Per- and polyfluoroalkyl substances (PFAS) are a diverse group of over 4,000 different compounds. Since the 1940s, PFAS have been manufactured and used around the globe, including in the United States. PFAS are resistant to chemical and thermal breakdown and impart stain and water-resistance properties, making them useful for a variety of commercial applications, but also persistent in the environment. Many PFAS are surfactants and can be a constituent of aqueous film-forming foams used to fight hydrocarbon fires. PFAS have been used in nonstick coatings for consumer products (water-repellent fabrics, food packaging, nonstick cooking surfaces) and in industrial activities including metal plating and fluoropolymer and plastic production, among others. PFAS are very persistent in the environment, and some PFAS are known to accumulate over time in the human body and in the food chain. Exposure to some PFAS has been linked to adverse human and ecosystem health effects.
Activities in the New England Water Science Center (WSC) span research on fate, transport, exposure, and effects of PFAS. On Cape Cod, the New England WSC has a long-term research site where ongoing activities investigate the persistence and transport of PFAS and PFAS precursors, temporal trends, diverse contaminant mixtures, groundwater discharge ecosystem buffers, surface-water/groundwater interactions, sewage effects, fish impacts, and human exposure implications.
Several studies have also been undertaken to investigate PFAS in streams and soils with cooperators including the New Hampshire Department of Environmental Services and the Massachusetts Department of Environmental Protection.
The New England WSC has contributed to several regional and national USGS efforts related to PFAS, including co-authoring a publication on the USGS strategic science vision for PFAS, and large scale sampling and analysis of PFAS in groundwater.
USGS Laboratory for the Analysis of Per- and Polyfluoroalkyl Substances (PFAS)
Per-and Polyfluoroalkyl Substances (PFAS) Integrated Science Team
Advanced PFAS Measurement Methods
National Water-Quality Assessment (NAWQA)
Confirmatory Sampling for Per- and Polyfluoroalkyl Substances (PFAS) in Shallow Soils Across New Hampshire, 2022
Field-scale investigation of per- and polyfluoroalkyl substances (PFAS) leaching from shallow soils to groundwater at two sites in New Hampshire, 2021-2022
Statewide survey of shallow soil concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data across New Hampshire, 2021
Environmental and Quality-Control Data for Per- and Polyfluoroalkyl Substances (PFAS) Measured in Selected Rivers and Streams in Massachusetts, 2020 (ver. 2.0, May 2023)
Concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data at and near surface-water/groundwater boundaries on Cape Cod, Massachusetts, 2016-19
Geochemical and Geospatial Data for Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Used As a Source of Drinking Water in the Eastern United States
Poly- and perfluoalkyl substances in contaminated groundwater, Cape Cod, Massachusetts, 2014-2016
Concentrations of per- and polyfluoroalkyl substances (PFAS) in selected rivers and streams in Massachusetts, 2020
Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
Integrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Surface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations
Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along
Public and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA
Per- and polyfluoroalkyl substances (PFAS) in New Hampshire soils and biosolids
The U.S. Geological Survey, in cooperation with the New Hampshire Department of Environmental Services, is undertaking a study on per- and polyfluoroalkyl substances (PFAS) in soils and biosolids. The study will characterize PFAS concentrations in shallow soil and selected biosolids throughout the State of New Hampshire, conduct laboratory experiments to improve understanding of how mobile PFAS ar
Isolating the AFFF signature in coastal watersheds using oxidizable PFAS precursors and unexplained organofluorine
Water supplies for millions of U.S. individuals exceed maximum contaminant levels for per- and polyfluoroalkyl substances (PFAS). Contemporary and legacy use of aqueous film forming foams (AFFF) is a major contamination source. However, diverse PFAS sources are present within watersheds, making it difficult to isolate their predominant origins. Here we examine PFAS source signatures among six adja
Hillslope groundwater discharges provide localized ecosystem buffers from regional PFAS contamination in a gaining coastal stream
Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study we used a combinatio
Geochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
- Overview
Per- and polyfluoroalkyl substances (PFAS) are a diverse group of over 4,000 different compounds. Since the 1940s, PFAS have been manufactured and used around the globe, including in the United States. PFAS are resistant to chemical and thermal breakdown and impart stain and water-resistance properties, making them useful for a variety of commercial applications, but also persistent in the environment. Many PFAS are surfactants and can be a constituent of aqueous film-forming foams used to fight hydrocarbon fires. PFAS have been used in nonstick coatings for consumer products (water-repellent fabrics, food packaging, nonstick cooking surfaces) and in industrial activities including metal plating and fluoropolymer and plastic production, among others. PFAS are very persistent in the environment, and some PFAS are known to accumulate over time in the human body and in the food chain. Exposure to some PFAS has been linked to adverse human and ecosystem health effects.
New Hampshire landscape in winter. A soil sampling site at Otter Brook State Park, managed by the Army Corps of Engineers. U.S. Geological Survey hydrologic technician collects a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS). Activities in the New England Water Science Center (WSC) span research on fate, transport, exposure, and effects of PFAS. On Cape Cod, the New England WSC has a long-term research site where ongoing activities investigate the persistence and transport of PFAS and PFAS precursors, temporal trends, diverse contaminant mixtures, groundwater discharge ecosystem buffers, surface-water/groundwater interactions, sewage effects, fish impacts, and human exposure implications.
Several studies have also been undertaken to investigate PFAS in streams and soils with cooperators including the New Hampshire Department of Environmental Services and the Massachusetts Department of Environmental Protection.
The New England WSC has contributed to several regional and national USGS efforts related to PFAS, including co-authoring a publication on the USGS strategic science vision for PFAS, and large scale sampling and analysis of PFAS in groundwater.
USGS Laboratory for the Analysis of Per- and Polyfluoroalkyl Substances (PFAS)
The U.S. Geological Survey laboratory for the analysis of per- and polyfluoroalkyl substances (PFAS) uses cutting-edge techniques to analyze environmental samples including tissues, plasma, water, and soils to undertake and support research projects across the country. PFAS are emerging contaminants of concern that can be found in air, rain, lakes, rivers, groundwater, soils, and in products we use every day, like non-stick pans and popcorn bags. PFAS exposure has been associated with a variety of human and ecosystem health effects, making it very important to have good analytical methods to ensure the data is of the highest quality. This short video outlines the types of research questions the laboratory works towards addressing and briefly outlines some of the techniques employed to ensure high-quality data is generated. - Science
Per-and Polyfluoroalkyl Substances (PFAS) Integrated Science Team
Increasing scientific and public awareness of the widespread distribution of per- and poly-fluoroalkyl substances (PFAS) in U.S. drinking-water supplies, aquatic and terrestrial ecosystems, wildlife, and humans has raised many public health and resource management questions that U.S. Geological Survey's (USGS) science can inform. The USGS Environmental Health Program's PFAS Integrated Science Team...Advanced PFAS Measurement Methods
Environmental Health Program scientists, in collaboration with other USGS scientists, are developing complementary field and laboratory methods and capabilities to detect and quantify a range of target and nontarget per- and polyfluoroalkyl substances (PFAS) and indicator compounds at low levels (parts per trillion) in a variety of environmental matrices. The PFAS Integrated Science Team is...National Water-Quality Assessment (NAWQA)
Our surface water, groundwater, and aquatic ecosystems are priceless resources, used by people across the Nation for drinking, irrigation, industry, and recreation. The National Water-Quality Assessment (NAWQA) Project is a leading source of scientific data and knowledge for development of science-based policies and management strategies to improve and protect our water resources. - Data
Confirmatory Sampling for Per- and Polyfluoroalkyl Substances (PFAS) in Shallow Soils Across New Hampshire, 2022
Data for per- and polyfluoroalkyl substances (PFAS) and related chemical and physical characteristics are presented from 30 soil sampling locations within the State of New Hampshire. A total of 15 sites were chosen based on the results of sampling efforts published in Santangelo and others(2022). Sites with relatively high concentrations of PFAS observed during the first study were selected for reField-scale investigation of per- and polyfluoroalkyl substances (PFAS) leaching from shallow soils to groundwater at two sites in New Hampshire, 2021-2022
Per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data are presented from shallow soil and groundwater at two sites in New Hampshire. The two sites, the former Brentwood Fire Training Area and White Farm, were selected because materials known to contain PFAS were used at each site. White Farm is an active farm where biosolids have been applied for several years. At the fStatewide survey of shallow soil concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data across New Hampshire, 2021
Per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data are presented from 100 shallow soil sampling locations within the State of New Hampshire. Sites were randomly determined through an equal-area grid approach (Scott, 1990) targeting undisturbed areas, which included lands classified by the 2016 National Land Cover Database (Dewitz, 2019) as forested, shrubland, scrublEnvironmental and Quality-Control Data for Per- and Polyfluoroalkyl Substances (PFAS) Measured in Selected Rivers and Streams in Massachusetts, 2020 (ver. 2.0, May 2023)
This data release includes concentrations of 24 per- and polyfluoroalkyl substances (PFAS) and physical properties of water-quality samples collected by the U.S. Geological Survey (USGS) at 64 selected sites in rivers and streams in Massachusetts over three rounds of sampling. The samples were collected from August to November 2020 when streamflow conditions were below normal (also considered to bConcentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data at and near surface-water/groundwater boundaries on Cape Cod, Massachusetts, 2016-19
Groundwater, surface-water, sediment, and associated quality-control samples were collected downgradient from a former fire training area and wastewater infiltration beds on Cape Cod, Massachusetts and analyzed for per- and polyfluoroalkyl substances (PFAS). Samples were collected between July 2016 and February 2019 following U.S. Geological Survey protocols. Field parameters reported include tempGeochemical and Geospatial Data for Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Used As a Source of Drinking Water in the Eastern United States
Concentrations of inorganic constituents, dissolved organic carbon (DOC), tritium, per- and polyfluoroalkyl substances (PFAS), volatile organic compounds (VOCs), and pharmaceuticals were measured in groundwater samples collected from 254 wells in 2019 and 2020. Concentrations of inorganic constituents, DOC, VOCs, and pharmaceuticals were measured at the U.S. Geological Survey (USGS) National WatePoly- and perfluoalkyl substances in contaminated groundwater, Cape Cod, Massachusetts, 2014-2016
Drinking water health advisories for perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS), were issued by the U.S. Environmental Protection Agency in 2016 in response to growing evidence associated with negative human health effects. PFOA and PFOS are often associated with other poly- and perfluorinated alkyl substances (PFAS). There has been increasing concern for groundwater quality o - Multimedia
- Publications
Concentrations of per- and polyfluoroalkyl substances (PFAS) in selected rivers and streams in Massachusetts, 2020
Water samples collected from 27 rivers and streams in Massachusetts were analyzed to characterize the presence and concentrations of per- and polyfluoroalkyl substances (collectively known as PFAS) in surface waters across the Commonwealth. Sampling sites were selected in urban rivers where PFAS were expected to be present, such as those that receive treated municipal wastewater, and in rural riveAuthorsJennifer G. Savoie, Denise M. ArguePerfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
AuthorsPeter B. McMahon, Andrea K. Tokranov, Laura M. Bexfield, Bruce D. Lindsey, Tyler D. Johnson, Melissa Lombard, Elise WatsonIntegrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Concerns related to perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sources of drinking water and in natural and engineered environments have captured national attention over the last few decades. This report provides an overview of the science gaps that exist in the fields of study related to PFAS that are relevant to the U.S. Geological Survey mission and identifies opportunities where tAuthorsAndrea K. Tokranov, Paul M. Bradley, Michael J. Focazio, Douglas B. Kent, Denis R. LeBlanc, Jeff W. McCoy, Kelly L. Smalling, Jeffery A. Steevens, Patricia L. ToccalinoSurface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations
Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along
AuthorsAndrea K. Tokranov, Denis R. LeBlanc, Heidi M. Pickard, Bridger J. Ruyle, Larry Barber, Robert B. Hull, Elsie M. Sunderland, Chad D. VecitisPublic and private tapwater: Comparative analysis of contaminant exposure and potential risk, Cape Cod, Massachusetts, USA
BackgroundHumans are primary drivers of environmental contamination worldwide, including in drinking-water resources. In the United States (US), federal and state agencies regulate and monitor public-supply drinking water while private-supply monitoring is rare; the current lack of directly comparable information on contaminant-mixture exposures and risks between private- and public-supplies underAuthorsPaul Bradley, Denis R. LeBlanc, Kristin Romanok, Kelly Smalling, Michael J. Focazio, Mary C. Cardon, Jimmy Clark, Justin M. Conley, Nicola Evans, Carrie E Givens, James L. Gray, L. Earl Gray, Phillip C. Hartig, Christopher P. Higgins, Michelle Hladik, Luke R. Iwanowicz, Keith Loftin, R. Blaine McCleskey, Carrie A. McDonough, Elizabeth Medlock-Kakaley, Christopher P. Weis, Vickie S. WilsonByEcosystems Mission Area, Water Resources Mission Area, Contaminant Biology, Environmental Health Program, Toxic Substances Hydrology, California Water Science Center, Eastern Ecological Science Center, New England Water Science Center, New Jersey Water Science Center, South Atlantic Water Science Center (SAWSC), Upper Midwest Water Science Center, National Water Quality LaboratoryPer- and polyfluoroalkyl substances (PFAS) in New Hampshire soils and biosolids
The U.S. Geological Survey, in cooperation with the New Hampshire Department of Environmental Services, is undertaking a study on per- and polyfluoroalkyl substances (PFAS) in soils and biosolids. The study will characterize PFAS concentrations in shallow soil and selected biosolids throughout the State of New Hampshire, conduct laboratory experiments to improve understanding of how mobile PFAS ar
AuthorsAndrea K. Tokranov, Kate Emma A. Schlosser, Jeffrey M. Marts, Anthony F. Drouin, Leah M. Santangelo, Sydney M. WelchIsolating the AFFF signature in coastal watersheds using oxidizable PFAS precursors and unexplained organofluorine
Water supplies for millions of U.S. individuals exceed maximum contaminant levels for per- and polyfluoroalkyl substances (PFAS). Contemporary and legacy use of aqueous film forming foams (AFFF) is a major contamination source. However, diverse PFAS sources are present within watersheds, making it difficult to isolate their predominant origins. Here we examine PFAS source signatures among six adja
AuthorsBridger J. Ruyle, Heidi M. Pickard, Denis R. LeBlanc, Andrea K. Tokranov, Colin P. Thackray, Xindi C. Hu, Chad D. Vecitis, Elsie M. SunderlandHillslope groundwater discharges provide localized ecosystem buffers from regional PFAS contamination in a gaining coastal stream
Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study we used a combinatio
AuthorsMartin A. Briggs, Andrea K. Tokranov, Robert B. Hull, Denis R. LeBlanc, A. Haynes, John W. LaneGeochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
AuthorsAndrea K. Weber, Larry B. Barber, Denis R. LeBlanc, Elsie M. Sunderland, Chad D. Vecitis - News
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