tanner, Lisamarie Windham-Myers, Jacob Fleck, Kenneth W. Tate, Stephen A. McCord, Bruce A. Linquist
Mercury and methylmercury in aquatic sediment across western North America
Large-scale assessments are valuable in identifying primary factors controlling total mercury (THg) and monomethyl mercury (MeHg) concentrations, and distribution in aquatic ecosystems. Bed sediment THg and MeHg concentrations were compiled for > 16,000 samples collected from aquatic habitats throughout the West between 1965 and 2013. The influence of aquatic feature type (canals, estuaries, lakes
Authors
Jacob Fleck, Mark C. Marvin-DiPasquale, Collin A. Eagles-Smith, Joshua T. Ackerman, Michelle A. Lutz, Michael T. Tate, Charles N. Alpers, Britt D. Hall, David P. Krabbenhoft, Chris S. Eckley
By
Ecosystems Mission Area, Water Resources Mission Area, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Forest and Rangeland Ecosystem Science Center, John Wesley Powell Center for Analysis and Synthesis, Upper Midwest Water Science Center, Mercury Research Laboratory