Science and Products
Filter Total Items: 20
Uptake of per- and polyfluoroalkyl substances by fish, mussel, and passive samplers in mobile laboratory exposures using groundwater from a contamination plume at a historical fire training area, Cape Cod, Massachusetts
Aqueous film-forming foams historically were used during fire training activities on Joint Base Cape Cod, Massachusetts, and created an extensive per- and polyfluoroalkyl substances (PFAS) groundwater contamination plume. The potential for PFAS bioconcentration from exposure to the contaminated groundwater, which discharges to surface water bodies, was assessed with mobile-laboratory experiments u
Authors
Larry Barber, Heidi M. Pickard, David Alvarez, Jitka Becanova, Steffanie H. Keefe, Denis R. LeBlanc, Rainer Lohmann, Jeffery A. Steevens, Alan M. Vajda
Wastewater reuse and predicted ecological risk posed by contaminant mixtures in Potomac River watershed streams
A wastewater model was applied to the Potomac River watershed to provide (i) a means to identify streams with a high likelihood of carrying elevated effluent-derived contaminants and (ii) risk assessments to aquatic life and drinking water. The model linked effluent discharges along stream networks, accumulated wastewater, and predicted contaminant loads of municipal wastewater constituents while
Authors
Kaycee E. Faunce, Larry Barber, Steffanie H. Keefe, Jeramy Jasmann, Jennifer L. Krstolic
Watershed-scale risk to aquatic organisms from complex chemical mixtures in the Shenandoah River
River waters contain complex chemical mixtures derived from natural and anthropogenic sources. Aquatic organisms are exposed to the entire chemical composition of the water, resulting in potential effects at the organismal through ecosystem level. This study applied a holistic approach to assess landscape, hydrological, chemical, and biological variables. On-site mobile laboratory experiments were
Authors
Larry Barber, Kaycee E. Faunce, David Bertolatus, Michelle Hladik, Jeramy Jasmann, Steffanie H. Keefe, Dana W. Kolpin, Michael T. Meyer, Jennifer L. Rapp, David A. Roth, Alan M. Vajda
Urban stormwater: An overlooked pathway of extensive mixed contaminants to surface and groundwaters in the United States
Increasing global reliance on stormwater control measures to reduce discharge to surface water, increase groundwater recharge, and minimize contaminant delivery to receiving waterbodies necessitates improved understanding of stormwater-contaminant profiles. A multi-agency study of organic and inorganic chemicals in urban stormwater from 50 runoff events at 21 sites across the United States demonst
Authors
Jason R. Masoner, Dana W. Kolpin, Isabelle M. Cozzarelli, Larry B. Barber, D.S. Burden, William T. Foreman, Kenneth J. Forshay, Edward Furlong, Justin F. Groves, Michelle Hladik, Matthew E. Hopton, Jeanne B. Jaeschke, Steffanie H. Keefe, David Krabbenhoft, Richard Lowrance, Kristin Romanok, David L. Rus, William R. Selbig, Brad Williams, Paul Bradley
By
Water Resources Mission Area, Contaminant Biology, Science Analytics and Synthesis (SAS) Program, Toxic Substances Hydrology, California Water Science Center, Central Midwest Water Science Center, New Jersey Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Environmental Sciences Center, Upper Midwest Water Science Center, Reston Biogeochemical Processes in Groundwater Laboratory
Integrated assessment of wastewater reuse, exposure risk, and fish endocrine disruption in the Shenandoah River watershed
Reuse of municipal and industrial wastewater treatment plant (WWTP) effluent is an important component in augmenting global freshwater supplies. The Shenandoah River Watershed was selected to conduct on-site exposure experiments to assess endocrine disrupting characteristics of different source waters. This investigation of the Shenandoah River Watershed integrates WWTP wastewater reuse modeling,
Authors
Larry Barber, Jennifer L. Krstolic, Chintamani Kandel, Steffanie H. Keefe, Jacelyn Rice, Paul Westerhoff, David Bertolatus, Alan M. Vajda
Effects of an extreme flood on trace elements in river water—From urban stream to major river basin
Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the Sou
Authors
Larry B. Barber, Suzanne Paschke, William A. Battaglin, Chris Douville, Kevin C. Fitzgerald, Steffanie H. Keefe, David A. Roth, Alan M. Vajda
Understanding the hydrologic impacts of wastewater treatment plant discharge to shallow groundwater: Before and after plant shutdown
Effluent-impacted surface water has the potential to transport not only water, but wastewater-derived contaminants to shallow groundwater systems. To better understand the effects of effluent discharge on in-stream and near-stream hydrologic conditions in wastewater-impacted systems, water-level changes were monitored in hyporheic-zone and shallow-groundwater piezometers in a reach of Fourmile Cre
Authors
Laura E. Hubbard, Steffanie H. Keefe, Dana W. Kolpin, Larry B. Barber, Joseph W. Duris, Kasey J. Hutchinson, Paul M. Bradley
Pre/post-closure assessment of groundwater pharmaceutical fate in a wastewater‑facility-impacted stream reach
Pharmaceutical contamination of contiguous groundwater is a substantial concern in wastewater-impacted streams, due to ubiquity in effluent, high aqueous mobility, designed bioactivity, and to effluent-driven hydraulic gradients. Wastewater treatment facility (WWTF) closures are rare environmental remediation events; offering unique insights into contaminant persistence, long-term wastewater impac
Authors
Paul M. Bradley, Larry B. Barber, Jimmy M. Clark, Joseph W. Duris, William T. Foreman, Edward T. Furlong, Carrie E. Givens, Laura E. Hubbard, Kasey J. Hutchinson, Celeste A. Journey, Steffanie H. Keefe, Dana W. Kolpin
Riverbank filtration potential of pharmaceuticals in a wastewater-impacted stream
Pharmaceutical contamination of shallow groundwater is a substantial concern in effluent-dominated streams, due to high aqueous mobility, designed bioactivity, and effluent-driven hydraulic gradients. In October and December 2012, effluent contributed approximately 99% and 71%, respectively, to downstream flow in Fourmile Creek, Iowa, USA. Strong hydrologic connectivity was observed between surfac
Authors
Paul M. Bradley, Larry B. Barber, Joseph W. Duris, William T. Foreman, Edward T. Furlong, Laura E. Hubbard, Kasey J. Hutchinson, Steffanie H. Keefe, Dana W. Kolpin
Persistence and potential effects of complex organic contaminant mixtures in wastewater-impacted streams
Natural and synthetic organic contaminants in municipal wastewater treatment plant (WWTP) effluents can cause ecosystem impacts, raising concerns about their persistence in receiving streams. In this study, Lagrangian sampling, in which the same approximate parcel of water is tracked as it moves downstream, was conducted at Boulder Creek, Colorado and Fourmile Creek, Iowa to determine in-stream tr
Authors
Larry B. Barber, Steffanie H. Keefe, Greg K. Brown, Edward T. Furlong, James L. Gray, Dana W. Kolpin, Michael T. Meyer, Mark W. Sandstrom, Steven D. Zaugg
Groundwater-quality data for a treated-wastewater plume near the Massachusetts Military Reservation, Ashumet Valley, Cape Cod, Massachusetts, 2006-08
A plume of contaminated groundwater extends from former disposal beds at the Massachusetts Military Reservation's wastewater-treatment plant toward Ashumet Pond, coastal ponds, and Vineyard Sound, Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to the rapid-infiltration beds for nearly 60 years before the disposal site was moved to a different location in December 1995. W
Authors
Jennifer G. Savoie, Denis R. LeBlanc, Gillian M. Fairchild, Richard L. Smith, Douglas B. Kent, Larry B. Barber, Deborah A. Repert, Charles P. Hart, Steffanie H. Keefe, Luke A. Parsons
Fate of 4-nonylphenol and 17β-estradiol in the Redwood River of Minnesota
The majority of previous research investigating the fate of endocrine-disrupting compounds has focused on single processes generally in controlled laboratory experiments, and limited studies have directly evaluated their fate and transport in rivers. This study evaluated the fate and transport of 4-nonylphenol, 17β-estradiol, and estrone in a 10-km reach of the Redwood River in southwestern Minnes
Authors
Jeffrey H. Writer, Joseph N. Ryan, Steffanie H. Keefe, Larry B. Barber
Unique Approach to Measure Per- and Polyfluoroalkyl Substances Uptake in Fish, Mussels, and Passive Samplers
Per- and polyfluoroalkyl substances (PFAS) uptake and bioconcentration by fish and mussels ─ housed in mobile laboratories at a legacy fire-training area contaminated by aqueous film-forming foams ─ varied by species, sex, and compound. PFAS in passive samplers deployed at the same time mimicked uptake by fish but not mussels indicating that passive samplers might prove useful as screening tools...
Uptake of Per- and Polyfluoroalkyl Substances by Fish, Mussel, and Passive Samplers in Mobile Laboratory Exposures using Groundwater from a Contamination Plume at a Historical Fire Training Area, Cape Cod, Massachusetts - Chemical and Biological Data from
This data release presents chemical and biological results from an investigation of the uptake of per- and polyfluoroalkyl substances (PFAS) from groundwater contaminated by fire training activities on Cape Cod, Massachusetts. Exposure experiments were conducted from August 29 to September 21, 2018 using groundwater from a relatively uncontaminated reference site and a fire training area contamina
Potomac River Watershed Accumulated Wastewater Ratios and Predicted Environmental Concentrations
Treated effluent from wastewater treatment plants (WWTPs) contains contaminants not fully removed during the treatment process and that may pose environmental health risks when discharged to surface waters. This data release presents inputs for and results from a wastewater reuse model that used data compiled from several sources to calculate the following estimates for each non-tidal, non-coastli
Chemical Data From 40 Years of Monitoring a Treated-Wastewater Groundwater Plume in a Sand and Gravel Aquifer, Cape Cod, Massachusetts, 1978-2018
This U.S. Geological Survey data release provides a comprehensive dataset of water-quality data and sampling-site characteristics collected in 1978-2018 during a study of the effects of land disposal of treated wastewater on groundwater quality in an unconsolidated sand and gravel aquifer on Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to rapid-infiltration beds at Joi
Assessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic c
Concentrations and associated method information for trace and major elements in Fourmile Creek near Ankeny, Iowa, USA during the 2011-2014 wastewater treatment facility pre/post-closure assessment
Dataset includes trace and rare earth element concentration data as well as water level elevation data in select groundwater piezometers recorded in 10 minute intervals during the period October 2011 to October 2014. Latitude and longitude data are provided for groundwater piezometer locations.
This data release supports the following publication:
Keefe, S.H., L.E. Hubbard, L.B. Barber, P
Survey of major and trace elements in stormwater runoff from across the United States, 2016 to 2017
This study focuses on providing a broad-scale assessment of composition of water chemistry in urban stormwater runoff. The stormwater runoff is a source of recharge to groundwater by Green Infrastructure (GI) practices or it may become a source of recharge to groundwater to reduce stormwater volumes to surface waters or augment groundwater supply. The chemical composition of the stormwater runoff
Science and Products
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Filter Total Items: 20
Uptake of per- and polyfluoroalkyl substances by fish, mussel, and passive samplers in mobile laboratory exposures using groundwater from a contamination plume at a historical fire training area, Cape Cod, Massachusetts
Aqueous film-forming foams historically were used during fire training activities on Joint Base Cape Cod, Massachusetts, and created an extensive per- and polyfluoroalkyl substances (PFAS) groundwater contamination plume. The potential for PFAS bioconcentration from exposure to the contaminated groundwater, which discharges to surface water bodies, was assessed with mobile-laboratory experiments uAuthorsLarry Barber, Heidi M. Pickard, David Alvarez, Jitka Becanova, Steffanie H. Keefe, Denis R. LeBlanc, Rainer Lohmann, Jeffery A. Steevens, Alan M. VajdaWastewater reuse and predicted ecological risk posed by contaminant mixtures in Potomac River watershed streams
A wastewater model was applied to the Potomac River watershed to provide (i) a means to identify streams with a high likelihood of carrying elevated effluent-derived contaminants and (ii) risk assessments to aquatic life and drinking water. The model linked effluent discharges along stream networks, accumulated wastewater, and predicted contaminant loads of municipal wastewater constituents whileAuthorsKaycee E. Faunce, Larry Barber, Steffanie H. Keefe, Jeramy Jasmann, Jennifer L. KrstolicWatershed-scale risk to aquatic organisms from complex chemical mixtures in the Shenandoah River
River waters contain complex chemical mixtures derived from natural and anthropogenic sources. Aquatic organisms are exposed to the entire chemical composition of the water, resulting in potential effects at the organismal through ecosystem level. This study applied a holistic approach to assess landscape, hydrological, chemical, and biological variables. On-site mobile laboratory experiments wereAuthorsLarry Barber, Kaycee E. Faunce, David Bertolatus, Michelle Hladik, Jeramy Jasmann, Steffanie H. Keefe, Dana W. Kolpin, Michael T. Meyer, Jennifer L. Rapp, David A. Roth, Alan M. VajdaUrban stormwater: An overlooked pathway of extensive mixed contaminants to surface and groundwaters in the United States
Increasing global reliance on stormwater control measures to reduce discharge to surface water, increase groundwater recharge, and minimize contaminant delivery to receiving waterbodies necessitates improved understanding of stormwater-contaminant profiles. A multi-agency study of organic and inorganic chemicals in urban stormwater from 50 runoff events at 21 sites across the United States demonstAuthorsJason R. Masoner, Dana W. Kolpin, Isabelle M. Cozzarelli, Larry B. Barber, D.S. Burden, William T. Foreman, Kenneth J. Forshay, Edward Furlong, Justin F. Groves, Michelle Hladik, Matthew E. Hopton, Jeanne B. Jaeschke, Steffanie H. Keefe, David Krabbenhoft, Richard Lowrance, Kristin Romanok, David L. Rus, William R. Selbig, Brad Williams, Paul BradleyByWater Resources Mission Area, Contaminant Biology, Science Analytics and Synthesis (SAS) Program, Toxic Substances Hydrology, California Water Science Center, Central Midwest Water Science Center, New Jersey Water Science Center, Oklahoma-Texas Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Environmental Sciences Center, Upper Midwest Water Science Center, Reston Biogeochemical Processes in Groundwater LaboratoryIntegrated assessment of wastewater reuse, exposure risk, and fish endocrine disruption in the Shenandoah River watershed
Reuse of municipal and industrial wastewater treatment plant (WWTP) effluent is an important component in augmenting global freshwater supplies. The Shenandoah River Watershed was selected to conduct on-site exposure experiments to assess endocrine disrupting characteristics of different source waters. This investigation of the Shenandoah River Watershed integrates WWTP wastewater reuse modeling,AuthorsLarry Barber, Jennifer L. Krstolic, Chintamani Kandel, Steffanie H. Keefe, Jacelyn Rice, Paul Westerhoff, David Bertolatus, Alan M. VajdaEffects of an extreme flood on trace elements in river water—From urban stream to major river basin
Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the SouAuthorsLarry B. Barber, Suzanne Paschke, William A. Battaglin, Chris Douville, Kevin C. Fitzgerald, Steffanie H. Keefe, David A. Roth, Alan M. VajdaUnderstanding the hydrologic impacts of wastewater treatment plant discharge to shallow groundwater: Before and after plant shutdown
Effluent-impacted surface water has the potential to transport not only water, but wastewater-derived contaminants to shallow groundwater systems. To better understand the effects of effluent discharge on in-stream and near-stream hydrologic conditions in wastewater-impacted systems, water-level changes were monitored in hyporheic-zone and shallow-groundwater piezometers in a reach of Fourmile CreAuthorsLaura E. Hubbard, Steffanie H. Keefe, Dana W. Kolpin, Larry B. Barber, Joseph W. Duris, Kasey J. Hutchinson, Paul M. BradleyPre/post-closure assessment of groundwater pharmaceutical fate in a wastewater‑facility-impacted stream reach
Pharmaceutical contamination of contiguous groundwater is a substantial concern in wastewater-impacted streams, due to ubiquity in effluent, high aqueous mobility, designed bioactivity, and to effluent-driven hydraulic gradients. Wastewater treatment facility (WWTF) closures are rare environmental remediation events; offering unique insights into contaminant persistence, long-term wastewater impacAuthorsPaul M. Bradley, Larry B. Barber, Jimmy M. Clark, Joseph W. Duris, William T. Foreman, Edward T. Furlong, Carrie E. Givens, Laura E. Hubbard, Kasey J. Hutchinson, Celeste A. Journey, Steffanie H. Keefe, Dana W. KolpinRiverbank filtration potential of pharmaceuticals in a wastewater-impacted stream
Pharmaceutical contamination of shallow groundwater is a substantial concern in effluent-dominated streams, due to high aqueous mobility, designed bioactivity, and effluent-driven hydraulic gradients. In October and December 2012, effluent contributed approximately 99% and 71%, respectively, to downstream flow in Fourmile Creek, Iowa, USA. Strong hydrologic connectivity was observed between surfacAuthorsPaul M. Bradley, Larry B. Barber, Joseph W. Duris, William T. Foreman, Edward T. Furlong, Laura E. Hubbard, Kasey J. Hutchinson, Steffanie H. Keefe, Dana W. KolpinPersistence and potential effects of complex organic contaminant mixtures in wastewater-impacted streams
Natural and synthetic organic contaminants in municipal wastewater treatment plant (WWTP) effluents can cause ecosystem impacts, raising concerns about their persistence in receiving streams. In this study, Lagrangian sampling, in which the same approximate parcel of water is tracked as it moves downstream, was conducted at Boulder Creek, Colorado and Fourmile Creek, Iowa to determine in-stream trAuthorsLarry B. Barber, Steffanie H. Keefe, Greg K. Brown, Edward T. Furlong, James L. Gray, Dana W. Kolpin, Michael T. Meyer, Mark W. Sandstrom, Steven D. ZauggGroundwater-quality data for a treated-wastewater plume near the Massachusetts Military Reservation, Ashumet Valley, Cape Cod, Massachusetts, 2006-08
A plume of contaminated groundwater extends from former disposal beds at the Massachusetts Military Reservation's wastewater-treatment plant toward Ashumet Pond, coastal ponds, and Vineyard Sound, Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to the rapid-infiltration beds for nearly 60 years before the disposal site was moved to a different location in December 1995. WAuthorsJennifer G. Savoie, Denis R. LeBlanc, Gillian M. Fairchild, Richard L. Smith, Douglas B. Kent, Larry B. Barber, Deborah A. Repert, Charles P. Hart, Steffanie H. Keefe, Luke A. ParsonsFate of 4-nonylphenol and 17β-estradiol in the Redwood River of Minnesota
The majority of previous research investigating the fate of endocrine-disrupting compounds has focused on single processes generally in controlled laboratory experiments, and limited studies have directly evaluated their fate and transport in rivers. This study evaluated the fate and transport of 4-nonylphenol, 17β-estradiol, and estrone in a 10-km reach of the Redwood River in southwestern MinnesAuthorsJeffrey H. Writer, Joseph N. Ryan, Steffanie H. Keefe, Larry B. Barber - Science
Unique Approach to Measure Per- and Polyfluoroalkyl Substances Uptake in Fish, Mussels, and Passive Samplers
Per- and polyfluoroalkyl substances (PFAS) uptake and bioconcentration by fish and mussels ─ housed in mobile laboratories at a legacy fire-training area contaminated by aqueous film-forming foams ─ varied by species, sex, and compound. PFAS in passive samplers deployed at the same time mimicked uptake by fish but not mussels indicating that passive samplers might prove useful as screening tools... - Data
Uptake of Per- and Polyfluoroalkyl Substances by Fish, Mussel, and Passive Samplers in Mobile Laboratory Exposures using Groundwater from a Contamination Plume at a Historical Fire Training Area, Cape Cod, Massachusetts - Chemical and Biological Data from
This data release presents chemical and biological results from an investigation of the uptake of per- and polyfluoroalkyl substances (PFAS) from groundwater contaminated by fire training activities on Cape Cod, Massachusetts. Exposure experiments were conducted from August 29 to September 21, 2018 using groundwater from a relatively uncontaminated reference site and a fire training area contaminaPotomac River Watershed Accumulated Wastewater Ratios and Predicted Environmental Concentrations
Treated effluent from wastewater treatment plants (WWTPs) contains contaminants not fully removed during the treatment process and that may pose environmental health risks when discharged to surface waters. This data release presents inputs for and results from a wastewater reuse model that used data compiled from several sources to calculate the following estimates for each non-tidal, non-coastliChemical Data From 40 Years of Monitoring a Treated-Wastewater Groundwater Plume in a Sand and Gravel Aquifer, Cape Cod, Massachusetts, 1978-2018
This U.S. Geological Survey data release provides a comprehensive dataset of water-quality data and sampling-site characteristics collected in 1978-2018 during a study of the effects of land disposal of treated wastewater on groundwater quality in an unconsolidated sand and gravel aquifer on Cape Cod, Massachusetts. Treated sewage-derived wastewater was discharged to rapid-infiltration beds at JoiAssessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic cConcentrations and associated method information for trace and major elements in Fourmile Creek near Ankeny, Iowa, USA during the 2011-2014 wastewater treatment facility pre/post-closure assessment
Dataset includes trace and rare earth element concentration data as well as water level elevation data in select groundwater piezometers recorded in 10 minute intervals during the period October 2011 to October 2014. Latitude and longitude data are provided for groundwater piezometer locations. This data release supports the following publication: Keefe, S.H., L.E. Hubbard, L.B. Barber, PSurvey of major and trace elements in stormwater runoff from across the United States, 2016 to 2017
This study focuses on providing a broad-scale assessment of composition of water chemistry in urban stormwater runoff. The stormwater runoff is a source of recharge to groundwater by Green Infrastructure (GI) practices or it may become a source of recharge to groundwater to reduce stormwater volumes to surface waters or augment groundwater supply. The chemical composition of the stormwater runoff