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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4097

An assessment of HgII to preserve carbonate system parameters in organic-rich estuarine waters An assessment of HgII to preserve carbonate system parameters in organic-rich estuarine waters

This work assesses the effectiveness of sample preservation techniques for measurements of pHT (total scale), total dissolved inorganic carbon (CT), and total alkalinity (AT) in organic-rich estuarine waters as well as the internal consistency of measurements and calculations (e.g., AT, pHT, and CT) in these waters. Using mercuric chloride (HgCl2)-treated and untreated water samples...
Authors
Christopher Moore, Robert H. Byrne, Kimberly Yates

Conserved grasslands support similar pollinator diversity as pollinator-specific practice regardless of proximal cropland and pesticide exposure Conserved grasslands support similar pollinator diversity as pollinator-specific practice regardless of proximal cropland and pesticide exposure

Pollinator diversity and abundance are declining globally. Cropland agriculture and the corresponding use of agricultural pesticides may contribute to these declines, while increased pollinator habitat (flowering plants) can help mitigate them. Here we tested whether the relative effect of wildflower plantings on pollinator diversity and counts were modified by proportion of nearby...
Authors
Johanna M. Kraus, Kelly Smalling, Mark W. Vandever, Carrie E. Givens, Cassandra Smith, Dana W. Kolpin, Michelle L. Hladik

Broad-scale assessment of methylmercury in adult amphibians Broad-scale assessment of methylmercury in adult amphibians

Mercury (Hg) is a toxic contaminant that has been mobilized and distributed worldwide and is a threat to many wildlife species. Amphibians are facing unprecedented global declines due to many threats including contaminants. While the biphasic life history of many amphibians creates a potential nexus for methylmercury (MeHg) exposure in aquatic habitats and subsequent health effects, the...
Authors
Brian J. Tornabene, Blake R. Hossack, Brian J. Halstead, Collin A. Eagles-Smith, Michael J. Adams, Adam R. Backlin, Adrianne Brand, Colleen Emery, Robert N. Fisher, Jillian Elizabeth Fleming, Brad Glorioso, Daniel A. Grear, Evan H. Campbell Grant, Patrick M. Kleeman, David Miller, Erin L. Muths, Christopher Pearl, Jennifer Rowe, Caitlin Teresa Rumrill, J. Hardin Waddle, Megan Winzeler, Kelly L. Smalling

Ammonia and aquatic ecosystems – A review of global sources, biogeochemical cycling, and effects on fish Ammonia and aquatic ecosystems – A review of global sources, biogeochemical cycling, and effects on fish

The purpose of this review is to better understand the full life cycle and influence of ammonia from an aquatic biology perspective. While ammonia has toxic properties in water and air, it also plays a central role in the biogeochemical nitrogen (N) cycle and regulates mechanisms of normal and abnormal fish physiology. Additionally, as the second most synthesized chemical on Earth...
Authors
Thea M. Edwards, Holly J. Puglis, Jonathan Lopez Duran, Lillian Bradshaw, Douglas B. Kent, Aida Farag

Photochemical mobilization of dissolved hydrocarbon oxidation products from petroleum contaminated soil into a shallow aquifer activate human nuclear receptors Photochemical mobilization of dissolved hydrocarbon oxidation products from petroleum contaminated soil into a shallow aquifer activate human nuclear receptors

Elevated non-volatile dissolved organic carbon (NVDOC) concentrations in groundwater monitoring wells under oil-contaminated hydrophobic soils originating from a pipeline rupture at the National Crude Oil Spill & Natural Attenuation Research Site near Bemidji, MN are documented.. We hypothesized the elevated NVDOC is comprised of water-soluble photooxidation products transported from the...
Authors
Phoebe Zito, Barbara A. Bekins, Dalma Martinović-Weigelt, Maxwell L. Harsha, Katherine E. Humpal, Jared J. Trost, Isabelle M. Cozzarelli, Lynn R. Mazzoleni, Simeon K. Schum, David C. Podgorski

Attenuation of barium, strontium, cobalt, and nickel plumes formed during microbial iron-reduction in a crude-oil-contaminated aquifer Attenuation of barium, strontium, cobalt, and nickel plumes formed during microbial iron-reduction in a crude-oil-contaminated aquifer

We assessed the spatial distribution of 35 elements in aquifer sediments and groundwater of a crude-oil-contaminated aquifer and show evidence of the dissolution of barium (Ba), strontium (Sr), cobalt (Co), and nickel (Ni) during hydrocarbon oxidation coupled to historic microbial Fe(III)-reduction near the oil. Trace element plumes occur in the crude-oil-contaminated aquifer, where 50%...
Authors
Katherine Jones, Brady Ziegler, Audrey Davis, Isabelle M. Cozzarelli

Assessing environmental oil spill based on fluorescence images of water samples and deep learning Assessing environmental oil spill based on fluorescence images of water samples and deep learning

Measuring oil concentration in the aquatic environment is essential for determining the potential exposure, risk, or injury for oil spill response and natural resource damage assessment. Conventional analytical chemistry methods require samples to be collected in the field, shipped, and processed in the laboratory, which is also rather time-consuming, laborious, and costly. For rapid...
Authors
D. P. Liu, Ming Liu, Guangyu Sun, Zhiqian Zhou, Duolin Wang, Fei He, Jiaxin Li, Jiacheng Xie, Ryan Gettler, Eric Brunson, Jeffery A. Steevens, Dong Xu

Nitrifying microorganisms linked to biotransformation of perfluoroalkyl sulfonamido precursors from legacy aqueous film forming foams Nitrifying microorganisms linked to biotransformation of perfluoroalkyl sulfonamido precursors from legacy aqueous film forming foams

Drinking water supplies across the United States have been contaminated by firefighting and fire-training activities that use aqueous film-forming foams (AFFF) containing per- and polyfluoroalkyl substances (PFAS). Much of the AFFF is manufactured using electrochemical fluorination by 3M. Precursors with six perfluorinated carbons (C6) and non-fluorinated amine substituents make up...
Authors
Bridger J. Ruyle, Lara Schultes, Denise M. Akob, Cassandra Rashan Harris, Michelle M. Lorah, Simon Vojta, Jitka Becanova, Shelly McCann, Heidi M. Pickard, Ann Pearson, Rainer Lohmann, Chad D. Vecitis, Elsie M. Sunderland

Uptake of per- and polyfluoroalkyl substances by fish, mussel, and passive samplers in mobile laboratory exposures using groundwater from a contamination plume at a historical fire training area, Cape Cod, Massachusetts Uptake of per- and polyfluoroalkyl substances by fish, mussel, and passive samplers in mobile laboratory exposures using groundwater from a contamination plume at a historical fire training area, Cape Cod, Massachusetts

Aqueous film-forming foams historically were used during fire training activities on Joint Base Cape Cod, Massachusetts, and created an extensive per- and polyfluoroalkyl substances (PFAS) groundwater contamination plume. The potential for PFAS bioconcentration from exposure to the contaminated groundwater, which discharges to surface water bodies, was assessed with mobile-laboratory...
Authors
Larry B. Barber, Heidi M. Pickard, David A. Alvarez, Jitka Becanova, Steffanie H. Keefe, Denis R. LeBlanc, Rainer Lohmann, Jeffery A. Steevens, Alan M. Vajda

Tracking status and trends in seven key indicators of stream health in the Chesapeake Bay watershed Tracking status and trends in seven key indicators of stream health in the Chesapeake Bay watershed

“The Bay Connects us, the Bay reflects us” writes Tom Horton in the book “Turning the Tide—Saving the Chesapeake Bay”. The Chesapeake Bay watershed contains the largest estuary in the United States. The watershed stretches north to Cooperstown, New York, south to Lynchburg and Virginia Beach, Virginia, west to Pendleton County, West Virginia, and east to Seaford, Delaware, and Scranton
Authors
Samuel H. Austin, Matthew J. Cashman, John W. Clune, James E. Colgin, Rosemary M. Fanelli, Kevin P. Krause, Emily H. Majcher, Kelly O. Maloney, Christopher A. Mason, Douglas L. Moyer, Tammy M. Zimmerman

The influence of short-term temporal variability on the efficacy of dragonfly larvae as mercury biosentinels The influence of short-term temporal variability on the efficacy of dragonfly larvae as mercury biosentinels

Mercury (Hg) exposure to fish, wildlife, and humans is widespread and of global concern, thus stimulating efforts to reduce emissions. Because the relationships between rates of inorganic Hg loading, methylmercury (MeHg) production, and bioaccumulation are extremely complex and challenging to predict, there is a need for reliable biosentinels to understand the distribution of Hg in the...
Authors
James Willacker, Collin A. Eagles-Smith, Sarah J. Nelson, Colleen M. Flanagan-Pritz, David P. Krabbenhoft
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